Ass #16-Lab Grown Diamonds

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Questions and Answers

What is one common indication that a trained gemologist looks for when examining a CVD lab-grown diamond?

  • Black graphitic inclusions (correct)
  • Presence of bubbles in the diamond
  • Presence of color zoning
  • High levels of fluorescence under UV

Which of the following represents a distinguishing feature of CVD lab-grown diamonds compared to HPHT diamonds?

  • More consistent color saturation
  • Presence of pronounced radial fractures
  • Higher levels of fluorescence
  • Irregular or mottled strain patterns (correct)

How do HPHT-treated CVD diamonds typically fluoresce under shortwave UV light?

  • They fluoresce bright blue.
  • They fluoresce very weak to moderate green. (correct)
  • They fluoresce bright red.
  • They show no fluorescence.

What is a primary advantage of using a microscope during the examination of diamonds?

<p>To identify growth interruptions. (D)</p> Signup and view all the answers

What change did the FTC implement in August 2018 regarding the diamond industry?

<p>Amendments to the Guides for the Jewelry Industry. (C)</p> Signup and view all the answers

During the process of distinguishing lab-grown diamonds, which procedure is crucial for checking fluorescence?

<p>UV radiation examination (C)</p> Signup and view all the answers

Which of the following is true regarding the growth of CVD diamonds?

<p>CVD diamonds are formed without the stabilization of high pressures. (A)</p> Signup and view all the answers

What is one of the functions of the DiamondView in gemology?

<p>To identify inclusions and growth features. (B)</p> Signup and view all the answers

What primarily causes the yellow color in type Ib HPHT lab-grown diamonds?

<p>Incorporation of isolated nitrogen in the crystal lattice (D)</p> Signup and view all the answers

Which element is NOT typically used as a nitrogen getter in the synthesis of colorless HPHT diamonds?

<p>Boron (A)</p> Signup and view all the answers

What is a common feature that gemologists examine to identify HPHT diamonds?

<p>Fluorescence under UV radiation (D)</p> Signup and view all the answers

What type of graining pattern is characteristic of HPHT diamonds?

<p>Cuboctahedral graining (C)</p> Signup and view all the answers

Which inclusions might indicate that a diamond is HPHT lab-grown?

<p>Surface-reaching feathers and chips (A)</p> Signup and view all the answers

Which type of HPHT diamond is considered the rarest in nature?

<p>Type Ib (C)</p> Signup and view all the answers

What aspect of HPHT diamonds contributes to their identification during microscopic examination?

<p>Metallic inclusions from the growth process (C)</p> Signup and view all the answers

What must be removed from the chamber for producing colorless HPHT diamonds?

<p>Nitrogen-containing air bubbles (D)</p> Signup and view all the answers

What mechanism primarily determines the growth patterns observed in HPHT diamonds?

<p>Cuboctahedral arrangement of internal growth sectors (C)</p> Signup and view all the answers

What is the challenge associated with growing colorless HPHT diamonds?

<p>High purity components and nitrogen removal are required (C)</p> Signup and view all the answers

Which components are essential for the CVD diamond synthesis process?

<p>Gaseous carbon source, substrate, energy source, and heating element (D)</p> Signup and view all the answers

What is the main effect of adding low concentrations of nitrogen or oxygen to the gas mixture during CVD diamond growth?

<p>It accelerates the diamond growth process (A)</p> Signup and view all the answers

What type of diamonds are the majority of CVD lab-grown diamonds classified as?

<p>Type IIa (A)</p> Signup and view all the answers

What distinguishes polycrystalline diamonds formed in CVD environments?

<p>They consist of many small interlocking diamond crystals (B)</p> Signup and view all the answers

Why are most CVD lab-grown diamonds unable to be identified using standard gem-testing equipment?

<p>They mimic natural diamonds too closely (B)</p> Signup and view all the answers

What is the primary method developed for producing diamonds that involves simulating natural conditions?

<p>High-Pressure, High-Temperature (HPHT) (A)</p> Signup and view all the answers

Which method was first successful in producing tiny diamonds before advancements were made in creating larger gems?

