MCH2006 Manufacturing Processes: Polymers Functions and Applications
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Questions and Answers

What are the properties of thermoplastics?

  • Low cost, lightweight, and flexible (correct)
  • Low cost, tough, and insulating
  • High cost, rigid, and brittle
  • High cost, heavy, and transparent
  • Which classification of polymers is based on the Polymerization mechanism?

  • Physical behavior
  • Polymerization chemistry (correct)
  • By origin
  • Structure/Architecture
  • What is a common origin for natural gas-derived polymers?

  • Animals (correct)
  • Insects
  • Plants
  • Coal
  • Which application is associated with polyethylene terephthalate (PETE)?

    <p>Wire insulation</p> Signup and view all the answers

    What are the properties of thermosets?

    <p>Hard, rigid, and non-recyclable</p> Signup and view all the answers

    How are polymers classified based on structure/architecture?

    <p>Physical behavior</p> Signup and view all the answers

    Where do biopolymers like chitan primarily come from?

    <p>Insect &amp; crustacean exoskeletons</p> Signup and view all the answers

    What is a key application of polyvinyl acetate (PVA)?

    <p>Adhesives</p> Signup and view all the answers

    Which family do materials like nylon-6 belong to?

    <p>Thermoplastics</p> Signup and view all the answers

    What are some common engineering applications of polystyrene?

    <p>Toys</p> Signup and view all the answers

    Study Notes

    Major Functions of Polymers

    • Adhesives: superglue, epoxies
    • Structural components: polyethylene, polyesters, PPMA or PC transparent sheets, molded ABS or HIPS
    • Barriers: polyethylene landfill, garbage bags, Sarah wrap
    • Insulation: polyurethane foam, Styrofoam, polyethylene wire coatings, Bakelite (phenol-formaldehyde)

    Types of Polymers

    • Thermoplastics: soften when heated and harden when cooled, relatively soft
    • Thermosetting polymers: network polymers with covalent cross-links between adjacent chains, generally harder and stronger

    History of Polymers

    • 1868: Cellulose Nitrate
    • 1909: Phenol-Formaldehyde
    • 1919: Casein
    • 1927: Cellulose Acetate, Polyvinyl Chloride
    • 1929: Urea-Formaldehyde
    • 1936: Acrylic, Polystyrene
    • 1938: Polyvinyl Butyrate, Polyvinylidene Chloride, Melamine-Formaldehyde
    • 1939: Nylon (Polyamide)
    • 1942: Polyester, Polyethylene
    • 1943: Fluorocarbon, Silicone
    • 1947: Epoxy
    • 1948: Acrylonitrile-Butadiene-Styrene
    • 1954: Polyurethane
    • 1956: Acetal
    • 1957: Polypropylene, Polycarbonate
    • 1964: Ionomer, Polyimide

    Classes of Ceramics

    • Glasses
    • Clay
    • Refractories
    • Abrasives
    • Cements
    • Advanced ceramics: optical, whiteware, bricks, sandpaper, composites, high T ceramics, structural ceramics

    Why Use Polymers

    • Easy to process
    • Cheap
    • Lightweight
    • Tough
    • Flexible
    • Transparent (sometimes)
    • Insulating (generally)

    Classification of Polymers

    • By origin
    • By physical behavior
    • By structure/architecture
    • By application/function
    • By polymerization mechanism
    • By polymerization chemistry
    • By cost

    Origin of Polymers

    • Biopolymers: proteins, cellulosic fibers, lignin & cellulose, chitin
    • Synthetic Polymers: coal, petroleum, natural gas

    Physical Behavior & Architecture

    • Thermoplastics: polystyrene, polyvinylchloride
    • Elastomers: synthetic rubbers, poly-cis-isoprene
    • Thermosets: phenolic resins, melamines, epoxies

    Applications/Function

    • Structural: nylon-6
    • Coatings: poly(vinyl acetate)
    • Fibers: poly(ethylene terephthalate)
    • Adhesives: poly(vinyl acetate)

    Cost: Commodity (Amorphous) Thermoplastics

    • Polyethylene (PE): grocery bag, 55-gallon drum, lawn furniture
    • Polypropylene (PP): washing machine agitator, carpet
    • Polyvinylchloride (PVC): irrigation pipe, wire insulation
    • Polystyrene (PS): toys, pipes, packing material (Styrofoam)

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