Kinetic Particle Theory Quiz
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Questions and Answers

Which statement correctly describes the arrangement of particles in solids?

  • Particles are closely packed and vibrate in fixed positions. (correct)
  • Particles are loosely packed and flow over each other.
  • Particles are far apart and move freely.
  • Particles are spread out and have high kinetic energy.
  • What happens to the particles of a substance when it transitions from a liquid to a gas?

  • Particles start to combine into larger clusters.
  • Particles lose energy and get closer together.
  • Particles gain energy and move freely apart. (correct)
  • Particles remain in a fixed position with no motion change.
  • How does increasing temperature affect the volume of a gas, according to kinetic particle theory?

  • Volume remains constant regardless of temperature changes.
  • Volume is unaffected by particle movement.
  • Volume increases because particles move faster and collide more forcefully. (correct)
  • Volume decreases as temperature increases.
  • Which effect does relative molecular mass have on the rate of diffusion of gases?

    <p>Lighter gases diffuse faster than heavier gases. (A)</p> Signup and view all the answers

    What describes the process of condensation in terms of kinetic particle theory?

    <p>Particles lose energy and come closer together. (B)</p> Signup and view all the answers

    Which of the following correctly describes an ionic bond?

    <p>A strong attraction between oppositely charged ions (D)</p> Signup and view all the answers

    What defines isotopes of an element?

    <p>Atoms with the same number of protons but different numbers of neutrons (C)</p> Signup and view all the answers

    Which statement about the atomic structure is correct?

    <p>Electrons are found in shells around the nucleus (C)</p> Signup and view all the answers

    What characteristic is true for Group VIII noble gases?

    <p>They have a full outer electron shell (C)</p> Signup and view all the answers

    How can the electronic configuration of an element with an atomic number of 12 be represented?

    <p>2,8,2 (B)</p> Signup and view all the answers

    Which of the following describes a covalent bond?

    <p>Formed by the sharing of a pair of electrons (A)</p> Signup and view all the answers

    What is the meaning of mass number in an atom?

    <p>The total number of protons and neutrons (A)</p> Signup and view all the answers

    Which property is typical of ionic compounds?

    <p>They form regular lattices (C)</p> Signup and view all the answers

    What happens to the properties of elements as you move from left to right across a period in the Periodic Table?

    <p>Electronegativity typically increases (A)</p> Signup and view all the answers

    What is the definition of oxidation in terms of electron transfer?

    <p>Loss of electrons (D)</p> Signup and view all the answers

    Which of the following statements is true about reducing agents?

    <p>They are oxidized when they reduce another substance. (B)</p> Signup and view all the answers

    How can a redox reaction be identified?

    <p>By simultaneous oxidation and reduction (C)</p> Signup and view all the answers

    What occurs during the neutralization reaction between an acid and an alkali?

    <p>Water is produced along with salt. (B)</p> Signup and view all the answers

    Which oxide is classified as amphoteric?

    <p>Al2O3 (B)</p> Signup and view all the answers

    In which of the following scenarios does an acid act as a proton donor?

    <p>When it reacts with a base. (C)</p> Signup and view all the answers

    What is the oxidation state of elements in their uncombined state?

    <p>Zero (D)</p> Signup and view all the answers

    How does the pH level relate to the concentration of hydrogen ions in a solution?

    <p>Lower pH means higher concentration of H+ ions. (B)</p> Signup and view all the answers

    Which of the following statements is correct about acids and their effect on litmus?

    <p>Acids turn litmus paper red. (A)</p> Signup and view all the answers

    Which of the following salts is insoluble according to general solubility rules?

    <p>Lead(II) chloride (C)</p> Signup and view all the answers

    What trend is observed in the alkali metals as you move down Group I?

    <p>Increasing reactivity (A)</p> Signup and view all the answers

    Which statement best explains why noble gases are considered unreactive?

    <p>They have a full external electron shell. (B)</p> Signup and view all the answers

    How does the electrical conductivity of metals generally compare to that of non-metals?

    <p>Metals are more conductive than non-metals. (B)</p> Signup and view all the answers

    What characteristic do transition metals commonly exhibit?

    <p>They form coloured compounds. (B)</p> Signup and view all the answers

    Which of the following statements about Group VII halogens is true?

    <p>They exist as diatomic molecules. (C)</p> Signup and view all the answers

    What is a primary reason that alloys are often stronger than pure metals?

    <p>The different sized atoms prevent layers from sliding. (A)</p> Signup and view all the answers

    How does the melting point of alkali metals change as you move down Group I?

    <p>It decreases. (B)</p> Signup and view all the answers

    What is the likely appearance of bromine at room temperature?

    <p>Red-brown liquid (D)</p> Signup and view all the answers

    What is one reason for the use of copper in electrical wiring?

    <p>It has good electrical conductivity and ductility. (C)</p> Signup and view all the answers

    Which property is NOT characteristic of transition elements?

    <p>Low densities (D)</p> Signup and view all the answers

    What is the expected observation when testing for ammonia (NH3) using damp red litmus paper?

    <p>The paper turns blue (A)</p> Signup and view all the answers

    Which gas is identified by its reaction with limewater, resulting in a color change due to the formation of calcium carbonate?

    <p>Carbon dioxide (CO2) (C)</p> Signup and view all the answers

    In a flame test, which color is expected when testing for lithium ions (Li+)?

    <p>Crimson red (C)</p> Signup and view all the answers

    Which of the following tests would confirm the presence of hydrogen gas (H2)?

    <p>Using a lighted splint that produces a 'pop' sound (D)</p> Signup and view all the answers

    Which cation is identified by a green flame in the flame test?

    <p>Copper(II) (Cu2+) (A)</p> Signup and view all the answers

    What is the correct order of reactivity in the reactivity series from most reactive to least reactive?

    <p>potassium, sodium, calcium, magnesium (D)</p> Signup and view all the answers

    What is the enthalpy change, ∆H, for an exothermic reaction?

