Podcast
Questions and Answers
What is one common indication that a trained gemologist looks for when examining a CVD lab-grown diamond?
What is one common indication that a trained gemologist looks for when examining a CVD lab-grown diamond?
- Black graphitic inclusions (correct)
- Presence of bubbles in the diamond
- Presence of color zoning
- High levels of fluorescence under UV
Which of the following represents a distinguishing feature of CVD lab-grown diamonds compared to HPHT diamonds?
Which of the following represents a distinguishing feature of CVD lab-grown diamonds compared to HPHT diamonds?
- More consistent color saturation
- Presence of pronounced radial fractures
- Higher levels of fluorescence
- Irregular or mottled strain patterns (correct)
How do HPHT-treated CVD diamonds typically fluoresce under shortwave UV light?
How do HPHT-treated CVD diamonds typically fluoresce under shortwave UV light?
- They fluoresce bright blue.
- They fluoresce very weak to moderate green. (correct)
- They fluoresce bright red.
- They show no fluorescence.
What is a primary advantage of using a microscope during the examination of diamonds?
What is a primary advantage of using a microscope during the examination of diamonds?
What change did the FTC implement in August 2018 regarding the diamond industry?
What change did the FTC implement in August 2018 regarding the diamond industry?
During the process of distinguishing lab-grown diamonds, which procedure is crucial for checking fluorescence?
During the process of distinguishing lab-grown diamonds, which procedure is crucial for checking fluorescence?
Which of the following is true regarding the growth of CVD diamonds?
Which of the following is true regarding the growth of CVD diamonds?
What is one of the functions of the DiamondView in gemology?
What is one of the functions of the DiamondView in gemology?
What primarily causes the yellow color in type Ib HPHT lab-grown diamonds?
What primarily causes the yellow color in type Ib HPHT lab-grown diamonds?
Which element is NOT typically used as a nitrogen getter in the synthesis of colorless HPHT diamonds?
Which element is NOT typically used as a nitrogen getter in the synthesis of colorless HPHT diamonds?
What is a common feature that gemologists examine to identify HPHT diamonds?
What is a common feature that gemologists examine to identify HPHT diamonds?
What type of graining pattern is characteristic of HPHT diamonds?
What type of graining pattern is characteristic of HPHT diamonds?
Which inclusions might indicate that a diamond is HPHT lab-grown?
Which inclusions might indicate that a diamond is HPHT lab-grown?
Which type of HPHT diamond is considered the rarest in nature?
Which type of HPHT diamond is considered the rarest in nature?
What aspect of HPHT diamonds contributes to their identification during microscopic examination?
What aspect of HPHT diamonds contributes to their identification during microscopic examination?
What must be removed from the chamber for producing colorless HPHT diamonds?
What must be removed from the chamber for producing colorless HPHT diamonds?
What mechanism primarily determines the growth patterns observed in HPHT diamonds?
What mechanism primarily determines the growth patterns observed in HPHT diamonds?
What is the challenge associated with growing colorless HPHT diamonds?
What is the challenge associated with growing colorless HPHT diamonds?
Which components are essential for the CVD diamond synthesis process?
Which components are essential for the CVD diamond synthesis process?
What is the main effect of adding low concentrations of nitrogen or oxygen to the gas mixture during CVD diamond growth?
What is the main effect of adding low concentrations of nitrogen or oxygen to the gas mixture during CVD diamond growth?
What type of diamonds are the majority of CVD lab-grown diamonds classified as?
What type of diamonds are the majority of CVD lab-grown diamonds classified as?
What distinguishes polycrystalline diamonds formed in CVD environments?
What distinguishes polycrystalline diamonds formed in CVD environments?
Why are most CVD lab-grown diamonds unable to be identified using standard gem-testing equipment?
Why are most CVD lab-grown diamonds unable to be identified using standard gem-testing equipment?
What is the primary method developed for producing diamonds that involves simulating natural conditions?
What is the primary method developed for producing diamonds that involves simulating natural conditions?
Which method was first successful in producing tiny diamonds before advancements were made in creating larger gems?
Which method was first successful in producing tiny diamonds before advancements were made in creating larger gems?
What significant advancement in diamond synthesis occurred in 1970?
What significant advancement in diamond synthesis occurred in 1970?
What was the weight of the largest reported HPHT lab-grown diamond crystal reported in 1993?
What was the weight of the largest reported HPHT lab-grown diamond crystal reported in 1993?