<p>Chemical Vapor Deposition (CVD) (D)</p> Signup and view all the answers

What significant advancement in diamond synthesis occurred in 1970?

<p>Production of the first cuttable gem-quality HPHT lab-grown diamonds (B)</p> Signup and view all the answers

What was the weight of the largest reported HPHT lab-grown diamond crystal reported in 1993?

<p>34.80 carats (B)</p> Signup and view all the answers

Which company was instrumental in creating the first batch of industrial diamonds using the HPHT method in the 1950s?

<p>General Electric Corporation (GE) (A)</p> Signup and view all the answers

What color range was produced by the early HPHT diamonds created in 1970?

<p>F - J in color (B)</p> Signup and view all the answers

What aspect of diamond growth did William G. Eversole contribute to in 1952?

<p>Production of tiny diamonds using CVD (A)</p> Signup and view all the answers

When did the jewelry industry start to accept lab-grown diamonds as a commercial product?

<p>2003 (B)</p> Signup and view all the answers

Why were early attempts at creating gem-quality diamonds limited?

<p>Technological limitations in producing larger crystals (D)</p> Signup and view all the answers

Which of the following colors did NOT appear in the HPHT diamonds produced by 2003?

<p>Red (D)</p> Signup and view all the answers

What is the main characteristic of CVD lab-grown diamonds compared to HPHT lab-grown diamonds?

<p>CVD diamonds require a lower probability of formation. (D)</p> Signup and view all the answers

What phenomenon is observed by using crossed polarizers on a diamond?

<p>Visible strain patterns indicating stress. (B)</p> Signup and view all the answers

Which type of fluorescence is most commonly observed in HPHT diamonds under shortwave UV?

<p>Greenish yellow to yellow fluorescence. (B)</p> Signup and view all the answers

What are bright interference colors in diamonds indicative of?

<p>Heavy strain within the diamond. (C)</p> Signup and view all the answers

What is the role of the second polarizer when examining a diamond for strain?

<p>To rotate and create a dark position. (C)</p> Signup and view all the answers

What characteristic differentiates HPHT diamonds from CVD diamonds in terms of luminescence?

<p>HPHT diamonds have subdued interference colors. (C)</p> Signup and view all the answers

In terms of stability, why are diamonds produced through CVD growth considered metastable?

<p>They can theoretically transform but remain stable over time. (B)</p> Signup and view all the answers

How does high pressure and temperature affect HPHT diamonds compared to CVD diamonds?

<p>HPHT diamonds are formed under conditions similar to natural diamonds. (C)</p> Signup and view all the answers

What type of colors can be observed in HPHT diamonds under cross-polarized light?

<p>Subdued colors such as white, gray, or black. (A)</p> Signup and view all the answers

What causes phosphorescence in specific HPHT diamonds?

<p>The incorporation of boron within the diamond. (A)</p> Signup and view all the answers

What shape can metallic inclusions take in HPHT diamond?

<p>rounded, elongated, or irregularly shaped (B)</p> Signup and view all the answers

Flashcards

CVD Lab-Grown Diamonds

Diamonds grown in a laboratory using Chemical Vapor Deposition (CVD) method.

HPHT Lab-Grown Diamonds

Diamonds grown in a laboratory using High Pressure/High Temperature (HPHT) method.

Microscope Examination

A gemological technique used to observe inclusions and other characteristics of a diamond under a microscope.

Strain in Diamonds

Distortion or stress in the diamond's crystal structure, observable as interference colors.

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Fluorescence in Diamonds

Diamonds emitting light when exposed to UV radiation.

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DiamondView

Device used for identifying growth sectors and interruptions in CVD diamonds using fluorescence.

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Lab-Grown Diamond Value Chain

The process from diamond growth to retail sale, similar to mined diamonds.

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FTC Guides for Jewelry Industry

U.S. Federal Trade Commission guidelines for jewelry marketing practices.

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Type Ib diamonds

Lab-grown diamonds containing isolated nitrogen, appearing yellow.