    <p>Negative (D)</p> Signup and view all the answers

    What reaction occurs when magnesium reacts with steam?

    <p>It forms magnesium oxide and water vapor. (A)</p> Signup and view all the answers

    What prevents rusting of iron using a barrier method?

    <p>Covering with plastic paint (C)</p> Signup and view all the answers

    Which of the following processes is endothermic?

    <p>Dissolving NaCl in water (A)</p> Signup and view all the answers

    What does activation energy, Ea, represent?

    <p>Minimum energy for reactants to collide (A)</p> Signup and view all the answers

    What is the purpose of using cryolite in the extraction of aluminium?

    <p>It lowers the melting point of aluminium oxide. (A)</p> Signup and view all the answers

    Which of the following statements describes sacrificial protection?

    <p>Connecting a metal to a more reactive metal to protect it. (C)</p> Signup and view all the answers

    Bond breaking is best described as which type of process?

    <p>Endothermic (A)</p> Signup and view all the answers

    Which method is NOT used to treat domestic water supplies?

    <p>Boiling to remove all contaminants (B)</p> Signup and view all the answers

    Which factor does NOT affect the rate of reaction according to collision theory?

    <p>Color of reactants (D)</p> Signup and view all the answers

    What is the primary function of using carbon in water treatment?

    <p>To remove offensive tastes and odours (D)</p> Signup and view all the answers

    In a reversible reaction at equilibrium, what condition must be true?

    <p>The rate of the forward reaction equals the rate of the reverse reaction (B)</p> Signup and view all the answers

    What effect does adding a catalyst have on a reaction?

    <p>Decreases the activation energy (B)</p> Signup and view all the answers

    Which of the following metals is the most likely to react with dilute hydrochloric acid?

    <p>Iron (A)</p> Signup and view all the answers

    How does increasing temperature generally affect reaction rates?

    <p>It increases the frequency of particle collisions (B)</p> Signup and view all the answers

    What is the primary constituent of rust formed from the reaction of iron with oxygen?

    <p>Iron(III) oxide (C)</p> Signup and view all the answers

    Which substance is beneficial for aquatic life found in natural water sources?

    <p>Dissolved oxygen (D)</p> Signup and view all the answers

    Which equation represents the production of ammonia in the Haber process?

    <p>N2(g) + 3H2(g) ⇌ 2NH3(g) (D)</p> Signup and view all the answers

    What is true about the conditions used in the Contact process for sulfur trioxide production?

    <p>450 °C and 200 kPa are commonly used (D)</p> Signup and view all the answers

    What happens to the enthalpy change in a reaction where bond breaking occurs?

    <p>It increases (D)</p> Signup and view all the answers

    Which statement about physical and chemical changes is correct?

    <p>Chemical changes involve the formation of new substances, while physical changes do not (D)</p> Signup and view all the answers

    In the context of a reversible reaction, how does changing pressure influence equilibrium?

    <p>It shifts the equilibrium toward the side with fewer moles of gas (B)</p> Signup and view all the answers

    Which of the following is NOT a factor that affects the collision theory?

    <p>Color of the reactants (D)</p> Signup and view all the answers

    What is the main component of natural gas?

    <p>Methane (A)</p> Signup and view all the answers

    What describes the bonding in alkenes?

    <p>Double carbon-carbon covalent bonds (C)</p> Signup and view all the answers

    Which fraction from petroleum is primarily used as jet fuel?

    <p>Kerosene (C)</p> Signup and view all the answers

    What occurs during the fractional distillation of petroleum?

    <p>Separation into useful fractions based on boiling points (B)</p> Signup and view all the answers

    Which of the following describes the properties of alkanes?

    <p>Generally unreactive except during combustion (B)</p> Signup and view all the answers

    What is produced from the reaction of a carboxylic acid with an alcohol?

    <p>Ester (B)</p> Signup and view all the answers

    Which process utilizes yeast to manufacture ethanol?

    <p>Fermentation of aqueous glucose (A)</p> Signup and view all the answers

    What characterizes metallic bonding?

    <p>Electrostatic attraction between positive ions and delocalised electrons (D)</p> Signup and view all the answers

    In the context of hydrocarbons, what are saturated hydrocarbons characterized by?

    <p>Only single covalent bonds (D)</p> Signup and view all the answers

    What is the primary use of the lubricating oil fraction obtained from petroleum?

    <p>Lubricants and waxes (D)</p> Signup and view all the answers

    Which property arises due to the structure of metals?

    <p>Malleability and ductility (C)</p> Signup and view all the answers

    How is the empirical formula of a compound defined?

    <p>The simplest whole number ratio of different atoms or ions (A)</p> Signup and view all the answers

    What distinguishes alkenes from alkanes in terms of their reaction characteristics?

    <p>Alkenes are more reactive due to the presence of a double bond (B)</p> Signup and view all the answers

    What does relative atomic mass, Ar, compare?

    <p>Average mass of isotopes to 1/12th of a carbon-12 atom (D)</p> Signup and view all the answers

    What is the Avogadro constant?

    <p>6.02 x 10^23 particles per mole (D)</p> Signup and view all the answers

    What describes electrolysis?

    <p>Decomposition of an ionic compound by electric current (D)</p> Signup and view all the answers

    During electrolysis, which product is typically formed at the anode?

    <p>Non-metal elements (C)</p> Signup and view all the answers

    Which of the following is true about a hydrogen–oxygen fuel cell?

    <p>It generates electricity with water as the only product (A)</p> Signup and view all the answers

    What is meant by the term 'molar gas volume' at room temperature and pressure?

    <p>The volume occupied by one mole of gas at standard conditions (A)</p> Signup and view all the answers

    How is the concept of limiting reactants important in stoichiometry?

    <p>It identifies which reactant runs out first during a reaction (D)</p> Signup and view all the answers

    What is the result of conducting electrolysis on molten lead(II) bromide?

