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Questions and Answers
Which fatty acid has a carboxyl group at one end and a methyl group at the other end?
Which fatty acid has a carboxyl group at one end and a methyl group at the other end?
What is a primary biological function of essential fatty acids (EFAs)?
What is a primary biological function of essential fatty acids (EFAs)?
Which type of fatty acid is classified by having one double bond in its hydrocarbon chain?
Which type of fatty acid is classified by having one double bond in its hydrocarbon chain?
What distinguishes omega-3 fatty acids from other fatty acids?
What distinguishes omega-3 fatty acids from other fatty acids?
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Which food source is known to be rich in omega-3 fatty acids?
Which food source is known to be rich in omega-3 fatty acids?
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Which of the following is NOT considered an essential fatty acid?
Which of the following is NOT considered an essential fatty acid?
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What effect do omega-3 fatty acids have on low-density lipoprotein (LDL) levels?
What effect do omega-3 fatty acids have on low-density lipoprotein (LDL) levels?
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Which statement about fatty acids is true regarding their saturation?
Which statement about fatty acids is true regarding their saturation?
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Which type of rancidity involves the reaction of oxygen with carbon in unsaturated fats?
Which type of rancidity involves the reaction of oxygen with carbon in unsaturated fats?
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What is the maximum recommended daily intake of saturated fat for adults?
What is the maximum recommended daily intake of saturated fat for adults?
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What function do lipids serve that relates to vitamin absorption?
What function do lipids serve that relates to vitamin absorption?
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Which of the following statements about the plasticity of fats is correct?
Which of the following statements about the plasticity of fats is correct?
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During lipid digestion, which digestive organ is responsible for secreting bile?
During lipid digestion, which digestive organ is responsible for secreting bile?
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What is a possible dietary disorder associated with consuming excessive saturated fats?
What is a possible dietary disorder associated with consuming excessive saturated fats?
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Which statement correctly describes the energy value of lipids?
Which statement correctly describes the energy value of lipids?
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What is hydrolytic rancidity primarily caused by?
What is hydrolytic rancidity primarily caused by?
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What is the main purpose of an emulsifier in food preparation?
What is the main purpose of an emulsifier in food preparation?
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At what temperature do fats begin to emit vapour, indicating a potential flash point?
At what temperature do fats begin to emit vapour, indicating a potential flash point?
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Which of the following best describes a permanent emulsion?
Which of the following best describes a permanent emulsion?
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Which lipid property primarily relates to its odor absorption capabilities?
Which lipid property primarily relates to its odor absorption capabilities?
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What occurs during the hydrogenation process of unsaturated oils?
What occurs during the hydrogenation process of unsaturated oils?
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What is the role of stabilisers in emulsions?
What is the role of stabilisers in emulsions?
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Which statement is true regarding the solubility of lipids?
Which statement is true regarding the solubility of lipids?
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What characterizes the melting point of solid fats?
What characterizes the melting point of solid fats?
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Study Notes
Elemental Composition of Lipids
- Lipids are composed of carbon (C), hydrogen (H), and oxygen (O).
Chemical Structure of Lipids
- Lipids are composed of triglycerides.
- A triglyceride contains one glycerol molecule and three fatty acid molecules.
- Glycerol is a trihydric alcohol with three hydroxyl (OH) groups.
- A fatty acid is an organic compound represented by the formula R-COOH. The R represents the hydrocarbon chain.
- Each hydroxyl group of glycerol combines with hydrogens from three fatty acids, resulting in the loss of three water molecules (condensation reaction).
Classification of Fatty Acids
- Fatty acids are long hydrocarbon chains with a carboxyl group (COOH) at one end and a methyl group (CH3) at the other.
- The number of carbon atoms varies between fatty acids.
- General chemical formula: CH3(CH2)nCOOH
- Fatty acids are categorized by their degree of saturation:
- Saturated fatty acids
- Monounsaturated fatty acids
- Polyunsaturated fatty acids
- Saturation refers to the amount of hydrogen molecules present in a fatty acid.
Saturated Fatty Acids
- Each carbon atom is fully saturated with hydrogen atoms.
- No double bonds between carbon atoms.
- Solid at room temperature (high melting point).
- Examples include butyric acid (in butter), stearic acid (in meat).
