JEE Main 2023-24: Class XI Full Test 1

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Questions and Answers

A sinusoidal traveling wave in a string has a propagation velocity of 300 m/s, and the time period of oscillations of the particles of the string is 0.04 s. What is the wavelength of the wave?

  • 12 m (correct)
  • 300 m
  • 0.0133 m
  • 7.5 m

Two identical particles execute Simple Harmonic Motion (SHM). What conditions must be met for their motions to be considered identical?

  • Different amplitude, frequency, and phase
  • Same amplitude, frequency, and phase (correct)
  • Same amplitude only
  • Same frequency and phase only

Consider a wave propagating through a medium. If the frequency of the wave is doubled while the tension in the medium remains constant, how does the velocity of the wave change?

  • The velocity is halved
  • The velocity quadruples
  • The velocity remains constant (correct)
  • The velocity doubles

Two waves with slightly different frequencies interfere to produce beats. If the frequencies of the two waves are 440 Hz and 444 Hz, what is the beat frequency?

<p>4 Hz (C)</p> Signup and view all the answers

Which of the following oxides is the most acidic?

<p>Cl2O7 (C)</p> Signup and view all the answers

A mass is attached to a spring and undergoes SHM. If the mass is doubled while keeping the spring constant the same, how does the period of oscillation change?

<p>The period increases by a factor of $\sqrt{2}$ (B)</p> Signup and view all the answers

Consider the following statements: (i) The ratio of the radii of the first three Bohr orbits of the hydrogen atom is 1 : 8 : 27. (ii) The ratio of the magnitude of Total Energy : Kinetic Energy : Potential Energy for any orbit is 1 : 1 : 2 (iii) The frequency of a green light is $6 \times 10^{14}$ Hz, (iv) The ratio of de-Broglie wavelength of a 'H' atom, 'He' atom and $CH_4$ molecule moving with equal kinetic energy is 4 : 2 : 1. which of the following options is correct?

<p>FTFT (A)</p> Signup and view all the answers

A sound wave travels from air into water. How does the wavelength of the sound wave change as it enters the water, given that the speed of sound is greater in water than in air?

<p>The wavelength increases (B)</p> Signup and view all the answers

What is the correct order of bond angles in the following species: $ClO_2^+$, $ClO_2$, $ClO_2^−$ ?

<p>$ClO_2^− &lt; ClO_2 &lt; ClO_2^+$ (A)</p> Signup and view all the answers

Two identical sound sources emit waves in phase. At a certain point, the path difference between the waves is half a wavelength ($\lambda/2$). What is the nature of the interference at this point?

<p>Destructive interference (D)</p> Signup and view all the answers

A closed organ pipe has a length $L$. What is the wavelength of the fundamental mode (first harmonic) of vibration?

<p>$4L$ (B)</p> Signup and view all the answers

In a collection of 'H' atoms, all electrons jump from n = 5 to finally the ground level (directly or indirectly). If during these transitions, no lines are emitted in the Paschen series, what is the number of possible different radiations?

<p>5 (D)</p> Signup and view all the answers

Consider the molecule $CH_3-CH_2-CH_2-CH(CH_2COOH)-COOH$. What is the number of carbons in the selected principal carbon chain for IUPAC nomenclature of this molecule?

<p>6 (C)</p> Signup and view all the answers

Which of the given options is correct?

<p>Option 1 (A)</p> Signup and view all the answers

Which combination of a diene and dienophile would you use to prepare the following compound? [Image of a Diels-Alder product]

<p>Option 1 (B)</p> Signup and view all the answers

Consider the equilibrium: $CaCO_3(s) \rightleftharpoons CaO(s) + CO_2(g)$. If the equilibrium constant is 1, what can be inferred about the reaction?

<p>The partial pressure of $CO_2$ at equilibrium is 1 atm. (A)</p> Signup and view all the answers

Which halogen, when in its reference state, exhibits the greatest absolute entropy per mole?

<p>Iodine (A)</p> Signup and view all the answers

Identify the least stable among the provided structures, considering factors like charge distribution and resonance.

<p>Structure C (B)</p> Signup and view all the answers

Which alcohol, upon heating with $H_2SO_4$, will undergo dehydration at the fastest rate?