    <p>Lead is deposited at the cathode (C)</p> Signup and view all the answers

    Which of the following describes a characteristic feature of ionic compounds?

    <p>They are generally poor conductors in solid state (C)</p> Signup and view all the answers

    Which ion is produced at the cathode during the electrolysis of concentrated aqueous sodium chloride?

    <p>Hydrogen (C)</p> Signup and view all the answers

    What are the main components of NPK fertilizers?

    <p>Nitrogen, Phosphorus, and Potassium (D)</p> Signup and view all the answers

    What is a major source of carbon monoxide in the environment?

    <p>Incomplete combustion of fuels (A)</p> Signup and view all the answers

    Which gas contributes to the greenhouse effect by reducing thermal energy loss to space?

    <p>Carbon Dioxide (A), Methane (C)</p> Signup and view all the answers

    Which process is primarily responsible for the formation of oxides of nitrogen in car engines?

    <p>Oxidation of nitrogen at high temperatures (B)</p> Signup and view all the answers

    What is the word equation for photosynthesis?

    <p>carbon dioxide + water → glucose + oxygen (D)</p> Signup and view all the answers

    How can acid rain be reduced according to environmental strategies?

    <p>Low-sulfur fuels and catalytic converters (A)</p> Signup and view all the answers

    Which statement describes a saturated compound?

    <p>Has only single carbon-carbon bonds (C)</p> Signup and view all the answers

    What are structural isomers?

    <p>Compounds with the same molecular formula but different structural arrangements (A)</p> Signup and view all the answers

    Which of the following statements relates to the general formula of alkenes?

    <p>CnH2n (A)</p> Signup and view all the answers

    What is the general characteristic of a homologous series?

    <p>Same functional group and similar properties (C)</p> Signup and view all the answers

    Which pollutant is primarily responsible for the toxicity observed in indoor environments?

    <p>Carbon monoxide (D)</p> Signup and view all the answers

    What is the impact of particulates in the air?

    <p>Increased risk of respiratory illnesses and cancer (C)</p> Signup and view all the answers

    Which of the following equations shows the reaction of carbon monoxide with nitrogen oxide in catalytic converters?

    <p>2CO + 2NO → 2CO2 + N2 (A)</p> Signup and view all the answers

    What is the effect of increased carbon dioxide levels in the atmosphere?

    <p>Global warming and climate change (A)</p> Signup and view all the answers

    What defines polymers?

    <p>Large molecules made from numerous monomers (D)</p> Signup and view all the answers

    What type of polymerization involves the elimination of a small molecule?

    <p>Condensation polymerization (C)</p> Signup and view all the answers

    Which of the following is a characteristic of addition polymers?

    <p>They contain repeating units identical to the monomer (A)</p> Signup and view all the answers

    What is the repeat unit of poly(ethene)?

    <p>C2H4 (C)</p> Signup and view all the answers

    What type of polymer is nylon classified as?

    <p>Polyamide (A)</p> Signup and view all the answers

    Which of the following accurately describes a polyester?

    <p>Made from a diol and a dicarboxylic acid (D)</p> Signup and view all the answers

    Which environmental challenge is associated with plastics?

    <p>Accumulation in oceans (A)</p> Signup and view all the answers

    What purpose do amino acids serve in protein formation?

    <p>They are monomers that build proteins (C)</p> Signup and view all the answers

    What type of solution contains the maximum possible concentration of a solute at a specific temperature?

    <p>Saturated solution (D)</p> Signup and view all the answers

    How can the purity of a substance be assessed?

    <p>By examining melting and boiling points (C)</p> Signup and view all the answers

    What is the main function of chromatography?

    <p>To separate mixtures of substances (C)</p> Signup and view all the answers

    Which statement best describes a residue?

    <p>A solid left after a separation process (B)</p> Signup and view all the answers

    In an acid-base titration, which apparatus is essential for accurate volume measurement?

    <p>Burette (D)</p> Signup and view all the answers

    What is the purpose of a suitable indicator in a titration?

    <p>To identify when the end-point is reached (C)</p> Signup and view all the answers

    Flashcards

    Solid

    The state of matter where particles are closely packed, have a fixed arrangement and only vibrate in fixed positions.

    Liquid

    The state of matter where particles are close together but can move around each other. They have a fixed volume but can take the shape of the container.

    Gas

    The state of matter where particles are widely spaced, move freely and have no fixed shape or volume.

    Melting

    The process of a substance changing from a solid to a liquid.

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    Boiling

    The process of a substance changing from a liquid to a gas.

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    Elements

    Pure substances that cannot be broken down into simpler substances by chemical means.

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    Compounds

    Substances formed when two or more elements chemically combine in a fixed ratio.

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    Mixtures

    A mixture contains two or more substances that are not chemically bonded, and can be separated by physical means.

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    Nucleus

    The central part of an atom, containing protons and neutrons.

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    Protons

    Subatomic particles with a positive charge, found in the nucleus.

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    Neutrons

    Subatomic particles with no charge (neutral), found in the nucleus.

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    Electrons

    Negatively charged subatomic particles that orbit the nucleus in electron shells.

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    Proton number

    The number of protons in the nucleus of an atom, also known as the atomic number.

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    Mass number

    The total number of protons and neutrons in the nucleus of an atom.

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    Isotopes

    Atoms of the same element that have the same number of protons but different numbers of neutrons.

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    Redox reaction

    A chemical reaction that involves the transfer of electrons between reactants, resulting in a change in oxidation states for at least two species.

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    Oxidation

    The process of gaining oxygen or losing electrons, resulting in an increase in oxidation number.

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    Reduction

    The process of losing oxygen or gaining electrons, resulting in a decrease in oxidation number.

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    Oxidizing agent

    A substance that causes another substance to be oxidized while itself being reduced. It gains electrons.

