Mixtures and Solutions

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Questions and Answers

Match the following terms with their definitions related to solutions:

Solute = The substance that is dissolved in a solution. Solvent = The substance that dissolves the solute, present in greater amount. Aqueous solution = A solution where the primary solvent is water. Dissociation = The process where ionic or polar solutes separate into ions in a solvent.

Match the types of solutions with their saturation levels:

Saturated solution = Contains the maximum amount of solute that can dissolve at a given temperature, with excess solute potentially settling out. Unsaturated solution = Contains less solute than the maximum it can dissolve at a given temperature. Supersaturated solution = Contains more solute than it can theoretically dissolve at a given temperature, often unstable. Electrolyte solution = A solution containing ions, allowing it to conduct electricity.

Match the types of electrolyte solutions with their dissociation behavior:

Strong electrolyte = Dissolves and completely dissociates into ions. Weak electrolyte = Dissolves but only partially dissociates into ions. Nonelectrolyte = Dissolves but does not dissociate into ions. Saturated solution = A solution with the maximum amount of dissolved solute.

Match the reaction types with their descriptions for reactions in solutions:

<p>Molecular equation = Shows the complete formulas of all reactants and products without indicating ionic forms. Overall ionic equation = Shows all soluble ionic substances dissociated into ions. Net ionic equation = Shows only the species that participate in the reaction, excluding spectator ions. Dilution equation = A reaction that shows the process of reducing a concentration of a solution.</p> Signup and view all the answers

Match the concentration units with their mathematical expressions:

<p>Parts per hundred (%) = $ rac{\text{mass of solute}}{\text{total mass of solution}} \times 100$ Parts per million (ppm) = $ rac{\text{mass of solute}}{\text{total mass of solution}} \times 10^6$ Parts per billion (ppb) = $ rac{\text{mass of solute}}{\text{total mass of solution}} \times 10^9$ Molarity (M) = $\frac{\text{moles of solute}}{\text{liters of solution}}$</p> Signup and view all the answers

Match the effect of temperature on solubility with the type of compound:

<p>Ionic compounds = Solubility generally increases with increasing temperature. Gases = Solubility generally decreases with increasing temperature. Polar solvents = Tend to dissolve polar and ionic compounds due to favorable interactions. Nonpolar solvents = Tend to dissolve nonpolar compounds due to London dispersion forces.</p> Signup and view all the answers

Match the following terms with their description

<p>Soluble = Most or all of a chemical dissolves into ions. Insoluble = Some ions dissolve, but not much or essentially none. Precipitate = A solid that forms out of a solution during a chemical reaction. Spectator ions = Ions that exist in the same form on both the reactant and product sides of a chemical reaction.</p> Signup and view all the answers

Match the type of solution with its behavior

<p>Saturated solution = Dissolved all it can, additional solute sinks. Unsaturated solution = Dissolves some solute but can dissolve more. Supersaturated solution = More dissolved than temperature dictates. Aqueous = A solution with H2O.</p> Signup and view all the answers

Match the term with the type of substance

<p>Polar = Dissolves other polar compounds (ionic). Nonpolar = Dissolves other nonpolar compounds. Ionic bonds = Break into atoms. Covalent bonds = Stay as molecules</p> Signup and view all the answers

Match the term with its respective meaning for performing calculations

<p>M = Molarity. V = Volume. NaCl = Table Salt. MgCl2 = Aqueous solution example.</p> Signup and view all the answers

Match each term with its definition in the context of solutions.

<p>Dilution = The process of decreasing the concentration of a solute in a solution. Concentration = The amount of solute present in a given volume of solution. Molarity = The number of moles of solute per liter of solution, denoted by M. Volume = The amount of space a solution occupies.</p> Signup and view all the answers

Match each concept with its application in solution chemistry.