<p>Alcohol B (C)</p> Signup and view all the answers

For the reversible reaction $I_2(g) + Br_2(g) \rightleftharpoons 2IBr(g)$, given $log K_P° = (\frac{170.2}{T} + 0.1)$, determine the absolute value of the standard Gibbs free energy change ($|\Delta_rG°|$) in kJ/mol.

<p>8 (B)</p> Signup and view all the answers

Calculate the volume of 0.02 M $Ba(OH)_2$ needed to be mixed with 40 ml of 0.02 M $NaOH$ and 20 ml of 0.01 M $HNO_3$ to obtain a solution with pH = 12.3. (Use log 2 = 0.3)

<p>40 ml (A)</p> Signup and view all the answers

How many different alkenes, upon catalytic hydrogenation, will yield iso-pentane as the sole product?

<p>2 (C)</p> Signup and view all the answers

A 50 ml solution of 0.2 M $H_2A$ is mixed with 10 ml of 0.5 M $NaOH$ at 25°C. Given $K_{a1} = 10^{-6}$ and $K_{a2} = 10^{-12}$ for $H_2A$, what is the approximate pH of the resulting solution?

<p>9 (D)</p> Signup and view all the answers

Which of the following silicon compounds, when hydrolyzed, would produce cyclic silicones?

<p>$(CH_3)_2SiCl_2$ (C)</p> Signup and view all the answers

In the redox reaction $HCl + KMnO_4 \rightarrow MnCl_2 + H_2O + Cl_2 + KCl$, what is the equivalent mass of $HCl$ in terms of its molecular mass 'M'?

<p>$\frac{10M}{16}$ (A)</p> Signup and view all the answers

Which of the following statements concerning periodic trends is incorrect?

<p>The absolute value of the electron affinity (|E.A.|) of oxygen is greater than that of chlorine. (B)</p> Signup and view all the answers

If the reaction quotient (Q) for a reversible reaction is less than 1 (Q < 1), which statement about the change in Gibbs free energy is correct?

<p>$\Delta G &gt; \Delta G^\degree$ (B)</p> Signup and view all the answers

Consider the decomposition of $CaCO_3(s)$ into $CaO(s)$ and $CO_2(g)$. Given that $\Delta G^\degree = -57.575$ kJ/mol at 2727°C, what is the pressure of $CO_2(g)$ in bar? (R = 25/3 J/mol-K)

<p>e^6.91 (B)</p> Signup and view all the answers

What is the approximate molarity of $H^+$ ions in a solution prepared by mixing 200 ml of 0.5 M $H_2SO_4$, 100 ml of 0.7 M $HNO_3$, and 100 ml of 0.3 M $HCl$? Assume the volumes are additive.

<p>1.15 M (C)</p> Signup and view all the answers

A solution contains two monoprotic acids, HA and HB. The ionization constant of HA is $1 \times 10^{-4}$ and that of HB is $1 \times 10^{-6}$. What does this indicate about their relative acid strengths at the same concentration?

<p>HA is a stronger acid than HB. (D)</p> Signup and view all the answers

Which of the following options accurately describes the impact of increased temperature on an endothermic reaction at equilibrium?

<p>The equilibrium shifts to favor the products. (A)</p> Signup and view all the answers

What is the radius of the circle defined by $Re(\frac{z}{iz - 1}) = 2$?

<p>$\frac{1}{2}$ (C)</p> Signup and view all the answers

If $x$ and $y$ represent the number of sexagesimal and centesimal seconds in an angle respectively, what is the value of $\frac{x}{y}$?

<p>$\frac{81}{250}$ (C)</p> Signup and view all the answers

Given that the derivative of $f(x)$ with respect to $x$ is $\frac{1}{2}sin^2(x)$, what is the period of $f(x)$?

<p>$\pi$ (D)</p> Signup and view all the answers

What is the value of $\frac{cos^2(33^{\circ}) - cos^2(57^{\circ})}{sin(3^{\circ}) - sin(87^{\circ})}$?

<p>$-\sqrt{3}$ (C)</p> Signup and view all the answers

A guard of 12 men is formed from a group of $n$ soldiers in all possible ways. If the number of times two particular soldiers A and B are together on guard is thrice the number of times three particular soldiers C, D, E are together on guard, then what is the value of $n$?

<p>50 (A)</p> Signup and view all the answers

How many positive integer solutions $(x, y, z)$ exist for the equation $xyz = 24$?