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    Reducing agent

    A substance that causes another substance to be reduced while itself being oxidized. It loses electrons.

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    Acid

    A substance that releases hydrogen ions (H+) when dissolved in water, resulting in a sour taste and the ability to react with metals, bases, and carbonates.

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    Alkali

    A base that is soluble in water.

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    Neutralization reaction

    A chemical reaction between an acid and a base, resulting in the formation of salt and water, with the neutralization of the acidic and basic properties.

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    Salt

    A compound formed by the reaction between an acid and a base, containing a cation from the base and an anion from the acid.

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    Periodic Table Arrangement

    The periodic table is a systematic arrangement of elements organized into horizontal rows called periods and vertical columns called groups, ordered by increasing atomic number (number of protons).

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    Metallic to Non-Metallic Trend

    Across a period (row) from left to right, elements generally change from metallic to non-metallic properties.

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    Group Number and Ion Charge

    The group number of an element often corresponds to the charge of the ion it forms. For example, elements in Group 1 form ions with a +1 charge.

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    Similar Chemical Properties in a Group

    Elements in the same group have similar chemical properties due to having the same number of valence electrons (electrons in the outermost shell).

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    Predicting Properties from the Periodic Table

    The Periodic Table can predict an element's properties based on its position. For example, elements in the same period have similar atomic radii but differ in electronegativity.

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    Group 1 Alkali Metals

    Group 1 elements (alkali metals) are soft metals with decreasing melting points and increasing reactivity down the group. Density also increases.

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    Group 7 Halogens

    Group 7 elements (halogens) are diatomic non-metals, meaning they exist as pairs of atoms. They show decreasing reactivity and increasing density down the group.

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    Transition Metals

    Transition metals are metals with high densities, high melting points, form colored compounds, and often act as catalysts. They can have multiple oxidation states (charges) in their ions.

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    Noble Gases

    Group 8 elements (noble gases) are unreactive, monatomic gases. Their unreactivity is due to their full outer electron shells, making them stable.

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    General Properties of Metals

    Metals are generally good conductors of heat and electricity, malleable (can be hammered into sheets), ductile (can be drawn into wires), and have high melting and boiling points. They react with acids, cold water, and oxygen.

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    Exothermic reaction

    A reaction that releases energy to its surroundings, causing the temperature to increase. This energy release is often in the form of heat.

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    Endothermic reaction

    A reaction that absorbs energy from its surroundings, causing the temperature to decrease. This energy absorption is often from heat.

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    Enthalpy change (∆H)

    The change in heat energy during a chemical reaction. It represents the difference between the enthalpy of the products and the enthalpy of the reactants. Exothermic reactions have a negative enthalpy change, while endothermic reactions have a positive enthalpy change.

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    Activation energy (Ea)

    The minimum amount of energy that colliding particles must possess to have a successful reaction. It is the energy barrier that needs to be overcome for a reaction to occur.

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    Reaction pathway diagram

    A diagram that shows the energy changes during a chemical reaction. It shows the energy of the reactants, products, the activation energy, and the enthalpy change.

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    Bond breaking

    The process of breaking chemical bonds. This process requires energy and is therefore endothermic.

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    Bond making

    The process of forming chemical bonds. This process releases energy and is therefore exothermic.

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    Calculating enthalpy change using bond energies

    The enthalpy change of a reaction can be calculated by considering the energy required to break bonds in the reactants and the energy released when forming bonds in the products. The difference between these two values gives the enthalpy change.

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    Physical change

    Any change that alters the appearance or form of a substance, but does not change its chemical composition. The substance remains the same.

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    Chemical change

    A change that involves the formation of new substances with different chemical properties. The original substances are chemically transformed.

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    Collision theory

    The theory that explains how reactions happen. It states that for a reaction to occur, the reacting particles must collide with sufficient energy and in the correct orientation to break the bonds in the reactants and form new bonds in the products.

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    Catalyst

    A substance that increases the rate of a reaction without being consumed in the reaction. It lowers the activation energy, providing an alternate pathway for the reaction.

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    Enzyme

    A special type of biological catalyst that speeds up biochemical reactions in living organisms.

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    Reversible reaction

    A reaction that can proceed in both directions, meaning the products can react to form the reactants and vice versa.

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    Equilibrium

    The state of a reversible reaction where the rate of the forward reaction is equal to the rate of the reverse reaction. The concentrations of the reactants and products remain constant.

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    Metallic bonding

    Metallic bonding is a type of chemical bonding that occurs between metal atoms. In this type of bonding, the outermost electrons of the metal atoms are delocalized, forming a "sea" of electrons that move freely throughout the metal lattice. This 'sea' of electrons is held together by electrostatic attraction to the positively charged ions. This strong electrostatic attraction is the foundation of metallic bonding.

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    Why are metals good conductors of electricity?

    Metals are excellent conductors of electricity because their delocalized electrons are free to move throughout the metal lattice. When an electrical potential is applied, these electrons can easily flow, carrying the electric current.

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    Explain malleability and ductility of metals.

    Malleability describes a metal's ability to be hammered or pressed into different shapes without breaking. Ductility is the ability to be drawn into wires. Both are possible because of the 'sea' of delocalized electrons. When a force is applied, the layers of metal atoms can slide past each other without breaking the metallic bonds, as the electrons continue to attract the positive ions.

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    What is a molecular formula?

    A molecular formula shows the actual number and type of atoms present in a single molecule of a compound. For example, the molecular formula of glucose is C6H12O6. This means each molecule of glucose contains 6 carbon atoms, 12 hydrogen atoms and 6 oxygen atoms.

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    What is an empirical formula?

    An empirical formula shows the simplest whole number ratio of atoms present in a compound. It is the most simplified version of a molecular formula. For example, the molecular formula of glucose is C6H12O6, but its empirical formula is CH2O.

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    What is relative atomic mass (Ar)?

