Molar Concentration Calculations Quiz

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Questions and Answers

A 70% (w/w) solution of nitric acid means that it contains 70 g of nitric acid per 100 g of solution.

True (A)

Volume percent is typically used to specify the concentration of a solution by diluting a solid compound with a liquid.

False (B)

A 5% (v/v) aqueous solution of methanol is prepared by diluting 5.0 mL of methanol with enough water to give 100 mL.

True (A)

Weight to volume percent is often used to describe the concentration of concentrated aqueous solutions.

<p>False (B)</p> Signup and view all the answers

Parts per Million (ppm) is a convenient way to express concentration for concentrated solutions.

<p>False (B)</p> Signup and view all the answers

When 20 ml of 10 N HCl are diluted with distilled water to form one liter of the solution, the normality of the diluted solution remains 10 N.

<p>True (A)</p> Signup and view all the answers

Molarity is the number of moles of a solvent that is contained in 1 liter of the solution.

<p>False (B)</p> Signup and view all the answers

Normality is the number of equivalents of solute that is contained in 1 liter of solution.

<p>True (A)</p> Signup and view all the answers

Weight percent is a common method used to express the concentration of commercial aqueous reagents.

<p>True (A)</p> Signup and view all the answers

For salt, the calculation of (n) is the total number of replaceable H+1 ions.

<p>False (B)</p> Signup and view all the answers

In a 2M H2SO4 solution, the molar mass of H2SO4 is 49g/mol.

<p>False (B)</p> Signup and view all the answers

In a 500ml solution, if 0.4g of NaOH (40g/mol) is dissolved, the molarity of the solution is 0.08M.

<p>False (B)</p> Signup and view all the answers

Flashcards

70% w/w Solution

Contains 70 g of solute in 100 g of solution.

Volume Percent

Specifies concentration by volume of liquid in the solution.

5% v/v Aqueous Solution

5.0 mL of solute diluted to a final volume of 100 mL.

Weight to Volume Percent

Describes concentration by mass of solute per volume of solution.

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Parts per Million (ppm)

Express concentration; best for very diluted solutions.

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Normality

Number of equivalents of solute in 1 liter of solution.

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Molarity Misconception

Molarity is moles of solute per liter of solution, not solvent.

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Weight Percent

Expresses concentration by mass of solute in 100 g of solution.

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Acid H+ Ions Calculation

For salts, count replaceable H+ ions; not just total mole ratio.

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Molar Mass of H2SO4

Molar mass is 98 g/mol, not 49 g/mol.

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Molarity Calculation

In 500 mL with 0.4 g NaOH (40 g/mol), molarity is 0.02 M, not 0.08 M.

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Dilution Law

Diluting HCl with water keeps normality constant if volume increases.

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Study Notes

Molar Concentration (Molarity)

  • Molarity is the number of moles of a solute in 1 liter of the solution.
  • Example: 2.30g of C2H5OH in 3.50 L of solution has a certain molar concentration.
  • Molarity can be calculated using the formula: Molarity = number of moles of solute / volume of solution (in liters).

Examples of Molarity Calculations

  • Example 1: Calculate the molar concentration of ethanol in an aqueous solution.
  • Example 2: Determine the mass of H2SO4 in a 2M solution.
  • Example 3: Calculate the molarity of a solution of NaOH.
  • Example 4: Calculate the molarity of a solution of sodium metal.

Normal Concentration (Normality)

  • Normality is the number of equivalents of solute in 1 liter of solution.
  • Calculation of normality (n) for acid: n = number of replaceable H+1.
  • Calculation of normality (n) for base: n = number of replaceable OH-1.
  • Calculation of normality (n) for salt: n = total number of positive or negative charge.
  • Example: Find the normality of H2SO4 in a 500ml solution.

Percent Concentration

  • Percent concentration is a way to express the concentration of a solution.
  • Three common methods are: weight percent, volume percent, and weight to volume percent.
  • Example: A 5% (w/v) aqueous solution of silver nitrate.

Parts per Million (ppm)

  • ppm is a convenient way to express concentration for very dilute solutions.
  • A handy rule: for dilute aqueous solutions, 1 ppm = 1.00 mg/L.

Dilution

  • Example: A 20 ml of 10 N HCl is diluted with distilled water to form one liter of the solution.
  • What is the normality of the diluted solution?

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