Laboratory Preparation of Sodium Chloride

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What is the observation when a gas jar containing hydrogen chloride gas is inverted over a jar full of ammonia gas?

Dense white fumes are formed, consisting of particles of solid ammonium chloride suspended in air.

What happens when hydrogen chloride gas reacts with metals like calcium, magnesium, zinc, and iron?

The respective metal chloride and hydrogen gas are formed, especially when heated.

What is the effect of heating hydrogen chloride gas above 500°C?

Hydrogen chloride dissociates into hydrogen and chlorine gases.

How does hydrogen chloride gas affect the color of various indicators?

<p>Hydrogen chloride gas turns litmus paper blue, methyl orange red, and phenolphthalein colorless.</p> Signup and view all the answers

Is hydrogen chloride gas combustible?

<p>No, hydrogen chloride gas is non-combustible and does not support combustion. It extinguishes a glowing splint.</p> Signup and view all the answers

What is the relationship between the solubility of hydrogen chloride gas in water and the Fountain Experiment?

<p>Hydrogen chloride gas is highly soluble in water, which is the basis for the Fountain Experiment.</p> Signup and view all the answers

What is the chemical formula for sodium bisulphate?

<p>NaHSO4</p> Signup and view all the answers

What gas is obtained during the reaction involving sodium chloride and sulphuric acid?

<p>Hydrogen chloride gas (HCl)</p> Signup and view all the answers

What is used to absorb moisture during the collection of dry hydrogen chloride gas?

<p>Concentrated sulphuric acid (H2SO4)</p> Signup and view all the answers

How is dry hydrogen chloride gas collected in the laboratory?

<p>By upward displacement of air</p> Signup and view all the answers

Why is it important for the lower end of the thistle funnel to dip below the acid in flask 'X'?

<p>To prevent the escape of HCl gas</p> Signup and view all the answers

Why is dry hydrogen chloride gas not collected over water?

<p>Highly soluble in water</p> Signup and view all the answers

What is the key observation in the simple experiment with the burning candle and dry HCl gas?

<p>The burning candle is extinguished when dry HCl gas is poured into the jar containing air, demonstrating that HCl gas is heavier than air.</p> Signup and view all the answers

What causes the blue litmus solution to rise up the jet tube in the fountain experiment?

<p>The dissolution of HCl gas in water creates a partial vacuum inside the flask, causing the higher outside air pressure to push the blue litmus solution up the jet tube.</p> Signup and view all the answers

What is the significance of using a red litmus solution in the flask for the fountain experiment?

<p>The red color indicates that the litmus solution turns red due to the high solubility of the acidic HCl gas in water.</p> Signup and view all the answers

How does the boiling point of liquid hydrogen chloride ($-83^\circ$C) compare to its melting point ($-113^\circ$C)?

<p>The boiling point of liquid hydrogen chloride ($-83^\circ$C) is higher than its melting point ($-113^\circ$C).</p> Signup and view all the answers

What property of hydrogen chloride gas is demonstrated by the red fountain emerging from the jet tube?

<p>The red fountain demonstrates the high solubility of hydrogen chloride gas in water.</p> Signup and view all the answers

Why is a dry gas jar used for the candle burning experiment with HCl gas?

<p>A dry gas jar is used to ensure there is no moisture that could dissolve the HCl gas before it displaces the air in the jar.</p> Signup and view all the answers

Based on the given information, what reaction proves that hydrogen chloride (HCl) contains hydrogen?

<p>The reaction of iron (Fe) with hydrochloric acid (HCl) to produce hydrogen gas (H₂) and iron(II) chloride (FeCl₂) proves that HCl contains hydrogen.</p> Signup and view all the answers

What is the purpose of adding ammonia solution (NH₄OH) to dilute hydrochloric acid (HCl)?

<p>Adding ammonia solution to dilute hydrochloric acid is a test to distinguish HCl from other acids, as it produces dense white fumes of ammonium chloride (NH₄Cl).</p> Signup and view all the answers

What is the purpose of adding silver nitrate (AgNO₃) solution to dilute hydrochloric acid (HCl)?