    The relative atomic mass, Ar, is the average mass of the isotopes of an element compared to 1/12th of the mass of an atom of carbon-12.

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    What is relative molecular mass (Mr)?

    The relative molecular mass, Mr, is the sum of the relative atomic masses of all the atoms in a molecule. For ionic compounds, the term relative formula mass, Mr, is used.

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    What is a mole?

    The mole is the SI unit of amount of substance. It is defined as the amount of substance that contains the same number of elementary entities (atoms, ions, molecules etc.) as there are atoms in 0.012 kilogram of carbon-12. This number is known as Avogadro's constant and is approximately 6.02 x 10^23.

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    What is electrolysis?

    Electrolysis is the process of decomposing an ionic compound by passing an electric current through its molten or aqueous solution. This process results in the separation of the compound into its constituent elements.

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    What is the anode?

    The anode is the positive electrode in an electrolytic cell. It is where oxidation occurs, meaning electrons are lost by ions. It's where non-metals (other than hydrogen) are usually formed.

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    What is the cathode?

    The cathode is the negative electrode in an electrolytic cell. It is where reduction occurs, meaning electrons are gained by ions. Metals or hydrogen are usually formed at this electrode.

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    What is electroplating?

    Electroplating is a process where a thin layer of metal is deposited onto the surface of another metal object. This is achieved by electrolysis, using the object to be plated as the cathode and the desired metal as the anode.

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    What is a hydrogen-oxygen fuel cell?

    A hydrogen-oxygen fuel cell is a device that converts chemical energy from the reaction of hydrogen and oxygen into electrical energy. Water is the only by-product of this process, making it a clean energy source.

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    What are the advantages and disadvantages of hydrogen-oxygen fuel cells?

    Hydrogen-oxygen fuel cells offer several advantages over gasoline/petrol engines. Some benefits include: Clean energy production with water as the only by-product; High energy efficiency compared to traditional combustion engines; Reduced emissions and greenhouse gases. However, they also have some drawbacks. These include: Hydrogen storage and transportation challenges; High initial cost; Limited infrastructure for refueling.

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    Reaction of Aluminium Ions (Al3+) with NaOH

    Aqueous sodium hydroxide (NaOH) solution reacts with aluminium ions (Al3+) to form a white gelatinous precipitate, which dissolves in excess sodium hydroxide solution to form a colorless solution.

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    Reaction of Ammonium Ions (NH4+) with NaOH

    Aqueous sodium hydroxide (NaOH) solution reacts with ammonium ions (NH4+) to produce a colorless gas with a pungent ammonia-like odor.

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    Reaction of Copper(II) Ions (Cu2+) with NaOH

    Aqueous sodium hydroxide (NaOH) solution reacts with copper(II) ions (Cu2+) to form a pale blue precipitate.

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    Reaction of Copper(II) Ions (Cu2+) with Ammonia

    Aqueous ammonia (NH3) reacts with copper(II) ions (Cu2+) to form a pale blue precipitate, which dissolves in excess ammonia to form a deep blue solution.

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    Flame Test

    A flame test is used to identify the cations of certain elements based on the color they produce when heated in a flame.

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    Reactivity Series

    A list of metals arranged in order of decreasing reactivity, with the most reactive metal at the top and the least reactive at the bottom.

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    Displacement Reaction

    A chemical reaction where a more reactive metal displaces a less reactive metal from its salt solution.

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    Reactivity of Metals

    The tendency of a metal to lose electrons and form positive ions.

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    Rusting

    The process of iron or steel reacting with oxygen and water to form hydrated iron(III) oxide (rust).

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    Barrier Methods (Preventing Rusting)

    Methods that prevent rusting by physically blocking oxygen or water from reaching the metal surface.

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    Sacrificial Protection

    The use of a more reactive metal to protect a less reactive metal from corrosion, by preferentially corroding itself.

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    Metal Extraction

    A process that involves extracting a metal from its ore, which is a naturally occurring solid containing the metal compound.

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    Iron Extraction (Blast Furnace)

    A chemical process used to extract iron from its ore, hematite, by reducing iron(III) oxide to iron using carbon monoxide.

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    Aluminium Extraction (Electrolysis)

    A chemical process used to extract aluminium from its ore, bauxite, by electrolysis, which uses an electric current to break down aluminium oxide into aluminium.

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    Water Treatment

    The process of removing impurities from a solution by sedimentation, filtration, and chemical treatment like chlorination.

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    What are hydrocarbons?

    Hydrocarbons are compounds that are made up of only hydrogen and carbon atoms.

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    What are fossil fuels?

    Fossil fuels are natural fuels formed over millions of years from the remains of ancient organisms.

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    Name the three main fossil fuels.

    Coal, natural gas, and petroleum are the three main types of fossil fuels.

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    What is petroleum made of?

    Petroleum is a mixture of hydrocarbons.

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    How is petroleum separated into fractions?

    Fractional distillation is the process of separating petroleum into different fractions based on their boiling points.

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    What is the main component of natural gas?

    Natural gas is mainly composed of methane, a simple hydrocarbon.

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    What is cracking?

    The cracking process breaks down larger alkanes into smaller, more useful alkenes and hydrogen gas. It uses high temperatures and a catalyst.

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    What are alkanes?

    Alkanes are saturated hydrocarbons, meaning they contain only single carbon-carbon bonds.

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    What are alkenes?

    Alkenes are unsaturated hydrocarbons, meaning they contain at least one double carbon-carbon bond.

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    How is ethanol manufactured?

    Ethanol can be produced by fermentation of glucose or by catalytic addition of steam to ethene.

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    Fertilizers: Ammonium Salts and Nitrates

    Ammonium salts and nitrates are chemical compounds used to provide essential nutrients like nitrogen to plants, promoting healthy growth.

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    NPK Fertilizers

    NPK fertilizers contain nitrogen (N), phosphorus (P), and potassium (K), which are crucial for plant growth and development. These nutrients are needed in different quantities for specific plant processes.

