Materials Science Chapter 2.1
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Questions and Answers

What is the term for the component of either a liquid or solid solution that is present to a lesser or minor extent?

  • System
  • Solvent
  • Microstructure
  • Solute (correct)
  • What is the maximum concentration of solute atoms that may dissolve in the solvent to form a solid solution?

  • Phase Diagram
  • System
  • Microstructure
  • Solubility Limit (correct)
  • What is the term for the distribution of phases and defects in a material?

  • System
  • Phase Diagram
  • Microstructure (correct)
  • Solubility Limit
  • In a unary phase diagram, what is the value of F in the single phase region?

    <p>2</p> Signup and view all the answers

    What type of phase diagram is obtained when there is complete solid and liquid solubility?

    <p>Isomorphous Phase Diagram</p> Signup and view all the answers

    What is the term for a specific body of material or object?

    <p>System</p> Signup and view all the answers

    What is the approximate tensile strength of pearlite?

    <p>120000 psi</p> Signup and view all the answers

    What is the crystal structure of Austenite?

    <p>Face-centered Cubic (FCC)</p> Signup and view all the answers

    What is the composition of Ledeburite?

    <p>4.3 %C</p> Signup and view all the answers

    What is the solubility limit of carbon in ferrite?

    <p>0.09 wt%</p> Signup and view all the answers

    What is the purpose of the TTT diagram?

    <p>To show the kinetics of isothermal transformations</p> Signup and view all the answers

    What is the temperature at which austenite is formed?

    <p>1147ºC</p> Signup and view all the answers

    What is the primary purpose of a phase diagram in materials science?

    <p>To demarcate regions of existence of various phases</p> Signup and view all the answers

    What is the difference between 'equilibrium' in phase diagrams and global equilibrium?

    <p>The former is a microstructural level equilibrium, whereas the latter is a global equilibrium</p> Signup and view all the answers

    What is a component of a system in the context of phase diagrams?

    <p>An independent chemical species that comprises the system</p> Signup and view all the answers

    What is the primary characteristic of a gas phase?

    <p>It is always a single phase mixed at the atomic or molecular level</p> Signup and view all the answers

    What is the definition of a phase in the context of phase diagrams?

    <p>A physically homogeneous and distinct portion of a material system</p> Signup and view all the answers

    What is phase transformation in the context of phase diagrams?

    <p>The change of one phase into another</p> Signup and view all the answers

    What is the main characteristic of an isomorphous system?

    <p>Complete solid solubility in the solid and liquid state</p> Signup and view all the answers

    How do you determine the actual chemical composition of phases in an alloy at a specified temperature?

    <p>Draw a horizontal line, called a tie line, to the boundaries of the field</p> Signup and view all the answers

    What is the principle behind the Lever rule?

    <p>The relative lengths of the lever arms are inversely proportional to the amount of the phases present</p> Signup and view all the answers

    What is the characteristic of a eutectic phase diagram?

    <p>One composition that freezes at a single temperature</p> Signup and view all the answers

    What is the reaction that occurs in a Peritectic reaction?

    <p>Liquid (L) reacts with one solid (a) to produce another solid (ß)</p> Signup and view all the answers

    What is the limitation of Peritectic reactions?

    <p>Difficult to equilibrate due to solid state diffusion</p> Signup and view all the answers

    Why is it difficult to equilibrate peritectic reactions?

    <p>Because the reaction is limited by solid state diffusion</p> Signup and view all the answers

    What is the name of the property exhibited by some metals, including Iron, Tin, Manganese, and Cobalt, where they can exist in more than one type of crystal structure depending on temperature?

    <p>Allotropy</p> Signup and view all the answers

    What is the term for the rearrangement of atoms in a solid solution, where the solute atoms move into definite positions in the lattice?

    <p>Ordering</p> Signup and view all the answers

    What is the composition of cementite in terms of carbon content?

    <p>6.67 wt.% C</p> Signup and view all the answers

    What is the crystal structure of ferrite?

    <p>B.C.C.</p> Signup and view all the answers

    What is the tensile strength of ferrite?

    <p>40,000 psi</p> Signup and view all the answers

    What is the temperature range below which Austenite transforms to Martensite?

    <p>Below Ms</p> Signup and view all the answers

    What is the characteristic of Martensite formation?

    <p>Dependent on temperature of quench</p> Signup and view all the answers

    What is the name of the structure that appears in the nose region of the TTT diagram?

    <p>Bainite</p> Signup and view all the answers

    What is the advantage of composites in terms of weight reduction?

    <p>High strength-to-weight ratio</p> Signup and view all the answers

    What is the property of composites that allows for tailored properties?

    <p>Ability to select different combinations of constituent materials</p> Signup and view all the answers

    What is the industry that uses composites for boat hulls and decks due to their corrosion resistance?

    <p>Marine</p> Signup and view all the answers

    What is the property of certain composites that makes them suitable for applications subjected to cyclic loading?

    <p>Fatigue resistance</p> Signup and view all the answers

    What is the characteristic of composite materials that allows for design flexibility?