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Type IIa diamonds

Colorless lab-grown diamonds, with very pure components.

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Nitrogen getters

Elements (like aluminum and titanium) that trap nitrogen and produce colorless diamonds.

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Cuboctahedral arrangement

A specific internal growth pattern in HPHT diamonds, related to their crystal structure.

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Fluorescence under UV radiation

Observing diamonds' response to ultraviolet light. Some diamonds fluoresce.

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Graining pattern

Distinctive growth patterns in colored lab-grown diamonds. Visible under magnification.

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Metallic inclusions

Inclusions of metal from the growth process visible in lab-grown diamonds.

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CVD Diamond Growth

CVD diamonds are grown in a laboratory by depositing carbon atoms layer by layer onto a substrate in a heated vacuum chamber. Gases like methane and hydrogen are used as the carbon source, and a microwave plasma provides energy to break down the gas molecules.

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CVD Diamond Substrate

A substrate, typically a pre-existing diamond crystal, serves as a base for new diamond growth in the CVD process. This substrate can be natural or lab-grown.

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CVD Diamond Color

CVD diamonds are mainly type IIa, often colorless or near-colorless. Adding nitrogen or oxygen to the gas mixture can speed up growth but may result in a brown color.

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CVD Diamond Crystal Shape

CVD lab-grown diamonds often resemble slabs with a square cross-section. The edges are initially covered in black graphite and require polishing to achieve a desired shape.

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CVD Diamond Identification

CVD lab-grown diamonds can be difficult to identify using standard gem-testing equipment. They typically require specialized laboratory testing for confirmation.

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Polarizer

A plastic disk with microscopic crystals that transmit polarized light, used for observing strain in diamonds.

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Crossed Polarizers

Two polarizers placed perpendicularly, blocking all light unless strain is present in the diamond.

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Interference Colors

Bright colors that appear under crossed polarizers due to strain in diamonds, ranging from red, pink, orange, yellow to green.

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HPHT diamonds and Strain

High-pressure/high-temperature lab-grown diamonds typically show subdued interference colors, indicating less strain.

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UV Luminescence

The ability of a diamond to emit light when exposed to ultraviolet radiation.

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Phosphorescence

The ability of a diamond to continue emitting light after the UV source is removed.

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CVD vs. HPHT

CVD diamonds form under less favorable conditions than HPHT diamonds, requiring more energy to break atomic bonds.

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Metastable Diamond

Diamonds are considered stable, although theoretically unstable, due to their longevity.

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Graphite and Diamond

Diamonds are the metastable form of carbon, while graphite is the stable form.

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Smithson Tennant's Discovery

In 1797, English chemist Smithson Tennant proved that diamonds are composed of pure, dense carbon.

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Early Diamond Synthesis Attempts

In the 1800s and early 1900s, researchers tried to create diamonds but lacked the technology to succeed.

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Percy Bridgman's Contribution

In 1941, Percy Bridgman, an American researcher, was hired by GE to advance high-pressure technology for diamond synthesis, though diamonds weren't made yet.

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William Eversole and the CVD Method

In 1952, William Eversole made tiny diamonds using the Chemical Vapor Deposition (CVD) method, a different approach to diamond growth.

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GE's First HPHT Diamonds

In December 1954, GE scientists created the first batch of industrial diamonds using the High-Pressure/High-Temperature (HPHT) method. They announced their achievement in 1955.

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First Cuttable Gem-Quality Diamonds

In 1970, GE produced the first cuttable gem-quality HPHT lab-grown diamonds, weighing about 1 carat each in rough form.

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HPHT Diamond Marketing

During the 1990s, Sumitomo Electric Industries, GE, and De Beers produced larger, near-colorless HPHT diamonds for high-tech applications and experimental use.

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Largest HPHT Lab-Grown Diamond Crystal

In 1993, a 34.80-carat HPHT lab-grown diamond crystal was produced, taking 600 hours to grow.

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Lab-Grown Diamonds in Jewelry

By 2003, the jewelry industry began accepting lab-grown diamonds as a commercial product, with HPHT diamonds of various colors being produced.