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    Composition of Clean Air

    Clean, dry air is primarily composed of nitrogen (N2) (around 78%), oxygen (O2) (around 21%), and a small percentage of noble gases like argon and carbon dioxide (CO2).

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    Source of Carbon Dioxide (CO2) Pollution

    Carbon dioxide is produced when carbon-containing fuels, like wood or fossil fuels, are completely burned in the presence of oxygen.

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    Source of Carbon Monoxide (CO) and Particulate Matter

    When carbon-containing fuels are burned incompletely, carbon monoxide (CO) and particulate matter (small particles) are released into the air.

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    Source of Methane (CH4) Pollution

    Methane is produced from the decomposition of organic matter, such as vegetation and waste, as well as from the digestive processes of animals.

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    Source of Oxides of Nitrogen (NOx) Pollution

    Oxides of nitrogen are primarily produced by internal combustion engines, particularly in cars, due to high temperatures and the reaction between nitrogen and oxygen in the air.

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    Source of Sulfur Dioxide (SO2) Pollution

    Sulfur dioxide is released when fossil fuels containing sulfur compounds, such as coal and oil, are burned.

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    Effect of Carbon Dioxide (CO2) on Climate

    High levels of carbon dioxide in the atmosphere trap heat, leading to an increase in global temperature and resulting in climate change.

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    Effects of Carbon Monoxide (CO) on Health

    Carbon monoxide is a toxic gas that can be fatal when inhaled in high concentrations, as it displaces oxygen in the blood, preventing red blood cells from carrying oxygen throughout the body.

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    Effects of Particulate Matter on Health

    Particulate matter can irritate the respiratory system, leading to respiratory problems such as asthma and bronchitis, and also increase the risk of developing lung cancer.

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    Effect of Methane (CH4) on Climate

    Elevated levels of methane in the atmosphere contribute to global warming, as methane is a potent greenhouse gas, trapping heat and leading to climate change.

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    Effects of Oxides of Nitrogen (NOx) Pollution

    Oxides of nitrogen contribute to acid rain, which damages buildings, forests, and aquatic ecosystems. They also contribute to photochemical smog, a type of air pollution that causes respiratory problems.

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    Effects of Sulfur Dioxide (SO2) Pollution

    Sulfur dioxide is a major contributor to acid rain, which damages ecosystems, buildings, and infrastructure. It also leads to respiratory problems in humans.

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    Photosynthesis

    Photosynthesis is the process by which plants use sunlight, water, and carbon dioxide to produce glucose (a type of sugar) and oxygen. This process is essential for life on Earth.

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    What are polymers?

    Large molecules made from many smaller repeating units called monomers.

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    What is addition polymerisation?

    The process of joining monomers to form a polymer without the loss of any atoms.

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    What is an addition polymer?

    A polymer formed by adding monomers together, with no loss of atoms.

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    What is a repeat unit?

    The basic repeating unit in a polymer.

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    What is condensation polymerisation?

    A polymer formed by the reaction of monomers, where small molecules such as water are lost during the reaction.

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    What is a condensation polymer?

    A polymer formed by the reaction of monomers, where small molecules such as water are lost during the reaction.

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    What are plastics?

    Polymers that are often used to make plastics.

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    What is a polyamide?

    A type of condensation polymer formed from a dicarboxylic acid (two COOH groups) and a diamine (two NH2 groups).

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    What is a polyester?

    A type of condensation polymer formed from a dicarboxylic acid (two COOH groups) and a diol (two OH groups).

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    What are the environmental challenges of plastics?

    The properties of plastics, such as their durability and non-biodegradability, make them a challenge to dispose of.

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    What are proteins?

    A natural polyamide made from amino acid monomers.

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    How does paper chromatography work?

    The process of separating substances with different solubilities in a solvent.

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    What is the Rf value in chromatography?

    The ratio of the distance traveled by a substance to the distance traveled by the solvent.

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    What are the different methods of separation and purification?

    Techniques used to separate and purify substances based on their physical properties.

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    What are solutes?

    Substances that dissolve in a solvent.

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    Study Notes

    States of Matter

    • Solids, liquids, and gases have distinct properties related to particle separation, arrangement, and motion.
    • Changes of state (melting, boiling, evaporating, freezing, condensing) are explained by kinetic particle theory.
    • Temperature and pressure significantly affect gas volume.
    • Diffusion is the movement of particles from an area of high concentration to low, explained by kinetic particle theory.
    • Relative molecular mass influences the rate of gas diffusion.

    Atoms, Elements, and Compounds

    • Elements, compounds, and mixtures differ in their compositions.
    • Atoms have a nucleus (protons and neutrons) surrounded by electrons in shells.
    • Protons, neutrons, and electrons have specific relative charges and masses.
    • Proton number (atomic number) defines the number of protons.
    • Mass number (nucleon number) is the total of protons and neutrons.
    • Electronic configurations, up to 20 protons, describe electron distribution in shells; e.g., 2,8,3.
    • Noble gases (Group VIII) have full outer electron shells.
    • Group number indicates the number of outer shell electrons (Groups I to VII).
    • Period number corresponds to the number of occupied electron shells.
    • Isotopes are atoms of the same element with the same proton number but different neutron numbers. This results in similar chemical properties.
    • Isotope symbols are used, like 126C, 35Cl–17.
    • Relative atomic mass is the weighted average mass of an element's isotopes.

    Ions and Ionic Bonds

    • Cations (positive ions) and anions (negative ions) are formed.
    • An ionic bond is an electrostatic attraction between oppositely charged ions.
    • Ionic compounds form giant lattice structures of alternating positive and negative ions.
    • Ionic compounds have high melting and boiling points and conduct electricity in molten or aqueous states but not as solids.
    • Ionic bonds are often formed between elements from Group I and Group VII.