Which company was instrumental in creating the first batch of industrial diamonds using the HPHT method in the 1950s?
Which company was instrumental in creating the first batch of industrial diamonds using the HPHT method in the 1950s?
What color range was produced by the early HPHT diamonds created in 1970?
What color range was produced by the early HPHT diamonds created in 1970?
What aspect of diamond growth did William G. Eversole contribute to in 1952?
What aspect of diamond growth did William G. Eversole contribute to in 1952?
When did the jewelry industry start to accept lab-grown diamonds as a commercial product?
When did the jewelry industry start to accept lab-grown diamonds as a commercial product?
Why were early attempts at creating gem-quality diamonds limited?
Why were early attempts at creating gem-quality diamonds limited?
Which of the following colors did NOT appear in the HPHT diamonds produced by 2003?
Which of the following colors did NOT appear in the HPHT diamonds produced by 2003?
What is the main characteristic of CVD lab-grown diamonds compared to HPHT lab-grown diamonds?
What is the main characteristic of CVD lab-grown diamonds compared to HPHT lab-grown diamonds?
What phenomenon is observed by using crossed polarizers on a diamond?
What phenomenon is observed by using crossed polarizers on a diamond?
Which type of fluorescence is most commonly observed in HPHT diamonds under shortwave UV?
Which type of fluorescence is most commonly observed in HPHT diamonds under shortwave UV?
What are bright interference colors in diamonds indicative of?
What are bright interference colors in diamonds indicative of?
What is the role of the second polarizer when examining a diamond for strain?
What is the role of the second polarizer when examining a diamond for strain?
What characteristic differentiates HPHT diamonds from CVD diamonds in terms of luminescence?
What characteristic differentiates HPHT diamonds from CVD diamonds in terms of luminescence?
In terms of stability, why are diamonds produced through CVD growth considered metastable?
In terms of stability, why are diamonds produced through CVD growth considered metastable?
How does high pressure and temperature affect HPHT diamonds compared to CVD diamonds?
How does high pressure and temperature affect HPHT diamonds compared to CVD diamonds?
What type of colors can be observed in HPHT diamonds under cross-polarized light?
What type of colors can be observed in HPHT diamonds under cross-polarized light?
What causes phosphorescence in specific HPHT diamonds?
What causes phosphorescence in specific HPHT diamonds?
What shape can metallic inclusions take in HPHT diamond?
What shape can metallic inclusions take in HPHT diamond?
Flashcards
CVD Lab-Grown Diamonds
CVD Lab-Grown Diamonds
Diamonds grown in a laboratory using Chemical Vapor Deposition (CVD) method.
HPHT Lab-Grown Diamonds
HPHT Lab-Grown Diamonds
Diamonds grown in a laboratory using High Pressure/High Temperature (HPHT) method.
Microscope Examination
Microscope Examination
A gemological technique used to observe inclusions and other characteristics of a diamond under a microscope.
Strain in Diamonds
Strain in Diamonds
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Fluorescence in Diamonds
Fluorescence in Diamonds
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DiamondView
DiamondView
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Lab-Grown Diamond Value Chain
Lab-Grown Diamond Value Chain
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FTC Guides for Jewelry Industry
FTC Guides for Jewelry Industry
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Type Ib diamonds
Type Ib diamonds
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Type IIa diamonds
Type IIa diamonds
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Nitrogen getters
Nitrogen getters
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Cuboctahedral arrangement
Cuboctahedral arrangement
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Fluorescence under UV radiation
Fluorescence under UV radiation
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Graining pattern
Graining pattern
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Metallic inclusions
Metallic inclusions
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CVD Diamond Growth
CVD Diamond Growth
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CVD Diamond Substrate
CVD Diamond Substrate
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CVD Diamond Color
CVD Diamond Color
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CVD Diamond Crystal Shape
CVD Diamond Crystal Shape
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CVD Diamond Identification
CVD Diamond Identification
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Polarizer
Polarizer
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Crossed Polarizers
Crossed Polarizers
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Interference Colors
Interference Colors
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HPHT diamonds and Strain
HPHT diamonds and Strain
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UV Luminescence
UV Luminescence
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Phosphorescence
Phosphorescence
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CVD vs. HPHT
CVD vs. HPHT
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Metastable Diamond
Metastable Diamond
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Graphite and Diamond
Graphite and Diamond
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Smithson Tennant's Discovery
Smithson Tennant's Discovery
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Early Diamond Synthesis Attempts
Early Diamond Synthesis Attempts
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Percy Bridgman's Contribution
Percy Bridgman's Contribution
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William Eversole and the CVD Method
William Eversole and the CVD Method
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GE's First HPHT Diamonds
GE's First HPHT Diamonds
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First Cuttable Gem-Quality Diamonds
First Cuttable Gem-Quality Diamonds
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HPHT Diamond Marketing
HPHT Diamond Marketing
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Largest HPHT Lab-Grown Diamond Crystal
Largest HPHT Lab-Grown Diamond Crystal
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Lab-Grown Diamonds in Jewelry
Lab-Grown Diamonds in Jewelry
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CVD Gem-Quality Diamonds for Jewelry
CVD Gem-Quality Diamonds for Jewelry
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Study Notes
Lab Grown Diamonds
- Two main methods for commercial lab-grown diamonds: High-Pressure, High-Temperature (HPHT) and Chemical Vapor Deposition (CVD).
