Podcast
Questions and Answers
What condition is essential for dynamic equilibrium to be achieved?
What condition is essential for dynamic equilibrium to be achieved?
- The system must be open, allowing reactants or products to enter.
- The system must involve only irreversible reactions.
- The system must be isolated to prevent any energy transfer.
- The system must be closed, and the rate of forward reaction equals the rate of the reverse reaction. (correct)
How is the equilibrium constant, $K_c$, defined for a reversible reaction?
How is the equilibrium constant, $K_c$, defined for a reversible reaction?
- The ratio of the product of active masses of the products to that of the reactants. (correct)
- The sum of the concentrations of products and reactants at equilibrium.
- The ratio of the product of active masses of the reactants to that of the products.
- The ratio of the sum of reactant concentrations to the sum of product concentrations.
What information does the value of the equilibrium constant, $K_c$, provide about a reaction at a given temperature?
What information does the value of the equilibrium constant, $K_c$, provide about a reaction at a given temperature?
- The extent to which a reaction proceeds towards product formation. (correct)
- The initial concentrations of reactants and products.
- The energy required for the reaction to occur.
- The speed at which equilibrium is reached.
Under which conditions is the reaction quotient, $Q_c$, defined?
Under which conditions is the reaction quotient, $Q_c$, defined?
How does the reaction quotient, $Q_c$, relate to the equilibrium constant, $K_c$, in determining the direction a reaction will proceed?
How does the reaction quotient, $Q_c$, relate to the equilibrium constant, $K_c$, in determining the direction a reaction will proceed?
How does temperature affect the equilibrium constant, $K_c$?
How does temperature affect the equilibrium constant, $K_c$?
In a balanced chemical equation, how are the active masses of reactants and products raised when calculating $K_c$?
In a balanced chemical equation, how are the active masses of reactants and products raised when calculating $K_c$?
What does a very small $K_c$ value indicate about the reaction?
What does a very small $K_c$ value indicate about the reaction?
What characterises reactions with a very large $K_c$ value?
What characterises reactions with a very large $K_c$ value?
What term describes the concentration of a reacting substance?
What term describes the concentration of a reacting substance?
At equilibrium, what can be said about the relationship between the rate of forward and reverse reactions, and the concentrations of reactants and products?
At equilibrium, what can be said about the relationship between the rate of forward and reverse reactions, and the concentrations of reactants and products?
Which statement accurately describes reversible reactions?
Which statement accurately describes reversible reactions?
In the context of equilibrium, which statement regarding forward and reverse reactions is correct?
In the context of equilibrium, which statement regarding forward and reverse reactions is correct?
What is the state of the rate of forward reaction and product formation at the start of a chemical reaction?
What is the state of the rate of forward reaction and product formation at the start of a chemical reaction?
What must typically be observed during the process of the chemical reaction to determine the state of equilibrium?
What must typically be observed during the process of the chemical reaction to determine the state of equilibrium?
Flashcards
Reversible Reactions
Reversible Reactions
Reactions proceed in either direction, forward and backward.
Dynamic Equilibrium
Dynamic Equilibrium
The rates of forward and reverse reactions equalize.
Equilibrium Condition
Equilibrium Condition
Rate of forward reaction equals to the rate of reverse reaction.
Active Mass
Active Mass
Signup and view all the flashcards
Equilibrium Constant (Kc)
Equilibrium Constant (Kc)
Signup and view all the flashcards
Extent of Chemical Reaction
Extent of Chemical Reaction
Signup and view all the flashcards
Reactions with low Kc
Reactions with low Kc
Signup and view all the flashcards
Kc is very large
Kc is very large
Signup and view all the flashcards
Reaction Quotient (Qc)
Reaction Quotient (Qc)
Signup and view all the flashcards
Study Notes
Lyapunov Stability Analysis
- Lyapunov's direct method can be used to determine the stability of an equilibrium point.
- Considering the system $\dot{x} = f(x)$, where $f(0) = 0$, $x = 0$ is an equilibrium.
- The Lyapunov function candidate is $V(x)$.
Lyapunov Function Candidate Conditions
- $V(x)$ must be continuously differentiable.
- $V(0) = 0$
- $V(x) > 0$ for all $x \neq 0$
Stability Conditions
- If $\dot{V}(x) \le 0$, the origin is stable.
- If $\dot{V}(x) < 0$, the origin is asymptotically stable.
