KFT431 Quantum Chemistry Part II
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KFT431 Quantum Chemistry Part II

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Questions and Answers

The energy difference between the n = 1 and n = 2 levels for an electron confined to a 1-D box is $1.13 \times 10^{-18} J$.

True

For a marble confined to a 1-D box of length 0.10 m, the energy difference between n = 1 and n = 2 levels is $5.48 \times 10^{-62} J$.

True

The wavelength corresponding to the spectral transition for an electron is $1.76 \times 10^{-7} m$.

True

For an electron in a 1-D box, the wavelength corresponding to the energy transition is less than the observed distance of any star.

<p>False</p> Signup and view all the answers

The wavefunctions $\psi_1$ and $\psi_2$ described for a particle-in-a-box system are orthogonal.

<p>True</p> Signup and view all the answers

An electron confined in a box of length $4.0 \times 10^{-10} m$ can have a measurable energy difference of $5.48 \times 10^{-62} J$.

<p>False</p> Signup and view all the answers

The formula for calculating energy levels in a 1-D box involves the mass of the particle and the length of the box.

<p>True</p> Signup and view all the answers

The wavelength calculated for an electron transition falls within the infrared region of the electromagnetic spectrum.

<p>False</p> Signup and view all the answers

The box length in the conjugated π-electron system is determined solely by the distance between two carbons.

<p>False</p> Signup and view all the answers

The empirical parameter p is derived from theoretical calculations rather than experimental results.

<p>False</p> Signup and view all the answers

The integral for the operation of x involves a multiplication of sin functions.

<p>True</p> Signup and view all the answers

The expression for the box length a considers only the number of carbons in the conjugated system.

<p>False</p> Signup and view all the answers

The equation x^2 is evaluated over the interval from 0 to a in the context of the provided solution.

<p>True</p> Signup and view all the answers

The variable n in the context of formulas generally represents the length of the molecule.

<p>False</p> Signup and view all the answers

The formula for R in the solution is defined as the integral of ψ∗ ψ dτ.

<p>True</p> Signup and view all the answers

The term 'nπ' appears in the context of evaluating sin functions in the solution.

<p>True</p> Signup and view all the answers

The operator for p is represented as $\hat{x}^2$.

<p>False</p> Signup and view all the answers

The eigenvalue equation is used to calculate the expectation value of $p^2_x$ for a particle in a 1-D box.

<p>True</p> Signup and view all the answers

The integral $\int_0^a \sin^2(n\pi x/a)dx$ equals $\frac{a}{2}$.

<p>True</p> Signup and view all the answers

The formula $sin^2\theta = 2sin\theta cos\theta$ is incorrect.

<p>False</p> Signup and view all the answers

For the operator $\hat{p}$, the formula includes a term with $\hbar^2$ in the denominator.

<p>True</p> Signup and view all the answers

The term $\psi^*$ represents the complex conjugate of the wave function $\psi$.

<p>True</p> Signup and view all the answers

The expectation value $<p^2_x>$ can only be calculated if the wave function is defined in the region $(0, a)$.

<p>True</p> Signup and view all the answers

The term $n^2 \pi^2$ appears in the formula for the expectation value $<p^2_x>$ for a particle in a box.

<p>True</p> Signup and view all the answers

The general solution to the Schrödinger equation is given by 𝛙(𝐱) = 𝐀 𝐬𝐢𝐧𝐤𝐱 + 𝐁 𝐜𝐨𝐬𝐤𝐱.

<p>False</p> Signup and view all the answers

The value of k is defined as $k = \frac{\sqrt{2mE}}{\hbar}$.

<p>True</p> Signup and view all the answers

The only solution to the Schrödinger equation when V is infinite is 𝛙 = 1.

<p>False</p> Signup and view all the answers

According to the given equations, the quantized energy levels can be derived from the equation $E_n = \frac{n^2 \pi^2 \hbar^2}{2ma}$.

<p>True</p> Signup and view all the answers

The boundary condition at x = a only affects the coefficient B in the general solution.

<p>False</p> Signup and view all the answers

The lowest value for the quantum number n is 0.

<p>False</p> Signup and view all the answers

A particle constrained between x = 0 and x = a has continuous energy values.

<p>False</p> Signup and view all the answers

The equation $\frac{d^2 \Psi}{dx^2} = -k^2 \Psi$ indicates a particle in a box.

<p>True</p> Signup and view all the answers

The energy change from the nth to (n+1)th level decreases with increasing n.

<p>False</p> Signup and view all the answers

In the particle-in-a-box model, the potential is zero inside the box and infinite outside the box.

<p>True</p> Signup and view all the answers

The equation for wavelength $\lambda$ in terms of energy $\Delta E$ involves the constants h and c.