Monounsaturated Fatty Acids
- Each carbon atom is not fully saturated with hydrogen atoms.
- One double bond between carbon atoms.
- Soft or liquid at room temperature (low melting point).
- Example includes oleic acid (in olive oil).
Polyunsaturated Fatty Acids
- Each carbon atom is not fully saturated with hydrogen atoms.
- More than one double bond between carbon atoms.
- Soft or liquid at room temperature (lowest melting point).
- Examples include alpha-linolenic acid, linoleic acid, arachidonic acid.
Essential Fatty Acids (EFAs)
- EFAs are fatty acids that the body cannot manufacture and must be obtained through food.
- Examples include linoleic acid (Omega-6), alpha-linolenic acid (Omega-3).
- Other polyunsaturated fatty acids can be synthesized from linoleic acid.
Sources of EFAs
- Nuts, seeds, olive oil, oily fish.
Biological Functions of EFAs
- Aid in cell membrane formation (essential for growth).
- Reduce the risk of coronary heart disease by increasing HDL (high-density lipoprotein) and lowering LDL (low-density lipoprotein).
- Decrease blood viscosity, preventing clots.
- Aid foetal brain development during pregnancy.
- Improve memory and cognitive function throughout life.
Omega-3 Fatty Acids
- Have a double bond between the third and fourth carbon atoms along the hydrocarbon chain.
- Two main types: eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA).
Cis and Trans Fatty Acids
- Cis fatty acids: Hydrogen atoms on the same side of the double bond.
- Trans fatty acids: Hydrogen atoms on opposite sides of the double bond.
- Cis fatty acids are naturally occurring in foods like olive oil and oily fish.
- Trans fatty acids are formed from cis fatty acids during heating or industrial processing (e.g., margarine).
- Trans fatty acids are generally considered less healthy than cis fatty acids.
Classification of Lipids by Source
- Animal fats are mainly saturated.
- Plant sources are mainly unsaturated.
- Marine sources are mainly polyunsaturated.
Properties of Lipids
- Solubility: Insoluble in water, soluble in solvents like ether and benzene.
- Flavor Absorption: Lipids easily absorb flavors.
- Heating: Melting points vary by type; decomposition occurs at higher temperatures.
- Emulsions: Mixture of immiscible liquids; temporary emulsions separate while permanent emulsions remain mixed (e.g., mayonnaise).
Emulsifiers
- Molecules with hydrophilic and hydrophobic properties preventing liquid separation in emulsion (e.g., lecithin, glycerol monostearate).
- Culinary use: Mayonnaise, ice cream.
Stabilisers
- Long-chained molecules maintaining emulsion stability (e.g., gums, gelatin).
- Culinary use: Yogurt, ice cream.
Hydrogenation
- Process of adding hydrogen to unsaturated fats.
- Converts oil into saturated fats (e.g., margarine production).
Rancidity
- Spoilage/decomposition of lipids (unpleasant odour/taste).
- Types include oxidative (oxygen reaction) and hydrolytic (enzyme/bacteria breakdown).
- Prevention methods (storage, antioxidants).
Plasticity
- Softening, pliability of fats at different temperatures.
- Depends on saturation levels (high saturation = harder).
Biological Functions of Lipids (Summary)
- Energy supply, body temperature maintenance, protection of organs, vitamin absorption, insulation, and essential fatty acid provision.
Dietary Allowance
- Adults: up to 70g total fat, up to 30g saturated fat per day.
- Women: up to 20g saturated fat per day.
Associated Dietary Disorders
- Consumption of too many saturated fats and fewer unsaturated fats leads to obesity, coronary heart disease (CHD), high cholesterol, strokes.
Digestion of Lipids
- Lipids are broken down into glycerol and fatty acids through hydrolysis.
- Digestion begins in the mouth (chewing), continues in the stomach (heating).
Absorption and Utilization of Lipids
- Fatty acids and glycerol are absorbed by the lymphatic system.
- Digested lipids are utilized to produce energy, cell membranes and stored as adipose tissue.
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Description
This quiz explores the elemental composition and chemical structure of lipids, focusing on triglycerides and fatty acids. It covers key concepts such as the functions of glycerol and fatty acids, as well as the classification based on saturation levels. Test your understanding of these fundamental biochemical components.