Rate of Change of Lyapunov Function
- The rate of change of the Lyapunov function is calculated as $\dot{V}(x) = \frac{\partial V}{\partial x} \dot{x} = \frac{\partial V}{\partial x} f(x)$.
Proof of Lyapunov Stability
- Shows that any solution $x(t)$ starting sufficiently close to 0 remains close to 0 for all time.
- The solution $x = 0$ of $\dot{x} = f(x)$ is stable if for any $\epsilon > 0$, there exists a $\delta > 0$ such that if $||x(0)|| < \delta$ then $||x(t)|| < \epsilon$ for all $t \ge 0$.
Steps
- Pick an $\epsilon > 0$ and consider $B_\epsilon = {x \in \mathbb{R}^n : ||x|| \le \epsilon }$.
- Must find a $B_\delta$ such that solutions starting in $B_\delta$ stay in $B_\epsilon$.
- Since $V(x)$ is continuous and $V(0) = 0$, the set ${x : V(x) \le c}$ is closed and bounded for sufficiently small $c$.
- Let $c = \min_{x \in \partial B_\epsilon} V(x)$ where $\partial B_\epsilon = {x \in \mathbb{R}^n : ||x|| = \epsilon }$.
- Now let $B_\delta = {x : V(x) \le c/2 }$.
- A trajectory that starts in $B_\delta$ will have $V(x(0)) \le c/2$ and, since $\dot{V}(x) \le 0$, $V(x(t))$ can only decrease.
- Therefore, $x(t)$ can never leave $B_\epsilon$.
Invariance Principle
- If a Lyapunov function $V(x)$ has $\dot{V}(x) \le 0$, then every solution starting in a compact set converges to $M$ as $t \to \infty$, where $M$ is the largest invariant set in $S = {x : \dot{V}(x) = 0 }$.
- A set $M$ is invariant if $x(0) \in M \implies x(t) \in M$ for all $t$.
Linear Systems
- Given $\dot{x} = Ax$, a Lyapunov function is $V(x) = x^T P x$ where $P = P^T > 0$.
- The rate of change is: $\dot{V}(x) = x^T (A^T P + PA) x$.
- Letting $Q = -(A^T P + PA)$, then $\dot{V}(x) = -x^T Q x$.
- Asymptotic stability occurs if $Q > 0$, then $\dot{V}(x) < 0$ for $x \neq 0$.
- Such a $P$ exists for a given $Q$ if $A$ is stable.
- Lyapunov Equation: $A^T P + PA = -Q$
Linear Algebra and Matrix Analysis
Matrix Calculus
- Deals with matrices and fundamental matrix operations
- Matrix is a rectangular collection of scalars, e.g., real or complex numbers
- Matrix calculus provides compact notation to denote and solve mathematical problems in various fields
Matrix Definition
- Matrix $A$ of size $m \times n$ is a rectangular array with $m$ rows and $n$ columns
- $A = \begin{bmatrix} a_{11} & a_{12} & \cdots & a_{1n} \ a_{21} & a_{22} & \cdots & a_{2n} \ \vdots & \vdots & \ddots & \vdots \ a_{m1} & a_{m2} & \cdots & a_{mn} \end{bmatrix}$
- Terminology
- $a_{ij}$: element in the $i$-th row and $j$-th column
- $A = [a_{ij}]_{m \times n}$
- $M_{m,n}(\mathbb{R})$: set of $m \times n$ matrices with real coefficients
- $M_{m,n}(\mathbb{C})$: set of $m \times n$ matrices with complex coefficients
- If $m = n$: square matrix of order $n$, denoted as $M_n(\mathbb{R})$ or $M_n(\mathbb{C})$
- Example: $A = \begin{bmatrix} 1 & 2 & 3 \ 4 & 5 & 6 \end{bmatrix}$ is a $2 \times 3$ matrix.
