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Lewis Bases and Acids
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Lewis Bases and Acids

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Questions and Answers

What is a characteristic of a Lewis base?

  • It has a lone pair of electrons available for bonding (correct)
  • It is a metal ion that can form complexes
  • It has empty orbitals to accept electron pairs
  • It is a solvent for many reactions
  • Which of the following is an example of a metal ion that can act as a Lewis acid?

  • Cu2+ (correct)
  • BF3
  • NH3
  • ROR'
  • What is a common use of boron compounds like BF3?

  • As a solvent in many reactions
  • As a Lewis base to form complexes
  • As a catalyst in organic reactions (correct)
  • As a metal ion to accept electron pairs
  • Which of the following is a characteristic of ammonia (NH3) as a Lewis base?

    <p>It can form complexes with metal ions</p> Signup and view all the answers

    What is a common feature of Lewis acids with empty orbitals?

    <p>They can form complexes with Lewis bases</p> Signup and view all the answers

    Which of the following is an example of a Lewis base with a lone pair of electrons?

    <p>NH3</p> Signup and view all the answers

    In the equation NH3 + H+ → NH4+, what is the role of NH3?

    <p>Lewis base</p> Signup and view all the answers

    Which of the following species acts as a Lewis acid in the equation BF3 + F- → BF4-?

    <p>BF3</p> Signup and view all the answers

    In the equation Zn2+ + 4NH3 → Zn(NH3)4²⁺, what is the role of Zn2+?

    <p>Lewis acid</p> Signup and view all the answers

    What is the role of NH3 in the equation NH3 + HCl → NH4Cl?

    <p>Lewis base</p> Signup and view all the answers

    Which of the following species acts as a Lewis acid in the equation BF3 + NH3 → F3BNH3?

    <p>BF3</p> Signup and view all the answers

    Study Notes

    Lewis Bases With Lone Pairs

    • A Lewis base is a species that donates an electron pair to form a covalent bond
    • Lewis bases typically have a lone pair of electrons that are available for bonding
    • Examples of Lewis bases:
      • Amines (e.g. NH3, RNH2)
      • Phosphines (e.g. PH3)
      • Ethers (e.g. ROR')
      • Thiols (e.g. RSH)

    Metal Ions As Lewis Acids

    • Metal ions can act as Lewis acids by accepting electron pairs to form covalent bonds
    • Metal ions have empty orbitals that can accommodate electron pairs
    • Examples of metal ions that act as Lewis acids:
      • Fe3+, Cu2+, Zn2+
    • Metal ions can form complexes with Lewis bases, such as water, ammonia, or chloride ions

    Ammonia As A Lewis Base

    • Ammonia (NH3) is a common Lewis base
    • NH3 has a lone pair of electrons that can be donated to form a covalent bond
    • NH3 can form complexes with metal ions, such as Cu2+ or Zn2+
    • NH3 can also act as a solvent for many reactions

    Boron Compounds As Lewis Acids

    • Boron compounds, such as BF3 and BCl3, are Lewis acids
    • Boron compounds have empty orbitals that can accept electron pairs
    • BF3 and BCl3 can form complexes with Lewis bases, such as amines or ethers
    • Boron compounds are often used as catalysts in organic reactions

    Lewis Acids With Empty Orbitals

    • Lewis acids can have empty orbitals that can accept electron pairs
    • Examples of Lewis acids with empty orbitals:
      • BF3
      • BCl3
      • AlCl3
    • These Lewis acids can form complexes with Lewis bases, such as amines or ethers
    • Lewis acids with empty orbitals are often used as catalysts in organic reactions

    Lewis Bases

    • A Lewis base is a species that donates an electron pair to form a covalent bond
    • Lewis bases typically have a lone pair of electrons available for bonding
    • Examples of Lewis bases include amines (e.g. NH3, RNH2), phosphines (e.g. PH3), ethers (e.g. ROR'), and thiols (e.g. RSH)

    Lewis Acids

    • Metal ions can act as Lewis acids by accepting electron pairs to form covalent bonds
    • Metal ions have empty orbitals that can accommodate electron pairs
    • Examples of metal ions that act as Lewis acids include Fe3+, Cu2+, and Zn2+

    Ammonia (NH3)

    • Ammonia (NH3) is a common Lewis base that can donate electron pairs to form covalent bonds
    • NH3 has a lone pair of electrons
    • NH3 can form complexes with metal ions, such as Cu2+ or Zn2+, and act as a solvent for many reactions

    Boron Compounds

    • Boron compounds, such as BF3 and BCl3, are Lewis acids that can accept electron pairs
    • Boron compounds have empty orbitals
    • BF3 and BCl3 can form complexes with Lewis bases, such as amines or ethers, and are often used as catalysts in organic reactions

    Characteristics of Lewis Acids

    • Lewis acids can have empty orbitals that can accept electron pairs
    • Examples of Lewis acids with empty orbitals include BF3, BCl3, and AlCl3
    • These Lewis acids can form complexes with Lewis bases, such as amines or ethers, and are often used as catalysts in organic reactions

    Lewis Bases

    • A Lewis base is a species that donates an electron pair to form a covalent bond
    • Lewis bases typically have a lone pair of electrons available for bonding
    • Examples of Lewis bases include amines (e.g. NH3, RNH2), phosphines (e.g. PH3), ethers (e.g. ROR'), and thiols (e.g. RSH)

    Metal Ions as Lewis Acids

    • Metal ions can act as Lewis acids by accepting electron pairs to form covalent bonds
    • Metal ions have empty orbitals that can accommodate electron pairs
    • Examples of metal ions that act as Lewis acids include Fe3+, Cu2+, and Zn2+

    Ammonia as a Lewis Base

    • Ammonia (NH3) is a common Lewis base with a lone pair of electrons that can be donated to form a covalent bond
    • NH3 can form complexes with metal ions, such as Cu2+ or Zn2+
    • NH3 can also act as a solvent for many reactions

    Boron Compounds as Lewis Acids

    • Boron compounds, such as BF3 and BCl3, are Lewis acids with empty orbitals that can accept electron pairs
    • BF3 and BCl3 can form complexes with Lewis bases, such as amines or ethers
    • Boron compounds are often used as catalysts in organic reactions

    Lewis Acids with Empty Orbitals

    • Lewis acids can have empty orbitals that can accept electron pairs
    • Examples of Lewis acids with empty orbitals include BF3, BCl3, and AlCl3
    • These Lewis acids can form complexes with Lewis bases, such as amines or ethers, and are often used as catalysts in organic reactions

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