Materials Science and Engineering Overview

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Questions and Answers

Which of the following areas are influenced by materials? (Select all that apply)

  • Transportation (correct)
  • Astronomy
  • Medicine (correct)
  • Personal hygiene (correct)

Materials science only contributes to engineering fields.

False (B)

Name one component that makes up the discipline of materials science and engineering.

Any specific component (e.g. structure, properties, performance, or processing).

Materials science contributes to fields such as medicine, transportation, and _____ production.

<p>food</p> Signup and view all the answers

Match the following applications with their corresponding fields influenced by materials:

<p>Medicine &amp; health = Advancements in treatments and diagnostics National security = Materials used in defense technologies Textiles = Production of clothing and fabrics Agriculture = Innovations in food science and farming techniques</p> Signup and view all the answers

Which method is used to determine the amount or concentration of a particular compound in a sample?

<p>Quantitative Analysis (D)</p> Signup and view all the answers

Qualitative analysis measures the concentration of substances in a sample.

<p>False (B)</p> Signup and view all the answers

Name one method used in quantitative analysis to determine concentrations.

<p>Titration or gravimetric methods.</p> Signup and view all the answers

Quantitative analysis involves measuring the sample's physical properties such as mass, volume, and _____ to determine concentrations.

<p>density</p> Signup and view all the answers

Match the types of analysis to their definitions:

<p>Qualitative Analysis = Identifies presence or absence of substances Quantitative Analysis = Measures the amount or concentration of substances</p> Signup and view all the answers

Which of the following is an example of a physical method in quantitative analysis?

<p>Atomic Emission Spectroscopy (AES) (D)</p> Signup and view all the answers

Chemical methods include physical characteristics of a sample.

<p>False (B)</p> Signup and view all the answers

What can result in inaccurate results in quantitative analysis?

<p>Assumptions and experimental mistakes.</p> Signup and view all the answers

What is the primary focus of Quality Assurance?

<p>Providing confidence that requirements will be fulfilled (D)</p> Signup and view all the answers

Quality Control is a subset of Quality Assurance.

<p>True (A)</p> Signup and view all the answers

What is the definition of Quality Control?

<p>Part of management focused on fulfilling quality requirements.</p> Signup and view all the answers

Quality Assurance provides confidence both internally to management and __________.

<p>externally to customers</p> Signup and view all the answers

In a service organization, what might Quality Control include?

<p>Quality control of involved products (B)</p> Signup and view all the answers

Match the following terms with their descriptions:

<p>Quality Assurance = Planned activities to ensure quality requirements are met Quality Control = Operational techniques for fulfilling quality needs Inspection = Measuring and testing product characteristics Service Quality Control = Quality control of tangible or document products involved in services</p> Signup and view all the answers

Inspection is only applicable to tangible products.

<p>False (B)</p> Signup and view all the answers

Quality Control relates to how a process is performed or how a product is __________.

<p>made</p> Signup and view all the answers

What happens to positive ions in the flame during the detection process?

<p>They are attracted to the cylindrical cathode. (A)</p> Signup and view all the answers

The electric current generated by the flame ionisation detector is significantly large.

<p>False (B)</p> Signup and view all the answers

What is the main disadvantage of using a flame ionisation detector?

<p>It destroys everything coming out of the column.</p> Signup and view all the answers

The areas under the peaks in the output are proportional to the amount of each compound which has passed the ______.

<p>detector</p> Signup and view all the answers

What does the flame ionisation detector output represent?

<p>The electric current measured. (A)</p> Signup and view all the answers

Compounds must be similar for accurate measurement using the flame ionisation detector.

<p>True (A)</p> Signup and view all the answers

In what way can the current be amplified in the flame ionisation detector?

<p>By increasing the amount of organic compound in the flame.</p> Signup and view all the answers

What is the effect of a compound having a high boiling point when first entering the column?

<p>It spends most of its time as a liquid. (C)</p> Signup and view all the answers

A higher column temperature results in longer retention times for all compounds.

<p>False (B)</p> Signup and view all the answers

What is the role of temperature in the chromatographic process?

<p>Temperature controls the retention time and separation of compounds through the column.</p> Signup and view all the answers

The presence of ions and electrons produced during the burning of an organic compound can be detected in the __________.

<p>flame ionisation detector</p> Signup and view all the answers

What happens to compounds with high solubility in the liquid phase?

<p>They spend less time in the gas phase. (D)</p> Signup and view all the answers

Match the characteristics with their corresponding effects on retention time:

<p>High boiling point = Long retention time High solubility in liquid phase = Short retention time High column temperature = Short retention time Low column temperature = Longer retention time</p> Signup and view all the answers

What is the recommended procedure for temperature management in the column?

<p>Start cool and gradually increase the temperature. (B)</p> Signup and view all the answers

The flame ionisation detector operates at a lower temperature than the column.

<p>False (B)</p> Signup and view all the answers

What is one major requirement for a thermobalance?