Matrix Operations
Matrix Addition
- For matrices $A = [a_{ij}]{m \times n}$ and $B = [b{ij}]{m \times n}$ of the same size, their sum is $C = A + B = [c{ij}]{m \times n}$, defined by: $c{ij} = a_{ij} + b_{ij}, \forall i,j$
- $\begin{bmatrix} 1 & 2 \ 3 & 4 \end{bmatrix} + \begin{bmatrix} 5 & 6 \ 7 & 8 \end{bmatrix} = \begin{bmatrix} 6 & 8 \ 10 & 12 \end{bmatrix}$
Scalar Multiplication
- For matrix $A = [a_{ij}]{m \times n}$ and scalar $\alpha$, the product is $B = \alpha A = [b{ij}]{m \times n}$, defined by: $b{ij} = \alpha a_{ij}, \forall i,j$
Matrix Multiplication
- Definition: For matrices $A = [a_{ij}]{m \times n}$ and $B = [b{ij}]{n \times p}$, the product is $C = AB = [c{ij}]{m \times p}$, defined by: $c{ij} = \sum_{k=1}^{n} a_{ik}b_{kj}, \forall i,j$
- Requirements: The number of columns of $A$ must equal the number of rows of $B$
- Example: $A = \begin{bmatrix} 1 & 2 \ 3 & 4 \end{bmatrix}$, $B = \begin{bmatrix} 5 & 6 \ 7 & 8 \end{bmatrix}$ . Product is $ \begin{bmatrix} 1\cdot5 + 2\cdot7 & 1\cdot6 + 2\cdot8 \ 3\cdot5 + 4\cdot7 & 3\cdot6 + 4\cdot8 \end{bmatrix} = \begin{bmatrix} 19 & 22 \ 43 & 50 \end{bmatrix}$
Matrix Transposition
- For matrix $A = [a_{ij}]{m \times n}$, the transpose $A^T$ is $B = [b{ij}]{n \times m}$, where $b{ij} = a_{ji}, \forall i,j$
- If $A = \begin{bmatrix} 1 & 2 \ 3 & 4 \ 5 & 6 \end{bmatrix}$, then $A^T = \begin{bmatrix} 1 & 3 & 5 \ 2 & 4 & 6 \end{bmatrix}$
Properties of Matrix Operations
- Associativity of addition: $(A + B) + C = A + (B + C)$
- Commutativity of addition: $A + B = B + A$
- Distributivity over Scalar Addition: $\alpha(A + B) = \alpha A + \alpha B$
- Distributivity over Scalar Multiplication: $(\alpha + \beta)A = \alpha A + \beta A$
- Associativity of Multiplication: $(AB)C = A(BC)$
- Distributivity of Multiplication over Addition: $A(B + C) = AB + AC$ and $(A + B)C = AC + BC$
- Transposition of a Product: $(AB)^T = B^T A^T$
Special Matrices
Identity Matrix
- $n \times n$ matrix, denoted $I_n$, with ones on the main diagonal and zeros elsewhere
- Formula: $I_n = \begin{bmatrix} 1 & 0 & \cdots & 0 \ 0 & 1 & \cdots & 0 \ \vdots & \vdots & \ddots & \vdots \ 0 & 0 & \cdots & 1 \end{bmatrix}$
- Property: For any matrix $A \in M_{m,n}(\mathbb{R})$, $AI_n = A$ and $I_mA = A$.
Diagonal Matrix
- Square matrix where all elements outside the main diagonal are zeros
Triangular Matrix
- Upper Triangular: all elements below the main diagonal are zeros
- Lower Triangular: all elements above the main diagonal are zeros
Confusion Matrix Elements
- Verdad: Describe si una instancia fue clasificada correctamente o no.
- Positiva Verdadera (TP): Casos en los que predijimos SI y la realidad era SI.
- Negativa Verdadera (TN): Casos en los que predijimos NO y la realidad era NO.
- Falsos Positivos (FP): Casos en los que predijimos SI y la realidad era NO. (Error Tipo I)
- Falsos Negativos (FN): Casos en los que predijimos NO y la realidad era SI. (Error Tipo II)
Métricas
- Calcular métricas de rendimiento del modelo de clasificación.
- Exactitud (Accuracy): $\frac{TP + TN}{TP + TN + FP + FN}$
- Precisión (Precision): $\frac{TP}{TP + FP}$
- Recuperación (Recall): $\frac{TP}{TP + FN}$
- Puntuación F1 (F1 Score): $2 * \frac{Precision * Recall}{Precision + Recall}$
Material properties of AA 6061
Composition of AA6061 (% by weight)
- Silicon (Si): 0.4 to 0.8
- Iron (Fe): 0.7 max
- Copper (Cu): 0.15 to 0.4
- Manganese (Mn): 0.15 max
- Magnesium (Mg): 0.8 to 1.2
- Zinc (Zn): 0.25 max
- Chromium (Cr): 0.04 to 0.35
- Titanium (Ti): 0.15 max
- Aluminum (Al): Balance
Typical applications of AA6061
- Aircraft components.