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CVD Gem-Quality Diamonds for Jewelry

In 2003, gem-quality lab-grown diamonds were produced for jewelry using the CVD method.

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Study Notes

Lab Grown Diamonds

  • Two main methods for commercial lab-grown diamonds: High-Pressure, High-Temperature (HPHT) and Chemical Vapor Deposition (CVD).
  • Early research: focused on industrial diamonds.
  • 1797: English chemist Tennant proved diamond is pure carbon.
  • 1800s-1900s: Researchers struggled to create diamonds; lacked suitable technology.
  • 1941: Bridgman (American researcher) joined GE for high-pressure physics research.
  • 1952: Scientists experimented with the CVD method.
  • 1954: GE created initial industrial diamonds using HPHT.
  • 1955: GE announced HPHT achievement.
  • 1970: First cuttable gem-quality HPHT diamonds created (1-carat).
  • 1990s: Japan (Sumitomo), GE, and De Beers produced larger, near-colorless HPHT diamonds.
  • 1993: Largest HPHT crystal (34.8 ct.) produced.
  • 2003: Jewelry industry started accepting lab-grown diamonds commercially; various colors (yellow, blue, green, pink).
  • 2003: CVD method for gem-quality diamonds; predominantly brown, smaller due to limited thickness.
  • 2007: Wide range of CVD colors (colorless-near-colorless, orange, pink, brown)
  • 2014: Russian company NDT produced large colorless, faceted HPHT diamonds (> 5.11 ct).
  • 2015: NDT made a 10.02-ct. colorless, VS-clarity faceted HPHT diamond from a 32.26-ct rough.
  • 2018: US FTC amends Guides for Jewelry industry.
  • 2019: CIBJO creates Lab-Grown Diamond Committee.
  • 2018: US FTC amends Publications.
  • 2018: US FTC Guidance.
  • 2018: U.S. Federal Trade Commission publication revised

Industrial Applications

  • Tools and equipment embedded with lab-grown diamonds for various uses: machining car components, cutting natural hardwoods, granite, and marble; as drill bits, machining tools, and saws; used for engraving on glassware; fine surgical procedures.

HPHT Synthesis

  • Mimics the earth's natural diamond creation process (high temp & pressure).
  • Uses carbon source (graphite or diamond powder) converted into diamond under high pressure (5-6 GPa).
  • Temperatures range from 1300-1600°C.
  • Diamond growth time varies from days to weeks, dependent on size goal.
  • Metal catalyst (iron, nickel, cobalt, titanium, etc.) used to reduce temperatures and pressures for faster growth.
  • Various press designs exist (cubic, BARS, toroid) with differences in anvil numbers and sizes affecting pressure capacity and the size of the resulting diamond.

CVD Synthesis

  • Growth at lower pressure and temperatures compared to HPHT
  • Metastable conditions - diamond theoretically unstable but stable over time
  • Uses a hydrocarbon gas (methane), hydrogen gas, substrate, energy source & a heating element.
  • Growth within a vacuum chamber using a substrate (natural or lab-grown) as a template.
  • Gas molecules broken down into carbon atoms via an energy source (microwave plasma).
  • CVD diamonds form in layers (terrace/riser growth), creating a polycrystalline appearance if not treated.

Diamond Types (HPHT & CVD)

  • Type IIa diamonds are most common; colorless-near colorless are difficult to achieve
  • Color zoning, strain patterns, impurities, growth sectors (cuboctahedral) used for identification.
  • Natural diamonds also have imperfections, but they tend to have different patterns and distributions.
  • Lab crystals sometimes have strain that results in interference colors; natural diamonds exhibit very clear patterns under these special conditions.

Diamond Identification

  • Standard gem-testing equipment might not identify lab-grown diamonds.
  • Skilled gemologists use microscopes, UV radiation, and strain observation techniques.
  • Characteristics like inclusions, fluorescence, and graining assist in assessing type and origin.
  • GIA provides synthetic diamond grading reports.

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