<p>Adding silver nitrate solution to dilute hydrochloric acid is a test to confirm the presence of chloride ions, as it produces a white precipitate of silver chloride (AgCl).</p> Signup and view all the answers

Adding manganese(IV) oxide to concentrated hydrochloric acid is a test to prove that HCl contains chlorine, as it produces chlorine gas (Cl₂).

<p>The text states that 'Action of conc. HCl on a mixture of MnO₂ &amp; conc. HCl proves that HCl contains chlorine [Cl₂ (g) evolved]'.</p> Signup and view all the answers

What is the purpose of adding sodium thiosulfate (Na₂S₂O₃) solution to hydrochloric acid (HCl)?

<p>Adding sodium thiosulfate solution to hydrochloric acid is a reference test to confirm the presence of HCl, as it produces sulfur dioxide gas (SO₂).</p> Signup and view all the answers

What is the purpose of adding lead(II) nitrate (Pb(NO₃)₂) solution to hydrochloric acid (HCl)?

<p>Adding lead(II) nitrate solution to hydrochloric acid is a test to confirm the presence of chloride ions, as it produces a white precipitate of lead(II) chloride (PbCl₂).</p> Signup and view all the answers

What is the drying agent used for hydrogen chloride preparation?

<p>Phosphorus pentoxide (P₂O₅) is used as the drying agent.</p> Signup and view all the answers

Why are quicklime (CaO) and respective chlorides not used as drying agents?

<p>Quicklime (CaO) and respective chlorides are not used as drying agents because they react with hydrogen chloride to form calcium chloride and water.</p> Signup and view all the answers

How is hydrogen chloride gas collected?

<p>Hydrogen chloride gas is collected by upward displacement of air, since it is denser (heavier) than air.</p> Signup and view all the answers

What is the solubility of hydrogen chloride gas in water?

<p>Hydrogen chloride gas is highly soluble in water, with 1 volume of water dissolving about 452 volumes of the gas.</p> Signup and view all the answers

Compare the relative densities of various gases with respect to air.

<p>Gases heavier than air are HCl, NH₃, SO₂, Cl₂, CO₂, and N₂O. Gases lighter than air are H₂, O₂, N₂, H₂S, and CO.</p> Signup and view all the answers

What are the physical properties of hydrogen chloride gas?

<p>Hydrogen chloride gas is colorless, has a pungent odor, causes a choking sensation if inhaled, has a vapor density of 18.25 (compared to air = 14.4), and is highly soluble in water.</p> Signup and view all the answers

Study Notes

Properties of Hydrogen Chloride (HCl)

  • HCl is a colorless gas with a pungent, choking odor
  • It is heavier than air, with a density of 18.25 (V.D. of air = 14.4)
  • Highly soluble in water, with 1 volume of water dissolving approximately 452 volumes of HCl gas
  • HCl is toxic and poisonous if inhaled, causing respiratory problems

Reactions of Hydrogen Chloride

  • With ammonia (NH3): forms a solid ammonium chloride (NH4Cl) suspended in air
  • With metals:
    • Calcium (Ca): forms calcium chloride (CaCl2) and hydrogen gas
    • Magnesium (Mg): forms magnesium chloride (MgCl2) and hydrogen gas
    • Iron (Fe): forms iron(II) chloride (FeCl2) and hydrogen gas
  • With other substances:
    • Sodium hydroxide (NaOH): forms sodium chloride (NaCl) and water
    • Sulphuric acid (H2SO4): forms sodium bisulphate (NaHSO4) and hydrogen chloride gas

Laboratory Preparation of HCl

  • By heating sodium chloride (NaCl) with concentrated sulphuric acid (H2SO4)
  • Using a round-bottom flask, washer bottle, and drying agent (e.g. conc. H2SO4) to collect the dry HCl gas

Experiments

  • Fountain experiment: demonstrates the high solubility of HCl in water
  • Combustibility experiment: shows that HCl does not burn or support combustion
  • Simple experiment: demonstrates the displacement of air by HCl gas, which is heavier than air

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