- Early research: focused on industrial diamonds.
- 1797: English chemist Tennant proved diamond is pure carbon.
- 1800s-1900s: Researchers struggled to create diamonds; lacked suitable technology.
- 1941: Bridgman (American researcher) joined GE for high-pressure physics research.
- 1952: Scientists experimented with the CVD method.
- 1954: GE created initial industrial diamonds using HPHT.
- 1955: GE announced HPHT achievement.
- 1970: First cuttable gem-quality HPHT diamonds created (1-carat).
- 1990s: Japan (Sumitomo), GE, and De Beers produced larger, near-colorless HPHT diamonds.
- 1993: Largest HPHT crystal (34.8 ct.) produced.
- 2003: Jewelry industry started accepting lab-grown diamonds commercially; various colors (yellow, blue, green, pink).
- 2003: CVD method for gem-quality diamonds; predominantly brown, smaller due to limited thickness.
- 2007: Wide range of CVD colors (colorless-near-colorless, orange, pink, brown)
- 2014: Russian company NDT produced large colorless, faceted HPHT diamonds (> 5.11 ct).
- 2015: NDT made a 10.02-ct. colorless, VS-clarity faceted HPHT diamond from a 32.26-ct rough.
- 2018: US FTC amends Guides for Jewelry industry.
- 2019: CIBJO creates Lab-Grown Diamond Committee.
- 2018: US FTC amends Publications.
- 2018: US FTC Guidance.
- 2018: U.S. Federal Trade Commission publication revised
Industrial Applications
- Tools and equipment embedded with lab-grown diamonds for various uses: machining car components, cutting natural hardwoods, granite, and marble; as drill bits, machining tools, and saws; used for engraving on glassware; fine surgical procedures.
HPHT Synthesis
- Mimics the earth's natural diamond creation process (high temp & pressure).
- Uses carbon source (graphite or diamond powder) converted into diamond under high pressure (5-6 GPa).
- Temperatures range from 1300-1600°C.
- Diamond growth time varies from days to weeks, dependent on size goal.
- Metal catalyst (iron, nickel, cobalt, titanium, etc.) used to reduce temperatures and pressures for faster growth.
- Various press designs exist (cubic, BARS, toroid) with differences in anvil numbers and sizes affecting pressure capacity and the size of the resulting diamond.
CVD Synthesis
- Growth at lower pressure and temperatures compared to HPHT
- Metastable conditions - diamond theoretically unstable but stable over time
- Uses a hydrocarbon gas (methane), hydrogen gas, substrate, energy source & a heating element.
- Growth within a vacuum chamber using a substrate (natural or lab-grown) as a template.
- Gas molecules broken down into carbon atoms via an energy source (microwave plasma).
- CVD diamonds form in layers (terrace/riser growth), creating a polycrystalline appearance if not treated.
Diamond Types (HPHT & CVD)
- Type IIa diamonds are most common; colorless-near colorless are difficult to achieve
- Color zoning, strain patterns, impurities, growth sectors (cuboctahedral) used for identification.
- Natural diamonds also have imperfections, but they tend to have different patterns and distributions.
- Lab crystals sometimes have strain that results in interference colors; natural diamonds exhibit very clear patterns under these special conditions.
Diamond Identification
- Standard gem-testing equipment might not identify lab-grown diamonds.
- Skilled gemologists use microscopes, UV radiation, and strain observation techniques.
- Characteristics like inclusions, fluorescence, and graining assist in assessing type and origin.
- GIA provides synthetic diamond grading reports.
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