<p>It must monitor the change in weight as a function of temperature. (B)</p> Signup and view all the answers

Thermogravimetric Analysis (TGA) can be used to study the moisture content of organic components.

<p>True (A)</p> Signup and view all the answers

What is one advantage of TGA?

<p>High accuracy of the balance</p> Signup and view all the answers

TGA is used for the thermal characterization of __________.

<p>polymers</p> Signup and view all the answers

Which of the following is a limitation of TGA?

<p>Only solid samples are allowed for both qualitative and quantitative analysis. (C)</p> Signup and view all the answers

Match the following applications of TGA with their correct descriptions:

<p>Thermal characterization of polymers = Determining material properties Corrosion studies = Analyzing material degradation Determining purity = Assessing the quality of materials Investigating moisture content = Evaluating component hydration levels</p> Signup and view all the answers

What does TGA not exhibit during analysis?

<p>Any chemical or physical alterations that do not result in a change in mass</p> Signup and view all the answers

The rate of heating in TGA should be linear for accurate analysis.

<p>True (A)</p> Signup and view all the answers

Flashcards

Materials Science

The study of materials and their properties, focusing on how these properties relate to a material's atomic and molecular structure. It's also concerned with how materials are processed and how their performance can be improved.

Materials Engineering

The application of scientific principles to design, develop, and produce new materials that meet specific performance requirements.

Materials Science: A Multi-disciplinary Discipline

Materials science and engineering are crucial across various industries, contributing to advancements in medicine, communication, transportation, and numerous other fields.

Structure-Property Relationship

Materials' properties depend on their atomic structure and how those atoms are arranged. This gives us clues about how materials will behave and how they can be used.

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Materials Processing

Materials science and engineering involve processing materials into desired forms and shapes. These processes can significantly influence a final product's properties.

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Quality Assurance (QA)

A planned and systematic set of activities that provide confidence that a product or service will meet quality requirements.

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Quality Control (QC)

A subset of QA activities focused on fulfilling quality requirements by inspecting and verifying the product or service.

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Relationship between QA and QC

The activities are all connected under the umbrella of a quality system.

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Alternative Definition of QA

All the planned and systematic activities implemented within a quality system focused on providing confidence that requirements for quality will be fulfilled.

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Alternative Definition of QC

The operational techniques and activities used to fulfill requirements for quality.

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Inspection

The process of measuring, examining, and testing to determine if a product or service meets specified requirements.

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QC in Service Organizations

The concept of quality control might not apply directly, as there isn't a tangible product to inspect.

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QA in Service Organizations

Quality Assurance in service organizations include checking the quality of any products involved in delivering the service, like documents or tangible items.

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Retention Time

The time a compound spends in the chromatography column, influenced by factors such as boiling point and solubility.

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High Boiling Point Compound

A compound that spends most of its time as a liquid at the beginning of the chromatography column, due to a high boiling point.

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High Solubility Compound

A compound that readily dissolves in the liquid phase of the chromatography column.

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High Column Temperature

Increases the movement of molecules into the gas phase, shortening retention times in chromatography.

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Temperature Gradient

A method used to separate compounds in chromatography by gradually increasing the column temperature over time, which allows different compounds to elute at different times.

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Detector

A device used to detect and measure the presence of compounds as they elute from a chromatography column.

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Flame Ionization Detector (FID)

A common type of detector in gas chromatography that uses a flame to ionize organic compounds, creating a measurable electrical signal.

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Detector Oven

An oven that surrounds the detector in gas chromatography, maintaining a higher temperature than the column to prevent condensation.

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Thermogravimetric Analysis (TGA)

A technique that measures the change in weight of a sample as a function of temperature.

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Thermobalance

A device that measures the change in weight of a sample as a function of temperature.

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Weight monitoring

The ability to monitor the change in weight of the sample during the heating process.

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Linear heating rate

The rate at which the sample is heated should be constant and predictable.

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Hot Zone

The part of the furnace where the sample is placed and experiences a constant temperature.

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Balance mechanism

The mechanism that measures the weight of the sample and should be protected from corrosive gases and the furnace environment.

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Accurate temperature measurement

Determining the temperature of the sample is crucial for accurate analysis.

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Applications of TGA

A method used for thermal characterization of polymers, analyzing compositions of alloys and mixtures, determining purity and thermal stability of materials, investigating moisture content, and more.

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Chromatography

The process of separating different components of a mixture based on their different affinities to a stationary phase.

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Detectability

The ability of a compound to be separated and detected in a chromatography system.

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Ionization

The process of producing ions from neutral molecules, often using a flame.

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Peak Area

The measurement of the area under a peak in a chromatogram, which is proportional to the amount of compound present.

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Destructive Detection

The process of using a flame to destroy the compounds passing through the detector.

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Mass Spectrometry

A technique that uses a beam of ions to identify and quantify different compounds present in a sample.

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What is quantitative analysis?

Quantitative analysis is used to determine the amount or concentration of a specific compound or element in a sample.

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How does quantitative analysis work?

This method involves measuring physical properties of the sample like mass, volume, and density, then performing calculations to find the amount of the substance.