<p>36 (D)</p> Signup and view all the answers

What is the distance of the point $(-1, -5, -10)$ from the point of intersection of the line $\frac{x-2}{3} = \frac{y+1}{4} = \frac{z-2}{12}$ and the plane $x - y + z = 5$?

<p>13 (A)</p> Signup and view all the answers

What is the value of $lim_{x \to 0} \frac{tan(e^2x) - tan(-e^2x)}{G.I.F. [\pi + x^2]}$, where G.I.F. represents the Greatest Integer Function?

<p>$2e^2$ (C)</p> Signup and view all the answers

A wave propagates from a source. What is the phase difference between the oscillations of particles located 10 m and 16 m away from the source, respectively, given that the wavelength of the wave is 12 m?

<p>$\pi$ (D)</p> Signup and view all the answers

A uniform rod of mass m and length $\lambda$ is in equilibrium between two smooth vertical walls, as shown. The distance between the walls is d. Determine cos$\theta$ in terms of d and $\lambda$.

<p>$(\frac{2d}{\lambda})^{\frac{1}{3}}$ (B)</p> Signup and view all the answers

A cubical block of wood weighs 13 kg and has a relative density of 0.6. How much additional weight must be placed on the block for it to be 90% immersed in water?

<p>$\frac{65}{6}$ kg (B)</p> Signup and view all the answers

Given two particles oscillating according to the equations $x_1 = 4 \sin(10t + \frac{\pi}{6})$ and $x_2 = 5 \cos(\omega t)$, find the value of $\omega$ for which the energies of both particles are equal.

<p>8 (B)</p> Signup and view all the answers

A particle travels in a straight line with uniform acceleration. If the particle's average speed is u for the entire motion, what is the maximum possible speed at the midpoint of the path?

<p>$\sqrt{2}u$ (A)</p> Signup and view all the answers

A ball of mass 3kg is suspended from a bar of the same mass with a light inextensible cord. Initially the system is held at rest as shown. Determine the tension in the string immediately after the system is released. The incline is fixed and frictionless.

<p>$ \frac{3mg}{\sqrt{2}} $ (B)</p> Signup and view all the answers

Two identical simple pendulums, A and B, are set into motion such that A has twice the kinetic energy of B. Assuming their amplitudes are small, what is the ratio of the amplitude of A to the amplitude of B?

<p>$\sqrt{2}$ (D)</p> Signup and view all the answers

A point source of light emits uniformly in all directions. At a distance of 2 meters from the source, the intensity of the light is $I$. What will be the intensity at a distance of 4 meters from the source?

<p>$I/4$ (C)</p> Signup and view all the answers

Flashcards

Traveling Wave

A wave that travels through a medium, transferring energy without transferring matter.

Wave Propagation Velocity

The speed at which the crest of a wave moves through a medium.

Time Period of Oscillation

The time it takes for one complete cycle of oscillation to occur.

Simple Harmonic Motion (SHM)

Motion where an object repeatedly moves back and forth around an equilibrium position.

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Oscillation

A single back and forth movement or vibration.

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Displacement

The displacement of an object from its equilibrium position.

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SHM Equation

A mathematical representation of SHM, showing displacement as a function of time.

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Phase Difference

The difference in phase between two oscillating points.

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Equilibrium Angle

The angle a rod makes with a vertical wall when in equilibrium, dependent on distance between walls and rod length.

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Buoyant force

Weight of the object - Weight of displaced fluid

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Equal Energy Oscillations

The angular frequency (ω) at which two particles have the same energy.

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Max Speed at Midpoint

Maximum possible speed at the midpoint of a path with uniform acceleration, given the average speed.

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Tension after Release

Tension in the string immediately after the system is released. Related to acceleration and forces.

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Relative Density

The weight of the object relative to the weight of an equal volume of water.

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Most acidic oxide

Oxides of nonmetals are generally acidic. Acidity increases with the oxidation state of the nonmetal.

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Bohr Orbit Ratios and Energy

The ratio of the radii of the first three Bohr orbits of the hydrogen atom is proportional to n^2 (1:4:9). Total Energy : Kinetic Energy : Potential Energy is 1 : 1 : 2. de-Broglie wavelength is inversely proportional to the square root of mass.

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Electron Transitions

When electrons jump from n=5 to ground level and no lines are emitted in the Paschen series it means transition stop at n=3, then possible different radiation is 5.

