Nucleophilic Substitution Reactions with Haloalkanes
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Questions and Answers

What type of reaction occurs when a nucleophile replaces an already existing nucleophile in a molecule?

  • Addition reaction
  • Substitution reaction (correct)
  • Reduction reaction
  • Elimination reaction

In nucleophilic substitution reactions, which part of the substrate molecule do nucleophiles attack?

  • Electron-deficient part (correct)
  • Positive part
  • Electron-rich part
  • Neutral part

What type of atom departs as a leaving group in a nucleophilic substitution reaction involving haloalkanes?

  • Nitrogen atom
  • Carbon atom
  • Halogen atom (correct)
  • Oxygen atom

Which functional groups are examples of ambident nucleophiles with two nucleophilic centers?

<p>Cyanides and nitrites (D)</p> Signup and view all the answers

Why is the cyanide group considered an ambident nucleophile?

<p>Due to its hybrid structure (C)</p> Signup and view all the answers

What type of carbon is typically bonded to the halogen atom in haloalkanes involved in nucleophilic substitution reactions?

<p>sp3 hybridized carbon (B)</p> Signup and view all the answers

In the presence of alcoholic KOH, what is the major product formed when treating alkyl chlorides?

<p>Alkenes (D)</p> Signup and view all the answers

What is the product obtained when primary alkyl halide C₄H₉Br reacts with alcoholic KOH?

<p>Alcohol (C)</p> Signup and view all the answers

When compound (b) obtained from (a) is reacted with HBr, what is the product (c) which is an isomer of (a)?

<p>Alkene (D)</p> Signup and view all the answers

What is the product formed when n-butyl bromide reacts with sodium metal?

<p>Alkane (D)</p> Signup and view all the answers

Which type of reaction involves the departure of a leaving group and the formation of a carbocation?

<p><strong>SN1 Reaction</strong> (A)</p> Signup and view all the answers

When alkyl chlorides react with aqueous KOH, what product is predominantly formed?

<p><strong>Alcohols</strong> (D)</p> Signup and view all the answers

What is the main reason why the methods used for the preparation of alkyl halides are not applicable for the preparation of aryl halides?

<p>The carbon-oxygen bond in phenols has a partial double bond character. (A)</p> Signup and view all the answers

In free radical monochlorination of (CH3)2CHCH2CH3, how many monochloro structural isomers can be expected to form?

<p>Four (B)</p> Signup and view all the answers

Which rule governs the predominant product formation in the addition of hydrogen halides to alkenes?

<p>Markovnikov's rule (D)</p> Signup and view all the answers

What is the color change observed when bromine in CCl4 is added to an alkene in the laboratory?

<p>Reddish brown to colorless (D)</p> Signup and view all the answers

Which type of reaction leads to the synthesis of vic-dibromides from alkenes?

<p>Addition of halogens (B)</p> Signup and view all the answers

Why does free radical chlorination or bromination of alkanes give a complex mixture of isomeric mono- and polyhaloalkanes?

<p>Because free radical reactions lack selectivity. (D)</p> Signup and view all the answers

What is the first step in a Sandmeyer's reaction involving primary aromatic amines?

<p>Treatment with sodium nitrite (C)</p> Signup and view all the answers

Why does the replacement of the diazonium group by iodine not require cuprous halide?

<p>Iodine is more reactive than cuprous halide (A)</p> Signup and view all the answers

What is the key factor that causes bromides and iodides to develop color when exposed to light?

<p>Photochemical reactions (C)</p> Signup and view all the answers

Which statement about alkyl halides is true regarding their color?

<p>Bromides and iodides are colorless when pure (D)</p> Signup and view all the answers

Why are methyl chloride, methyl bromide, ethyl chloride, and some chlorofluoromethanes gases at room temperature?

<p>They have weak intermolecular forces (B)</p> Signup and view all the answers

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