<p>True</p> Signup and view all the answers

The maximum wavelength $\lambda_{max}$ for polyenylic ions is determined solely by the value of n.

<p>False</p> Signup and view all the answers

The time-independent Schrödinger equation is represented as $\hat{H} \Psi(x, y) = E \Psi(x, y)$.

<p>True</p> Signup and view all the answers

Separation of variables is a technique used to solve the time-independent Schrödinger equation.

<p>True</p> Signup and view all the answers

The formula for energy levels $E_n$ includes a term $𝑛^2$ multiplied by $h^2$.

<p>True</p> Signup and view all the answers

The term $\cos 30^{ ext{o}}$ is included in the expressions for energy levels and wavelength.

<p>True</p> Signup and view all the answers

The equation $\frac{1}{d^2 \Psi_x} - \frac{1}{d^2 \Psi_y} = 2mE$ shows the energy levels depend on different variables.

<p>True</p> Signup and view all the answers

In the normalized wavefunction, if $n_x$ is equal to 3, $n_y$ must also be equal to 3.

<p>False</p> Signup and view all the answers

The allowed energy levels can be expressed as $E = \frac{h^2 n_x^2 n_y^2}{8mab}$.

<p>True</p> Signup and view all the answers

If both sides of equation (37) are equal to a constant, it implies a relationship between $\Psi_x$ and $\Psi_y$.

<p>True</p> Signup and view all the answers

The term $\frac{\hbar^2 d^2 \Psi_y}{2m d y^2} = E_y \Psi_y$ states that the energy $E_y$ is proportional to the second derivative of the wavefunction $\Psi_y$.

<p>True</p> Signup and view all the answers

The variable 'a' in the equations corresponds to the width of the box in the normalized wavefunction.

<p>True</p> Signup and view all the answers

In the equations provided, $E = E_x + E_y$ means the total energy is the sum of the energy contributions from both dimensions.

<p>True</p> Signup and view all the answers

If the sides of the box are not equal, it implies that $E_x$ and $E_y$ will have the same values.

<p>False</p> Signup and view all the answers

Equation (38) indicates that the kinetic energy term is invariant under one variable's transformation.

<p>False</p> Signup and view all the answers

The normalization condition ensures that the wavefunctions are defined over the dimensions of the box correctly.

<p>True</p> Signup and view all the answers

Study Notes

KFT431 Physical Chemistry III: Quantum Chemistry (Part II)

  • Course covers Quantum mechanics for simple systems, including the free particle, particle-in-a-box (1-D, 2-D, and 3D), harmonic oscillator, and rigid rotor.
  • Free Particle:
    • Total energy is the kinetic energy.
    • Energy is not quantized.
    • Probability of finding the particle at any point along the x-axis is equal.
  • Particle-in-a-Box (1-D):
    • Potential energy is zero for 0 < x < a and infinite outside this region.
    • Energy levels are quantized: En = n2h2/8ma2, where n=1,2,3...
    • Wavefunction ψn(x) = √(2/a)sin(nπx/a).
  • Particle-in-a-Box (Multiple dimensions):
    -Energy levels are quantized by Enx,ny = (h2/8m)(nx2/a2 + ny2/b2) for a 2 dimensional box. For a 3 dimensional box, E = h2/8m(nx2/a2 + ny2/b2 + nz2/c2) -The solutions to these equations in multiple dimensions are similar to the 1-dimenstional case: ψnx, ny (x,y) = √(2/a)(2/b)sin(nx πx/a)sin(ny πy/b)
  • Harmonic Oscillator:
    • The allowed energy levels are equally spaced.
    • Zero-point energy exists.
    • Ev = (v + 1/2)hν, where v is the vibrational quantum number.
  • Rigid Rotor:
    • Represents diatomic molecules rotating with constant distance btwn the atoms.
    • Energy (E) = J (J+1) h2 / 2I, where J is rotational quantum number.
    • The rotational levels are (2J +1) fold degenerate.

Quantum Mechanical Operators 

  • Operators for quantum mechanical quantities, and how they relate to classical versions.

Examples of Calculations

  • Calculations of energy differences, transition wavelengths. 
  • Probability of finding a particle within a given range.
  • Expected values for different quantum mechanical operators .

Degeneracy

  • When energy levels correspond to more than one state, it's called degenerate.

Application of Particle in a Box

  • Calculations of electronic spectra of conjugated π-electron systems provide insight into molecular structures.

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Description

Explore the principles of quantum mechanics in simple systems, including the free particle, particle-in-a-box in one, two, and three dimensions, harmonic oscillator, and rigid rotor. This quiz will test your understanding of energy quantization and wavefunctions. Dive deep into the fascinating world of quantum chemistry!

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