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IUPAC Nomenclature

The principal carbon chain is selected to include the carbon in carboxylic group. Thus, the number of carbons will be 4.

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Bond Angle Order

Bond angle increases with increasing s-character and decreasing lone pair repulsion.

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Circle Radius

The radius of the circle defined by Re(iz - 1) = 2.

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Sexagesimal vs. Centesimal Seconds Ratio

Ratio between sexagesimal and centesimal seconds in an angle measure.

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Function Period

The period of a function f(x) is the smallest positive value T such that f(x + T) = f(x) for all x.

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Guards Arrangement

Finding an arrangements involving a constraint. Two soldiers together on guard.

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Integer Solutions to xyz=24

Finding positive integers (x, y, z) that when multiplied together give 24.

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Point-Line-Plane Distance

Euclidean distance between point and intersection of line and plane.

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Limit simplification of tan

Simplify the limit expression to extract greatest integer function

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cos(A) - cos(B) evaluation

cos(A) - cos(B)

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Cyclic Silicone Production

Hydrolysis of (CH3)2SiCl2 produces cyclic silicone polymers due to the two organic groups allowing chain formation and cyclization.

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Equivalent Mass in Redox

To determine equivalent mass, you must balance the redox reaction. Find the change in oxidation number for the element that is reduced or oxidised. Use this change to relate molecular mass to equivalent mass. For the given reaction the answer is M/10

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First Ionization Potential

The effective nuclear charge causes the first ionization potential of Al to be less than Mg.

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Reaction Quotient (Q) < 1

If the reaction quotient (Q) is less than 1, it indicates that the ratio of products to reactants is less than that at equilibrium. Therefore, ΔG (Gibbs Free Energy change) is less than ΔG° (standard Gibbs Free Energy change), hence ΔG° > ΔG.

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Pressure of CO2 from ΔG°

To relate Gibbs Free Energy () to pressure, use the equation = -RTln(K), where K is the equilibrium constant related to the pressure of CO2. Knowing ΔG°, solve for pressure.

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Mixing Acidic Solutions [H+]

You must find the number of moles of Hydrocloric acid (HCl), Sulfuric Acid and Nitric acid contributed by each solution, then divide by the final volume to calculate the molarity of H+ ion.

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Halogen with Greatest Entropy

The halogen with the greatest molecular weight and weakest intermolecular forces has the highest absolute entropy per mole in its reference state.

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Least Stable Structure

Less stable structures generally violate the octet rule or have formal charges on atoms that do not align with their electronegativity.

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Alcohol Dehydration Rate

Tertiary alcohols undergo dehydration most rapidly due to the formation of a more stable carbocation intermediate.

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Gibbs Free Energy

ΔrG° = -R * T * ln(Kp). The equation relates the change in Gibbs free energy to the equilibrium constant.

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Alkene Hydrogenation Product

Catalytic hydrogenation reduces alkenes to alkanes. Count the structurally distinct alkenes that yield iso-pentane.

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Stereoisomers of Natural Compound

Determine the number of chiral centers and consider possible stereoisomers.

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Buffer Solution pH

pH = pKa + log([A-]/[HA]). Since K a1 >> K a2, only consider the first dissociation. Use the Henderson-Hasselbalch equation.

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Mixed Solution pH Calculation

Use the equation pH + pOH = 14 to find the pOH, and derive the [OH-] concentration. Use the total volume and molarity to find needed volume

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Study Notes

  • JEE MAIN-2023-24 (FULL TEST-1) for CLASS-XI includes Physics, Chemistry, and Mathematics.
  • The test duration is 3 hours.
  • The test booklet contains 90 questions.
  • The maximum marks are 300.
  • There are three parts: Physics, Chemistry, and Mathematics.
  • Each part has 30 questions of equal weightage.
  • Each part contains two sections: Section-A and Section-B.

Section-A

  • Contains 20 multiple-choice questions with only one correct answer.
  • Each correct answer earns 4 marks.
  • Each incorrect answer results in a -1 mark deduction.

Section-B

  • Contains 10 questions.
  • Attempt any 5 out of the 10 questions.
  • The answer to each question is a numerical value
  • Every correct response is worth 4 marks
  • Every incorrect response means -1 mark.
  • Round off the answer to the nearest integer.

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