    Simple Molecules and Covalent Bonds

    • Covalent bonds are formed by electron sharing between atoms to achieve stable configurations similar to noble gases.
    • Dot-and-cross diagrams illustrate electron sharing in simple molecules like H2, Cl2, H2O, CH4, NH3, HCl, CH3OH, C2H4, O2, CO2, N2.
    • Simple molecular compounds have low melting and boiling points due to weak intermolecular forces.
    • They generally do not conduct electricity.

    Giant Covalent Structures

    • Diamond and graphite have giant covalent structures.
    • Graphite is used as a lubricant and electrode due to its structure.
    • Diamond is used in cutting tools.
    • Silicon(IV) oxide also has a giant covalent structure.

    Metallic Bonding

    • Metallic bonding is the electrostatic attraction between positive metal ions and a "sea" of delocalized electrons.
    • Metals are good conductors of electricity and heat due to their structure.
    • Metals are malleable and ductile because their layers can slide over each other.

    Stoichiometry

    • Chemical formulas for elements and compounds are stated.
    • Molecular formulas show the number and type of atoms in a molecule.
    • Empirical formulas show the simplest ratio of atoms in a compound.
    • Word and symbol equations represent chemical reactions, including state symbols.
    • Reacting masses can be calculated without the mole concept.

    The Mole and Avogadro's Constant

    • The mole (mol) is a unit of amount of substance, equal to 6.02 × 10^23 particles.
    • Calculations involve mass, amount, molar mass, relative atomic/molecular/formula mass, and the number of particles.
    • Concentration can be expressed as g/dm³ or mol/dm³.
    • The molar gas volume is 24 dm³ at room temperature and pressure (r.t.p.).
    • Calculations can involve stoichiometry, limiting reactants, gas volumes, volumes of solutions, and concentrations (g/dm³ and mol/dm³).
    • Titration experimental data can be used for stoichiometric calculations.

    Electrolysis

    • Electrolysis decomposes ionic compounds (molten or aqueous) using an electric current.
    • Electrolytic cells involve electron movement in the external circuit and ion movement in the electrolyte.
    • Anode is the positive electrode; cathode is the negative electrode.
    • Electrolysis products are predictable based on the compound.
    • Ionic half-equations at anodes (oxidation) and cathodes (reduction) can be written.
    • Metals are electroplated to improve appearance and resistance to corrosion.

    Hydrogen-Oxygen Fuel Cells

    • Hydrogen and oxygen produce electricity with water as the only product.
    • Fuel cells have advantages and disadvantages compared to gasoline engines.

    Chemical Energetics

    • Exothermic reactions release heat, endothermic reactions absorb heat.
    • Enthalpy change (∆H) is the heat transfer during a reaction (negative for exothermic, positive for endothermic).
    • Activation energy (Ea) is the minimum energy for reactant collisions to react.
    • Reaction pathway diagrams depict reactants, products, ∆H, and Ea, for exothermic and endothermic reactions.
    • Bond breaking is endothermic; bond making is exothermic.

    Chemical Reactions

    • Physical and chemical changes differ.

    Rate of Reaction

    • Collision theory explains factors affecting reaction rates (numbers of particles, collision frequency, kinetic energy, activation energy).
    • Factors such as changing concentration, pressure, surface area, temperature, and catalysts (including enzymes) affect reaction rate.
    • Catalysts increase reaction rate without being consumed.
    • Catalysts lower activation energy.

    Reversible Reactions and Equilibrium

    • Some reactions are reversible.
    • At equilibrium, forward and reverse reaction rates are equal; reactant and product concentrations are constant.
    • Reversible reactions can be affected by temperature and pressure. Examples include hydrated/anhydrous compounds (e.g., copper(II) sulfate, cobalt(II) chloride).

    Redox Reactions

    • Redox reactions involve simultaneous oxidation and reduction.
    • Oxidation involves electron loss; reduction involves electron gain.
    • Oxidation number is used to track electron transfer during redox reactions. Examples include compounds in their uncombined state, monatomic ions, and components of compounds/ions.
    • Oxidizing agents cause oxidation and are reduced.
    • Reducing agents cause reduction and are oxidized.

    Acids, Bases, and Salts

    • Acids react with metals, bases, and carbonates.
    • Acids change litmus, thymolphthalein, and methyl orange colors.
    • Bases are metal oxides or hydroxides; alkalis are soluble bases.
    • Bases react with acids and ammonium salts.
    • Alkalis change litmus, thymolphthalein, and methyl orange colors.
    • Aqueous acid solutions contain H+ ions; aqueous alkali solutions contain OH- ions.
    • Acids are proton donors; bases are proton acceptors.
    • Strong acids wholly dissociate in aqueous solution; weak acids partially dissociate.
    • Neutralization reactions between acids and alkalis produce water.

    Oxides

    • Oxides can be acidic (like SO2, CO2) or basic (like CuO, CaO) based on their metallic/non-metallic nature.
    • Amphoteric oxides react with both acids and bases. (e.g.,Al2O3 & ZnO)

    Preparation of Salts

    • Insoluble salts can be prepared via precipitation reactions.
    • Soluble salts can be prepared by reacting an acid with a metal, excess metal, excess insoluble base, or excess insoluble carbonate.
    • Solubility rules for common salts are listed for prediction purposes.

    The Periodic Table

    • The Periodic Table arranges elements in periods and groups by increasing proton/atomic numbers.
    • Metallic character decreases across a period.
    • Group number correlates to the charge of ions formed from elements within that group.
    • Elements in the same group have similar chemical properties due to similar electron configurations.

    Group I Properties

    • Alkali metals (Li, Na, K) are relatively soft metals.
    • Properties typically increase in reactivity/density/volume as you move down a group.