<p>&quot;Like Dissolves Like&quot; = Polar solvents dissolve polar solutes, and nonpolar solvents dissolve nonpolar solutes. Dissociation = The separation of ions when an ionic compound dissolves in water. Solubility = The maximum amount of solute that can dissolve in a solvent at a given temperature. Molarity = A measure of the concentration of a solution.</p> Signup and view all the answers

Match each process with the factor that affects its rate in solution chemistry.

<p>Dissolving = Increased by mixing or agitating the solution. Heating = Increases the speed of movement and water breaking apart, speeding up dissolving. Breaking up solute = Facilitates interaction with the solvent, speeding up dissolving. Cooling = Can decrease the amount of molecules than can be dissolved.</p> Signup and view all the answers

Match each solution type with its characteristic concentration state.

<p>Saturated Solution = Contains the maximum concentration of solute that will dissolve in the solvent. Unsaturated Solution = Contains less than the maximum concentration of solute that can dissolve in the solvent. Supersaturated Solution = Contains more than the maximum concentration of solute that should dissolve in the solvent. Dilute Solution = Contains a small amount of solute.</p> Signup and view all the answers

Match the term to which process is useful in the context of calculations

<p>Solute = Part that is dissolved. Solvent = Part that does the dissolving, major amount. Volume = Amount of the substance. Molarity = Measure the concentration of a solution.</p> Signup and view all the answers

Match each type of equation with its role in representing chemical reactions in solutions.

<p>Molecular Equation = Shows all reactants and products as neutral, complete formulas. Complete Ionic Equation = Shows all soluble ionic substances dissociated into ions in the solution. Net Ionic Equation = Shows only the species that participate in the reaction, excluding spectator ions. Chemical equations = Depicts a visual representation of a chemical process.</p> Signup and view all the answers

Match the concentration unit with its application in expressing very low concentrations accurately.

<p>Parts per Million (ppm) = Used for expressing the concentration of a solute at very low levels, like contaminants in water. Parts per Billion (ppb) = Used for expressing extremely low concentrations, like trace elements or pollutants. Parts per hundred (%) = Used to calculate percentages. Molarity = Used for common concentration values.</p> Signup and view all the answers

Match the change to a solution with its effect on concentration or volume as indicated by the dilution equation.

<p>Adding solvent = Increases the volume and decreases the concentration. Evaporating solvent = Decreases the volume and increases the concentration. Increasing the moles of solute = Increase the concentration. Pouring the solution down the drain = Removes volume from the solution.</p> Signup and view all the answers

Match the characteristic of what a solution needs to have in order to become an electrolyte.

<p>Ions = Must have dissolved ions present in the water solution. Electrons = Needs to have charged electrons in order to carry the charge. Aqueous = Needs to be Aqueous. Temperature = Has a certain temperature.</p> Signup and view all the answers

Match each feature with its purpose

<p>Mol of solute/L of solution = Molarity Ionic/polar solute = Will get ripped apart by H2O. Mixing up Solution = Speeds up dissolving. “Like dissolves like” = Polarity</p> Signup and view all the answers

Flashcards

Heterogeneous mixture

Not evenly mixed; components are easily distinguishable.

Homogeneous mixture

Evenly mixed at a microscopic level; appears uniform throughout.

Solute

The substance that dissolves in a solvent.

Solvent

The substance that dissolves the solute.

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Aqueous solution

A solution where the solvent is water.

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"Like dissolves like"

Polar substances dissolve polar substances; nonpolar dissolves nonpolar.

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Dissociation

The process where ionic or polar solutes are separated into ions when dissolved in water.

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Saturated solution

A solution that contains the maximum amount of solute that can be dissolved at a given temperature.

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Unsaturated solution

A solution that contains less than the maximum amount of solute that can be dissolved at a given temperature.

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Supersaturated solution

A solution that contains more solute than can normally be dissolved at a given temperature.

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Electrolyte solution

A solution containing ions, enabling it to conduct electricity.

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Strong electrolyte solution

Solution where 100% of the dissolved chemical splits into ions.

