Joule-Thomson Effect in Gas Expansion
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Questions and Answers

What causes the drop in temperature during the Joule-Thomson effect?

  • Energy overcoming cohesive forces between molecules (correct)
  • Expansion of molecules
  • Decrease in intermolecular distance
  • Increase in kinetic energy

What happens to the kinetic energy of gas molecules when the Joule-Thomson effect occurs?

  • It transforms into potential energy
  • It decreases (correct)
  • It increases
  • It remains constant

Which method for liquefying gases involves compressing air to about 200 atmospheres?

  • Faraday’s method
  • Joule-Thomson method
  • Claude’s method (correct)
  • Linde’s method

In Claude's apparatus, where does a part of the air go after passing through pipe ABC?

<p>Down the spiral towards a jet nozzle (A)</p> Signup and view all the answers

What is required to cause liquefaction of a gas using methods based on the Joule-Thomson effect?

<p>A sufficient drop in temperature (A)</p> Signup and view all the answers

How does compression of air to about 200 atmospheres contribute to liquefaction in Claude's method?

<p>It provides energy for cooling (D)</p> Signup and view all the answers

What is the main purpose of liquefaction of gases?

<p>To prepare pharmaceutical aerosols (C)</p> Signup and view all the answers

Which method is responsible for the further cooling of precooled incoming compressed air in the liquefaction process?

<p>Joule-Thomson expansion (C)</p> Signup and view all the answers

How do the properties of liquids differ from those of gases in terms of compressibility and density?

<p>Liquids are less compressible and have higher density than gases (A)</p> Signup and view all the answers

What effect does the cooled air have on the portion of incoming compressed air in the liquefaction process?

<p>It decreases the kinetic energy of gas molecules (D)</p> Signup and view all the answers

Which factor plays a significant role in driving the engine during the liquefaction process?

<p>Overcoming forces of attraction (C)</p> Signup and view all the answers

In what state do liquids differ from gases in terms of molecule motion and volume assumption?

<p>Gases have higher kinetic energy and fill all available space unlike liquids (B)</p> Signup and view all the answers

What is the significance of critical temperature in relation to intermolecular forces?

<p>Gases with high critical temperature have stronger intermolecular forces, making them easier to liquefy. (D)</p> Signup and view all the answers

How does cooling a gas below its critical temperature affect the pressure required for liquefaction?

<p>Decreases pressure required as cooling reduces intermolecular forces. (A)</p> Signup and view all the answers

Which method is NOT commonly used to achieve gas liquefaction?

<p>Boiling (B)</p> Signup and view all the answers

What effect does compression have on gas molecules during liquefaction?

<p>Compression brings molecules closer together, aiding in liquefaction. (C)</p> Signup and view all the answers

What is the relationship between critical pressure and liquefaction of a gas?

<p>Higher critical pressure makes liquefaction more difficult. (B)</p> Signup and view all the answers

What role does intense coldness play in achieving gas liquefaction?

<p>Intense coldness weakens intermolecular forces, aiding in liquefaction. (B)</p> Signup and view all the answers

What does vapor pressure express for a molecule in a liquid?

<p>Tendency to evaporate (C)</p> Signup and view all the answers

Why do liquids with weak intermolecular forces have high vapor pressure?

<p>Molecules escape readily (D)</p> Signup and view all the answers

What does the Clausius-Clapeyron equation describe?

<p>Vapor pressure and temperature relationship (C)</p> Signup and view all the answers

Which factor affects the vapor pressure of a liquid at room temperature?

<p>Nature of the liquid's intermolecular forces (D)</p> Signup and view all the answers

How does the vapor pressure of a liquid change with increasing temperature?

<p>Vapor pressure increases (D)</p> Signup and view all the answers

Which type of liquids would you expect to have the highest vapor pressure at room temperature?

<p>Liquids with weak attractive forces (D)</p> Signup and view all the answers

What happens to the rate of condensation as the amount of vaporized liquid in the gaseous state continues to increase?

<p>It increases until it equals the rate of vaporization (B)</p> Signup and view all the answers

How do intermolecular forces in liquids compare to those in gases?

<p>They are weaker in liquids (A)</p> Signup and view all the answers

Which property of liquids explains their tendency to flow in response to external forces?

<p>Viscosity (A)</p> Signup and view all the answers

What effect does an increase in temperature have on the kinetic energy of the molecules of a liquid?

<p>It significantly increases the kinetic energy (A)</p> Signup and view all the answers

Which equation is used to describe the relationship between vapor pressure and temperature?

<p>Clausius-Clapeyron Equation (B)</p> Signup and view all the answers

What is the primary significance of the molar heat of vaporization in pharmaceutical applications?

<p>Affecting drug stability (B)</p> Signup and view all the answers

What happens to the vapor pressure of a liquid with a positive enthalpy of vaporization as temperature increases?

<p>Increases exponentially (A)</p> Signup and view all the answers

How does the addition of a non-volatile solute to a solvent affect the vapor pressure of the solution?

<p>Decreases vapor pressure (D)</p> Signup and view all the answers

Which equation is useful for understanding the interrelationship between vapor pressure and temperature of common liquids?

<p>Clausius-Clapeyron equation (A)</p> Signup and view all the answers

How does the boiling point of a liquid change in relation to the atmospheric pressure?

<p>Boiling point increases as atmospheric pressure increases (B)</p> Signup and view all the answers

What is the significance of the molar heat of vaporization (ΔHv) of a liquid?

<p>It represents the heat absorbed during vaporization (B)</p> Signup and view all the answers

Why do drugs with high vapor pressure have a tendency to diffuse out of tablets and vaporize?

<p>Due to their low solubility in tablet matrices (A)</p> Signup and view all the answers

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