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What are some chemical methods used in quantitative analysis?

Titration methods, gravimetric methods, combustion analysis methods, and chemical reactions like oxidation, reduction, precipitation, and neutralization are examples of chemical methods.

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What are some physical methods used in quantitative analysis?

Physical methods analyze the sample's physical characteristics. Examples include AES (Atomic Emission Spectroscopy), x-ray fluorescence, spectroscopy, mass spectroscopy, and more.

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How do physical and chemical methods work together in quantitative analysis?

Both physical and chemical analysis methods combined with specific calculations help determine the exact concentration of a component in a sample.

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What are some potential challenges in quantitative analysis?

Assumptions and experimental errors can lead to inaccurate results in quantitative analysis.

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What is the main difference between quantitative and qualitative analysis?

Qualitative analysis identifies whether a specific substance is present or absent in a sample, while quantitative analysis measures the amount or concentration of that substance.

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What are some examples of quantitative analysis applications?

Quantitative analysis can be used to determine the amount of a substance in a sample, such as a chemical solution or a biological specimen.

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Study Notes

Role of Materials in Engineering

  • Materials are crucial to modern life, impacting transportation, housing, communication, and more.
  • Materials science and engineering deal with the relationships between material structure and properties.
  • Materials scientists create new materials, while engineers utilize existing resources to build new products/systems.
  • Materials science and engineering combine fundamental knowledge of physics, chemistry, and mathematics with engineering disciplines.

Materials Science and Engineering

  • Materials science focuses on the relationships between structure and properties of materials.
  • Materials engineering applies these relationships, designing materials with specific properties.
  • The four key elements are processing/synthesis, structure/composition, properties, and performance/application.
  • This discipline is vital for designing and producing materials to meet societal needs.

Quality Assurance and Quality Control

  • Quality assurance (QA) focuses on ensuring quality requirements are met, providing confidence to both internal management and external parties.
  • Quality control (QC) focuses on fulfilling quality requirements—it's the operational techniques/activities.
  • Inspection involves measuring, examining, and testing products or services to ensure conformity to specified requirements.
  • Auditing is part of QA, comparing actual conditions with requirements and reporting results to management.

Qualitative and Quantitative Analysis

  • Qualitative analysis identifies the presence/absence of elements or compounds in a sample.
  • Qualitative analysis uses observational techniques, including color, texture, odor, and chemical tests.
  • Quantitative analysis measures the quantity/concentration of a specific element or compound in a sample.

Quantitative Analysis Methods

  • Titration, gravimetric, combustion, and chemical reactions (oxidation, reduction, precipitation, neutralization) are examples of quantitative analysis methods.
  • Physical methods also measure physical characteristics to determine concentration (Atomic emission spectroscopy, x-ray fluorescence, spectroscopy, and mass spectroscopy).

Difference Between Qualitative and Quantitative Analysis

  • Qualitative Analysis identifies elements/compounds presence or absence; Quantitative analysis measures the amount/concentration.
  • Qualitative analysis is simple using chemical tests (color, precipitate); Quantitative analysis is more precise with instruments (mass, volume).
  • Qualitative analysis is less precise relying on subjective observations. Quantitative analysis is more precise using objective measurements.
  • Qualitative analysis uses small sample sizes; Quantitative analysis uses larger sample sizes for accurate results.

UV-Vis Spectroscopy

  • UV-Vis spectroscopy measures the absorption or emission of electromagnetic radiation in the ultraviolet and visible regions.
  • Electrons in molecules move from ground to higher energy states upon ultraviolet radiation absorption
  • UV-Vis spectroscopy is used to identify impurities, elucidate the structure of organic compounds, and measure the quantitative determination of compounds.

High-Performance Liquid Chromatography (HPLC)

  • HPLC is a liquid chromatography technique for separating, identifying, and quantifying compounds in a mixture.
  • HPLC involves a stationary phase and mobile phase (a solvent); High pressure forces the mobile phase through the column for better separation.
  • Detection methods such as UV-Vis spectroscopy are used for identification and quantification of separated compounds.

Gas-Liquid Chromatography (GLC)

  • GLC separates volatile compounds in a gaseous mobile phase.
  • GLC typically uses a high-boiling-point liquid adsorbed onto a solid as a stationary phase in a column.
  • Compounds with stronger interactions with the stationary phase (i.e. higher solubility) spend more time in the column, resulting in different retention times.

Thermogravimetric Analysis (TGA)

  • TGA measures weight changes of a sample as a function of temperature.
  • TGA provides information on thermal characteristics of polymers, alloys, and determining the purity of specific samples.
  • TGA is used for corrosion studies and kinetic studies of isothermal reactions.

Scanning Electron Microscopy (SEM)

  • SEM is a microscopy technique that scans a surface with a focused beam of electrons.
  • SEM uses secondary electrons emitted from the sample to generate an image, allowing visualization of surface topography and compositional information
  • SEM is used to examine various materials, including biological samples, and useful in determining structure and composition of samples.

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