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Nonelectrolyte solution

Solution where 0% of the dissolved chemical splits into ions.

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Weak electrolyte solution

Solution where only 5% splits into ions, 95% stays a compound.

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Soluble

Almost all of the chemical dissolves into ions.

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Insoluble

Some dissolves ions but not much, or none.

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Molecular Equation

An equation showing the overall reaction, but not in terms of individual ions.

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Overall ionic equation

An equation showing all the ions present in a solution.

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Net ionic equation

An equation showing only the ions that participate in forming a precipitate.

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Molarity

Moles of solute divided by liters of solution.

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Study Notes

Mixtures

  • Heterogeneous mixtures are not evenly mixed
  • Homogenous mixtures are evenly mixed solutions

Solutions

  • Solutions consist of two or more parts
  • The solute is the part that gets dissolved
  • The solvent is the part that does the dissolving and makes up the major amount of the solution
  • Aqueous solutions contain chemicals with H2O, for example, MgCl2 (aq)

"Like Dissolves Like"

  • Polar substances dissolve other polar, ionic compounds
  • Nonpolar substances dissolve other nonpolar compounds
  • Polar substances do not dissolve nonpolar substances

Dissolving Process

  • Dissolving is called dissociation
  • Ionic or polar solutes are broken apart by H2O
  • The lattice crystal slowly breaks apart in the process

Speeding up Dissolving

  • Mixing or agitating increases solute and solvent interactions
  • Heating speeds up movement and the rate at which water breaks apart
  • Breaking up the solute increases the speed of dissolving

Bonds in Solutions

  • Covalent bonds remain as molecules
  • Ionic bonds break into atoms

Types of Solutions

Saturated Solution

  • At saturation point, the solute only dissolves a fixed amount
  • A saturated solution has dissolved all it can, and the excess solute forms a solid chunk

Unsaturated Solution

  • An unsaturated solution has dissolved some solute but can dissolve more

Supersaturated Solution

  • A supersaturated solution contains more dissolved solute than dictated by temperature

Electrolyte Solutions

  • Electrolyte solutions have ions present in the solution
  • 100% of the dissolved chemical splits into ions in an electrolyte solution
  • Nonelectrolyte solutions have 0% of the dissolved chemical splitting into ions
  • Weak electrolyte solutions have 5% of the dissolved chemical splitting into ions, while 95% remains a compound

Chemical Reactions for Dissolving

  • The goal is to write a reaction that transforms a chemical from a solid to an aqueous state
  • An ionic solution results from a dissociation reaction
  • Examples of such reactions include CuF2, Cu2SO4, Al2O3, and FeBr3

Solubility

  • Solubility is at saturation point
  • Soluble substances have most or all of the chemical dissolving into ions
  • Insoluble substances have some ions dissolving but not much/none

Dissociation Reactions

  • Soluble Example: NaCl (100g) dissociates into Na^+ + Cl^- (100 ions)
  • Insoluble Example: AgCl (90% solid) dissociates into Ag^+ + Cl^- (2g ions)

Mixing Two Solutions

  • Mixing two solutions has two possible outcomes:
  • Nothing happens (no reaction)
  • Precipitate reaction (double replacement reaction) expressed as: XY (aq) + AB (aq) → AY (s) (ppt) + XB (aq)
  • Example: Pb(NO3)2 + KI → PbI2 + KNO3

Dissociation Reactions: 3 Main Reactions

  • Molecular Equation: An overview of what happened
  • Overall Ionic Equation: Depicts what actually happened
  • Net Ionic Equation: Shows what actually reacted
  • When given two solutions, know how to find all of these and Remember to balance
  • Examples: Na2CrO4 and Al(NO3)3, K3PO4 and CuNO3, Sr3N2 and Na2SO4

Measuring Solution Concentrations

Measuring Concentrations

  • Parts per hundred (%)
  • Parts per million (ppm)
  • Parts per billion (ppb)
  • Calculation: Part/whole times 100/1 million/1 billion = %/ppm/ppb