- Camera lenses.
- Couplings.
- Marine fittings and hardware.
- Heavy-duty structures.
- Truck and marine transportation.
Important mechanical properties of AA6061
- Density: 2.70 g/cm3.
- Ultimate Tensile Strength: 310 MPa.
- Tensile Yield Strerngth: 276MPa.
- Elastic Modulus: 68.9 GPa.
- Poisson's Ratio: 0.33.
- Shear Modulus: 26 GPa.
- Hardness, Brinell: 95 HB.
- Fatigue Strength: 96.5 MPa.
- Machinability: good.
Important thermal properties of AA6061
- Thermal Conductivity: 167 W/m-K.
- Coefficient of Thermal Expansion: 23.6 µm/m-°C.
- Melting Point: 582 - 652°C.
- Solidus: 582°C.
- Liquidus: 652C.
Important electrical properties of AA6061
- Electrical Conductivity: 43% IACS.
- Electrical Resistivity: 0.040 µΩ-cm
Processing/Fabrication properties of AA6061
- Can be work hardened but has limited formability.
- Possesses good weldability using common methods.
- Is heat treatable.
- Includes Solution Heat Treatment, Quenching, and Precipitation Hardening (Aging).
Corrosion resistance features of AA6061
- Exhibits good corrosion resistance, particularly marine.
- Can be enhanced with anodizing.
What is static electricity?
- Build-up of electrical charges on an object's surface.
- It stays put until it's discharged.
How does static electricity form?
- Most objects are electrically neutral with an equal amount of positive and negative charge.
- Static electricity forms when rubbing two objects produces the shift of electrons from one surface to another.
- The material that looses electrons get a positive charge while the other becomes negative.
Different methods of creating electricity
- Rubbing a balloon on your hair creates negative electrical charges on the balloon and positive in the hair.
- Walking across a carpet shifts electrons from the carpet to your feet, which creates negative charge. When you touch a metal, the electrical discharge releases and creates a static shock.
Atomic structure basics
–Atom: Basic matter component.
- Proton: Positive charge, located in the nucleus.
- Neutron: No charge, located in the nucleus.
- Electron: Negative charge, orbits the nucleus.
Triboelectric sequences
- Rank substances in their propensity to gain or loose electrons.
- Material high in the list loose electrons and result in + charge while those lower gain electrons and turn -.
Material and Polarity summary
–Material: Air/Human Skin/Leather/ rabbit Fur/ Glass/Quartz/Mica/Nylon/Wool/Cat Fur/Silk/Paper/cotton/Wood etc , Polarity: positive
- Material: Amber/hard Rubber/Nickel, Copper/brass Silver/Gold Platinium/polyester/styrene/saran wrap/polyurethande/polyethylene/PVC/Silicon/Teflon,
- Polarity: Negative
Charge Interaction
- Similar repel and opposites attract.
Conductors vs Insulators
- Conductors let electrons to shift easily (e.g., metals). -Insulators resist electrons to shift (e.g., plastic, glass).
Charging Techniques
–Shifting of electrons when rubbing (friction).
- Switching electrons by direct touch (conduction).
- Shifting of electrical charges because of an existing charge(Induction).
Importance of grounding
- Removes and controls build up of excess electrical charge by connecting the object to the Earth for balance.
Static electrical discharge
- Electrical shift when a potential electrical difference occurs.
- Usually, a spark occurs with cracking.
Static electricity practical uses
- Electrostatic dust removers that clear particles.
- Electrostatic paints where electrical charges help paintings. Photocopiers and laser prints with static electricity on drums
Static electrical danger
–Electrical discharge can damage electrical components.
- Flammable materials are prone to ignition with this charge.
Precautions: Mitigating Static Electricity
- Humidity control that eliminates static build up.
- Grounding techniques prevent build up.
- Anti static electrical sprays that decrease static build up.
Fundamental Coulomb's Law
–Relationship of charge and force, $F = k \frac{|q_1q_2|}{r^2}$
- F = Electrostatic force
- k = Coulomb's constant ($8.99 \times 10^9 Nm^2/C^2$)
- q_1 and q_2 = Magnitude of the charges
- r = Distance between the charges
Algorithmic Trading
- Automated order execution based on pre-programmed instructions.