    <p>Ability to create complex shapes and structures</p> Signup and view all the answers

    What is the advantage of composites in terms of electrical applications?

    <p>Electrical insulation</p> Signup and view all the answers

    What is the application of composites in sports equipment?

    <p>Tennis rackets and golf clubs</p> Signup and view all the answers

    Study Notes

    Introduction to Phase Diagrams

    • A phase diagram is a graphical representation of the equilibrium relationships between phases in a system
    • It is used to identify the phases present in a system at a given temperature and composition
    • Phase diagrams can be unary (one component), binary (two components), or ternary (three components)

    Components of a System

    • A system consists of independent chemical species, which can be elements, ions, or compounds
    • Examples:
      • Au-Cu system: components are Au and Cu (elements)
      • Ice-water system: component is H2O (compound)
      • Al2O3-Cr2O3 system: components are Al2O3 and Cr2O3

    Phases

    • A phase is a physically homogeneous and distinct portion of a material system
    • Phases can be classified based on:
      • State: gas, liquid, solid
      • Atomic order: amorphous, quasi-crystalline, crystalline
      • Band structure: insulating, semiconducting, semi-metallic, metallic
      • Property: para-electric, ferromagnetic, superconducting
      • Stability: stable, metastable, unstable
      • Size/geometry of an entity: nano-crystalline, mesoporous, layered

    Phase Transformations

    • Phase transformation is the change of one phase into another
    • Examples:
      • Solid → Liquid → Gas

    Solvent and Solute

    • Solvent: the component present in a greater extent in a solution
    • Solute: the component present in a lesser extent in a solution

    Phase Diagrams

    • Unary phase diagram: a phase diagram with one component
    • Binary phase diagram: a phase diagram with two components
    • Isomorphous phase diagram: a phase diagram with complete solid and liquid solubility
    • Eutectic phase diagram: a phase diagram with limited solid solubility and one composition at which the liquid freezes at a single temperature
    • Peritectic phase diagram: a phase diagram with complete liquid solubility and a reaction between the liquid and a solid to produce another solid

    Tie Line and Lever Rule

    • Tie line: a horizontal line drawn at a specified temperature to determine the chemical composition of phases in equilibrium
    • Lever rule: a method to determine the relative amounts of each phase in equilibrium

    Eutectic and Peritectic Phase Diagrams

    • Eutectic reaction: a reaction where the liquid freezes at a single temperature
    • Peritectic reaction: a reaction where the liquid reacts with a solid to produce another solid
    • Characteristics of eutectic and peritectic reactions:
      • Complete liquid solubility
      • Limited solid solubility
      • Formation of a new solid phase

    Allotropic Transformations

    • Allotropic transformations: changes in crystal structure of a metal with temperature
    • Examples:
      • Iron: B.C.C. to F.C.C. structure
      • Tin: diamond cubic to tetragonal structure

    TTT Diagrams

    • Time-Temperature-Transformation (TTT) diagrams: diagrams that show the kinetics of isothermal transformations
    • Determination of TTT diagrams: using molten salt bath techniques combined with metallography and hardness measurements
    • Utility of TTT diagrams: predicting microstructures and kinetics of phase transformations

    Composite Materials

    • Composite materials: engineered materials made from two or more constituent materials with different physical or chemical properties
    • Advantages of composite materials:
      • High strength-to-weight ratio
      • Tailored properties
      • Corrosion resistance### Benefits of Composites
    • Offer designers greater flexibility in creating complex shapes and structures that would be difficult or impossible to achieve with traditional materials like metals
    • Exhibit excellent fatigue resistance, making them suitable for applications subjected to cyclic loading
    • Have good electrical insulation properties, making them suitable for electrical and electronic applications

    Applications of Composite Materials

    Aerospace Industry

    • Extensively used due to high strength-to-weight ratio
    • Components made from composites include aircraft fuselages, wings, and engine components

    Automotive Industry

    • Used to manufacture body panels, chassis components, and interior parts
    • Contribute to weight reduction and improved fuel efficiency

    Marine Industry

    • Widely used for boat hulls, decks, and other structural components
    • Chosen for corrosion resistance and high strength

    Construction

    • Used in bridges, buildings, and infrastructure components
    • Valued for durability, corrosion resistance, and design flexibility

    Sports and Recreation

    • Prevalent in sports equipment such as tennis rackets, golf clubs, bicycles, and skis
    • Lightweight nature and ability to enhance performance make them ideal

    Wind Energy

    • Wind turbine blades are often made from composite materials
    • High strength and fatigue resistance enable efficient energy generation

    Medical Industry

    • Used in medical applications such as prosthetics, orthopaedic implants, and dental materials
    • Biocompatibility and tailored mechanical properties make them suitable

    Electronics

    • Composite materials with excellent electrical insulation properties are used in electronic components, circuit boards, and insulation materials

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    Description

    Learn about phase diagrams, an essential tool in materials science, and how they illustrate the existence of different phases. Understand the concept of microstructural level equilibrium.

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