Molarity

  • Molarity (M) = moles of solute/liters of solution

Molarity Calculations

  • Molarity = Moles of solute / Liters of solution
  • "[x]" represents the concentration of x

Concentration of Ions

  • Find the concentration of the molecule and then multiply by how many cations/anions there are to find the concentration of the cations/ions
  • Multiply by the concentration of the molecule by both and then add the two products together to find the concentration of the ions

Dilution

  • Dilution involves increasing/decreasing the volume of a solution
  • Types of dilution problems:
  • Dilution of a solution
  • Reaction based (multiple solutions)
  • Dilution Equation: M1V1 = M2V2
  • M = molarity, V = volume
  • Molarity increases and volume decreases after solution is diluted

Volume Changes in Dilution

  • Types of volume changes:
  • Volume becomes “V2=___”
  • Add ____ to the solution (V2= V1+____)
  • Example: 50mL of 2.0M KCl solution has 200mL added, so V2=200+50=250mL

Stoichiometry with Molarity

  • Mass of ppt will form if 250mL of .95M VCl2 reacts with excess in the reaction: Pb(NO3)2+2VCl2→PbCl2+2V(NO3)4
  • Volume of 4.20M Li2CO3 used to make 700.g of ppt in the reaction: 3Li2CO3+Fe2(SO4)3→3Li2SO4+Fe2
  • Mass of ppt will form if 200.mL of 3.5M Pb(NO3)2 reacts with 100.0mL of .75M VCl4a in the reaction: 2Pb(NO3)2+VCl4→2PbCl2+V(NO3)4
  • The [anions] of 5M of calcium phosphate
  • Mass of ppt is formed when 600.mL of 1.7M K2CrO4 mixed with excess ZnF2
  • How many g of CaCl2 was needed to make it, if A.75L solution contains 3.5M Cl^-

Solution Review

  • Define:
  • Solute
  • Solvent
  • Saturated solution
  • Unsaturated solution
  • Electrolyte solution
  • Nonelectrolyte solution
  • To become an electrolyte solution, a compound needs to split into ions when dissolved in a water solution.
  • "Like dissolves like" is referring to intermolecular forces
  • A polar solute will dissolve in a polar solvent
  • A nonpolar solute will dissolve in a nonpolar solvent
  • An ionic compound will dissolve in a polar solvent
  • Aqueous means that the chemical is dissolved in water
  • How to write the Dissociation reaction for the following compounds:
    • Fe2(SO4)3
    • AlBr3
    • Tungsten (V) fluoride

Calculations

  • Given 22 grams of gold mixed with 16 grams of silver what the percent gold in 14-karat gold?
  • Given a 555 kg stone contains 3.7 grams of gold. What is the concentration of gold in parts per million?
  • How to calculate [K3PO4], if mixing 333 g K3PO4 into water to make a 875 mL solution?
  • What is the [cations] in 0.45 M tungsten (V) sulfate?
  • Given 750 grams precipitated when 500. mL of Li2S and 500. mL of excess Au(ClO3)3 solutions mixed together, what was the concentration of the Li2S solution in the following reaction: 3Li2S(aq) + 2Au(ClO3)3 (aq) → Au2S3 (s) + 6LiClO3 (aq)
  • If 111 g FeCl3 is dissolved into a 555 mL solution, what is the concentration of the solution? What is the concentration of the anions in the solution?
  • What is the volume needed to take 244 g KCl and make a 1.45 M solution?
  • If mixing 35 grams of NaBrO3 into a 150. ml solution when a student mistakenly added 100. mL of water to the solution, what is the concentration after this mistake?
  • If a Jar with 10.0 L of .650 M Fe(ClO3)3 solution is left out in the sun for the summer and concentration of anions in the new solution, when I get back to class and find there is only 1.30 L of solution left?

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