    Group VII Properties

    • Halogens (Cl, Br, I) are non-metals. Their reactivity/density/state of matter increase as you move down a group.
    • Chlorine is a pale yellow-green gas at room temperature.
    • Bromine is a red-brown liquid at room temperature.
    • Iodine is a grey-black solid at room temperature.
    • Halogens react via displacement reactions with other halide ions.

    Transition Elements

    • Transition elements are metals with high densities, melting points, form colored compounds, and often act as catalysts.
    • Transition metal ions often have variable oxidation states.

    Noble Gases

    • Noble gases are unreactive, monatomic gases due to their complete outer electron shells.

    Metals

    • Metals have characteristic physical properties like thermal and electrical conductivity, malleability, ductility, melting points, and boiling points.
    • Metals usually react with dilute acids, cold water, and steam.

    Uses of Metals

    • Metal uses are frequently linked to their physical properties.

    Alloys and Their Properties

    • Alloys are mixtures of metals with other elements.

    Reactivity Series

    • The reactivity series orders the reactivity of metals, based on their ability to displace other metal ions.
    • Potassium, sodium, calcium are highly reactive with water.
    • Aluminium's apparent unreactivity comes from the formation of an oxide coating.

    Corrosion of Metals

    • Rusting requires oxygen, water, and iron.
    • Barrier methods of corrosion prevention include painting, grease, and coating(plastic).
    • Sacrificial protection uses more reactive metals.

    Extraction of Metals

    • Metal extraction depends on the metal's position in the reactivity series.
    • Iron extraction from hematite involves coke burning, CO2 and CO formation, reduction, limestone decomposition to slag.
    • Aluminum extraction is via electrolysis of bauxite.
    • Bauxite purification and cryolite role in aluminum extraction are important.

    Chemistry of the Environment

    • Water testing uses anhydrous cobalt(II) chloride and copper(II) sulfate.
    • Natural water contains dissolved oxygen, metal compounds, plastics, sewage, microbes, nitrates, and phosphates.
    • Water treatment (sedimentation, filtration, carbon, chlorination) removes pollutants.
    • Fertilizers (ammonium salts, nitrates) provide nutrients.

    Air Quality and Climate

    • Air composition is mostly nitrogen and oxygen, with trace gases.
    • Air pollutants include carbon dioxide, carbon monoxide, methane, oxides of nitrogen, and sulfur dioxide.
    • Pollutant sources and effects, including global warming issues, are detailed.
    • Strategies for pollution reduction are associated with chemical production.
    • Photosynthesis converts carbon dioxide and water into glucose and oxygen.

    Organic Chemistry

    • Displayed formulas depict molecules' atom and bond arrangement.
    • General formulae describe similar compounds (e.g., alkanes CnH2n+2).
    • Functional groups determine chemical properties.
    • Structural isomers share the same molecular formulas but differ structurally (e.g., C4H10, C4H8)
    • Homologous series have a shared functional group, general formula, and incremental -CH2- differences, along with trends in physical and chemical properties.
    • Saturated compounds have single carbon-carbon bonds.
    • Unsaturated compounds have double or triple carbon-carbon bonds.

    Naming Organic Compounds

    • Names of various hydrocarbons, including unbranched alkanes, alkenes, alcohols, and carboxylic acids, are detailed.
    • Identification from chemical names, molecular formulas or displayed formulas can be performed.
    • Relevant product naming and formula drawing associated with reactions are included.

    Fuels

    • Fossil fuels (coal, natural gas, petroleum) are hydrocarbons.
    • Fractional distillation separates petroleum into fractions with differing boiling points, chain length, volatility, and viscosities that consequently have different uses (e.g., refinery gas for heating, gasoline for cars).
    • Hydrocarbons contain carbon and hydrogen only.

    Alkanes

    • Alkanes are saturated hydrocarbons with single bonds.
    • They are relatively unreactive except for combustion and substitution reactions (e.g., with chlorine).
    • Substitution reactions replace atoms or groups.

    Alkenes

    • Alkenes are unsaturated hydrocarbons with double bonds.
    • Alkenes are formed via cracking.
    • Tests distinguish between saturated and unsaturated hydrocarbons (e.g., with bromine).
    • Addition reactions to alkenes form single bonds.

    Alcohols

    • Ethanol can be made via fermentation or catalytic addition of steam.
    • Ethanol is used as a solvent and fuel.

    Carboxylic Acids

    • Ethanoic acid reactions with metals, bases, and carbonates are detailed.
    • Ethanoic acid formation via ethanol oxidation is explained, involving bacterial oxidation (e.g., vinegar production) .

    Polymers

    • Polymers are built from monomers.
    • Poly(ethene) is an example of addition polymerisation.
    • Plastics have varied properties affecting disposal (e.g., land fill, ocean accumulation, toxic fumes during burning).
    • Addition and condensation polymerisation are contrasted methods. Illustrations can be given for nylon and PET(polyethylene terephthalate) and their structures, and monomers used.
    • Proteins are natural polyamides formed from amino acids.

    Experimental Techniques and Chemical Analysis

    • Apparatus for time, temperature, mass, and volume measurements are listed, along with advantages/disadvantages of various techniques.
    • Solvent, solute, solution definitions as well as the related terms (saturated solution, residue, filtrate are included)
    • Acid-base titrations utilize specific equipment (burette, pipette, indicator) to measure required data.
    • Paper chromatography separates mixtures of soluble substances (coloured or colourless), determined from Rf values.
    • Separation and purification methods (solvent, filtration, crystallisation, distillation) and their applications are described.
    • Tests for anions (e.g., carbonate, chloride, nitrate, sulfate, sulfite).
    • Tests for cations (e.g., using sodium hydroxide and ammonia solutions).
    • Tests for gases (e.g., using litmus paper, limewater, glowing/lighted splints).
    • Flame tests identify specific metal cations.

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    Test your understanding of kinetic particle theory with this quiz. Explore how particles behave in different states of matter and how temperature influences gas volume. Answer questions on particle arrangement, transitions between states, and diffusion rates.

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