MO Theory in Organic Chemistry
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Questions and Answers

What is the expected site of addition under kinetic control?

  • The point where the HOMO is concentrated
  • The point where the LUMO is not concentrated
  • The point where the empty acceptor orbital is concentrated (correct)
  • The point where the nucleophile is present
  • Why does pentadienyl (L2X) react before allyl (LX)?

  • Pentadienyl is more electron-withdrawing than allyl
  • Pentadienyl has less X character than allyl (correct)
  • Pentadienyl is more negatively charged than allyl
  • Pentadienyl has more anionic character than allyl
  • What is the difference between the LX2 form of butadiene and the X2 form of ethylene?

  • The LX2 form is more reactive than the X2 form
  • The LX2 form is a less significant contributor to butadiene complexes than the X2 form is to ethylene complexes
  • The LX2 form is a more significant contributor to butadiene complexes than the X2 form is to ethylene complexes (correct)
  • The LX2 form is more stable than the X2 form
  • Why do terminal carbons of even, open ligands undergo addition?

    <p>The LUMO is predominant at the terminal carbon</p> Signup and view all the answers

    What is the condition for terminal addition to occur in an odd, open polyenyl?

    <p>The metal is sufficiently electron-withdrawing</p> Signup and view all the answers

    What is the difference between ψ2 and ψ3 in the MO picture of the allyl group?

    <p>ψ2 prefers the terminus, and ψ3 is predominant at the central carbon</p> Signup and view all the answers

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