- Algorithms consider factors like price, timing, and volume.
Benefits of Algorithmic Trading
- Reduced transaction costs.
- Improved order execution.
- Enhanced liquidity.
- Enables complex trading strategies.
Common Algorithmic Trading Strategies
Trend Following
- Capitalizing on assets moving in a consistent direction.
- Moving Averages: Using moving averages to trade in line with the prevailing trend.
- Breakout Strategies: Buying when prices exceed resistance or selling when they fall below support.
Mean Reversion
- Based on the concept that prices will revert to their average over time.
- Pairs Trading: Exploiting price differences between correlated assets with the expectation of convergence.
- Bollinger Bands: Identifying overbought or oversold conditions and trading contrarian.
Arbitrage Strategies
- Exploiting price differences in different markets or forms of the same asset.
- Statistical Arbitrage: Using statistical models to identify mispricing across a basket of assets.
- Triangular Arbitrage: Profiting from price discrepancies between three currencies in the foreign exchange market.
Sentiment Analysis
- Gauging market sentiment from news and social media to inform trades.
- News Sentiment Analysis: Trading based on positive or negative signals extracted from news headlines.
- Social Media Sentiment: Aligning trades with market sentiment indicated by social media trends.
Machine Learning
- Using machine learning algorithms to predict price movements.
- Supervised Learning: Training models on historical data to predict future price movements.
- Reinforcement Learning: Learning optimal trading strategies through interaction with the market.
Example of Algorithmic Trading Programmed Rules
- An algorithm buys shares of stock if the 50-day moving average exceeds the 200-day moving average.
Note
- Algorithmic trading strategies have advantages but carry risks.
Atomic Habits: Introduction
- Book about building good habits and breaking bad ones.
- By James Clear.
Dijkstra's algorithm
- Given by Edsger W. Dijkstra.
- Calculates the shortest path from a source node to a target node in a graph.
- Allows to find paths to every other node.
- Used in route planners, for example.
Description of the Algorithmus
- Directed on graph $G = (V, E)$ with the edge weights $w: E \to \R_{\ge 0}$.
- Weights indicate distance.
- Finds the shortest path from a source $s \in V$ to every other node $v \in V$.
Key Algorithim Initialization steps.
- Initalize distances to all nodea as "infinite" except source which is zero.
- Create a set with all nodes of the graph.
Process steps
- while the set of unvisited nodes exists, do the following:
- Select the one that is unvisited with the least distance. The Source nodes does this.
- Then, iterate through each neighboring node to compute total length and update accordingly.
- Update the lengths on neighbor if smaller from existing.
Key steps in thermodynamics; definitions:
- A phase refers to a substance that is uniform and has similar physcial properties.
- Compressing a object refers to a scenario where magnetic, gravitation and tension are negligible.
- Pure substance: A substance that is uniform and unchangeable when it comes to composition.
Phase Diagrams
- Include the phase diagrams to track different phases.
Essential Properties of Diagrams to Consider
-T-v diagram: Temperature vs specific volume
- P-v diagram: Pressure vs specific volume
- P-T diagram: Pressure vs Temperature
Understanding of Property Tables
- Saturated liquid
- Saturated vapor
- Compressed liquid
- Superheated vapor
- 2-Phase mixture
Applying properties to Quality
$$ x = \frac{m_{vapor}}{m_{total}} $$
Specific volume considerations
$$ v = v_f + x v_{fg} $$
Estimating of internal energy
$$ u = u_f + x u_{fg} $$
Estimating Enthalpy
$$ h = h_f + x h_{fg} $$
Applying it to entropy
$$ s = s_f + x s_{fg} $$
Understanding Ideal Gas Equation of State
$$ Pv = RT $$
- P is the absolute pressure
- v is the specific volume
- R is the gas constant
- T is the absolute temperature
Compressibility Factor defined as
$$ Z = \frac{Pv}{RT} $$
Van der Waals state and equation example
$$ P = \frac{RT}{v-b} - \frac{a}{v^2} $$
Redlich-Kwong Equation of State details
$$ P = \frac{RT}{v-b} - \frac{a}{v(v+b)T^{1/2}} $$
Studying That Suits You
Use AI to generate personalized quizzes and flashcards to suit your learning preferences.