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Questions and Answers

What color indicates the presence of chlorine in a solution?

  • Brown
  • Colorless
  • Bright yellow
  • Very pale green (correct)

What happens when potassium bromide is combined with chlorine?

  • Bromine is displaced and a yellow solution forms (correct)
  • No reaction occurs
  • Chlorine gas is released
  • A green solution is formed

What is the significance of adding nitric acid when testing for halide ions with silver nitrate?

  • It transforms halides into nitrates
  • It reacts with carbonates to avoid interference in results (correct)
  • It increases the solubility of halides
  • It enhances the color of the precipitate

Which of the following correctly represents the reaction between chlorine and iodide ions?

<p>Cl2(aq) + 2I-(aq) → 2Cl-(aq) + I2(aq) (C)</p> Signup and view all the answers

What are the products when bromine reacts with iodide ions?

<p>Br2(aq) and 2I-(aq) (D)</p> Signup and view all the answers

What role does H2SO4 play in the reaction with NaCl?

<p>Acid (proton donor) (B)</p> Signup and view all the answers

What gas is produced when NaBr reacts with H2SO4?

<p>HBr (B)</p> Signup and view all the answers

What observation indicates the presence of HCl during the reaction between NaCl and H2SO4?

<p>White steamy fumes (C)</p> Signup and view all the answers

What is the overall reaction when bromide ions are involved with H2SO4?

<p>2NaBr + 3H2SO4 → 2NaHSO4 + SO2 + Br2 + 2H2O (C)</p> Signup and view all the answers

What is the reduction product when iodide ions reduce the sulfur in H2SO4?

<p>S (C)</p> Signup and view all the answers

What is the physical state of Bromine at room temperature?

<p>Red liquid (B)</p> Signup and view all the answers

Which halogen has the highest electronegativity?

<p>Fluorine (A)</p> Signup and view all the answers

What happens to the melting and boiling points of the halogens as you move down the group?

<p>They increase (B)</p> Signup and view all the answers

What color is Chlorine when dissolved in water?

<p>Very pale green (C)</p> Signup and view all the answers

How does the oxidizing strength of halogens change as you go down the group?

<p>It decreases down the group (C)</p> Signup and view all the answers

Which of the following halogens can displace both bromide and iodide ions from their compounds?

<p>Chlorine (A)</p> Signup and view all the answers

What effect does increasing atomic radii have on electronegativity?

<p>Decreases electronegativity (C)</p> Signup and view all the answers

What color solution indicates the presence of Iodine in a test tube?

<p>Brown (A)</p> Signup and view all the answers

What color precipitate is produced when Ag+ reacts with I-?

<p>Pale yellow (C)</p> Signup and view all the answers

Which of the following halides produces a white precipitate when reacted with Ag+?

<p>Chloride (C)</p> Signup and view all the answers

What is the result of treating AgBr with concentrated ammonia?

<p>It forms a colorless solution. (B)</p> Signup and view all the answers

Why do fluoride and chloride ions not act as reducing agents in reactions with concentrated sulfuric acid?

<p>They are much weaker reducing agents. (B)</p> Signup and view all the answers

What is formed when NaF reacts with H2SO4?

<p>NaHSO4 and HF (D)</p> Signup and view all the answers

How does the reducing power of halides change within group 7 elements?

<p>It increases as you move down the group. (A)</p> Signup and view all the answers

What happens to silver iodide (AgI) when treated with ammonia?

<p>It does not react due to its insolubility. (D)</p> Signup and view all the answers

What is the product of the reaction between Ag+ and Br- ions?

<p>AgBr(s) (B)</p> Signup and view all the answers

What is the role of H2SO4 in the first step of the reaction involving Iodine?

<p>It plays the role of an acid. (D)</p> Signup and view all the answers

Which product is NOT formed in the redox reactions involving H2SO4 and iodide ions?

<p>Oxygen (O2) (B)</p> Signup and view all the answers

What is the characteristic smell of Hydrogen sulfide (H2S) often compared to?

<p>Rotten eggs (D)</p> Signup and view all the answers

In the disproportionation of chlorine, which of the following reactions occurs?

<p>Chlorine is oxidized while chlorine atoms are reduced. (B)</p> Signup and view all the answers

What happens to the greenish color of chlorine water when it reacts in sunlight?

<p>It fades as chlorine reacts and O2 is produced. (B)</p> Signup and view all the answers

During the reaction of chlorine with water, what is formed along with HCl?

<p>HClO (A)</p> Signup and view all the answers

What is the benefit of chlorine in water treatment?

<p>It kills bacteria effectively. (D)</p> Signup and view all the answers

Which of the following statements about the product of disproportionation reactions of chlorine is incorrect?

<p>Both HCl and HClO turn the water green. (C)</p> Signup and view all the answers

Flashcards

Halogen Reactivity Trend

Reactivity of halogens decreases down the group. Stronger oxidising agents displace weaker ones.

Halogen Oxidising Strength

Halogens' ability to gain electrons. Chlorine is a stronger oxidising agent than bromine, which is stronger than iodine.

Displacement Reaction

A stronger halogen displaces a weaker halogen from a compound.

Electronegativity

The ability of an atom to attract electrons in a covalent bond.

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Halogen Melting/Boiling Point Trend

Melting and boiling points increase down the group due to increasing van der Waals forces.

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van der Waals Forces

Weak intermolecular forces between molecules caused by temporary dipoles.

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Halide Ions

Ions formed from halogens by gaining an electron; e.g., Cl⁻.

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Halogen Colour Tests

Different colours reveal the presence of particular free halogens (colour of solution indicates specific halogen).

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Halide Ion Reactions

Reactions between chlorine, bromine, and iodine in solution with potassium halide ions (bromide and iodide). These reactions show how reactivity increases down the group.

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Oxidizing Power of Halogens

Halogens (Cl2, Br2, I2) can act as oxidizing agents; they accept electrons and are reduced. This is demonstrated by chlorine displacing bromine and iodine from potassium bromide and potassium iodide solutions.

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Halogens Displacing Reactions

Chlorine displaces bromine and iodine, bromine displaces iodine. This shows reactivity trends down the halogen group. A more reactive halogen will displace a less reactive one!

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Halide Test with Silver Nitrate

Adding silver nitrate to an acidic solution of halide ions produces different coloured precipitates based on the halide ion present. Nitric acid is used to remove carbonate interference.

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Role of Nitric Acid in Halide Test

Nitric acid is added to remove carbonate ions, preventing the formation of a silver carbonate precipitate that would interfere with the silver halide precipitations.

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H2SO4's role in acid-base reactions

H2SO4 acts as a proton donor (acid) in reactions with metal halides, producing hydrogen halide gases.

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Reducing agent strength (halides)

Bromide (Br⁻) ions are stronger reducing agents than chloride (Cl⁻) or fluoride (F⁻) ions, meaning they readily lose electrons.

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Redox reaction with H2SO4

H2SO4, in the presence of bromide or iodide ions, can act as an oxidizing agent in reducing the sulfur from +6 to +4 oxidation state.

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Iodide ion reduction products

Iodide ions (I⁻) are the strongest reducing agents among the halides, capable of reducing H2SO4 to various oxidation products, like sulfur.

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Overall equation for NaBr and H2SO4 reaction

2NaBr + 3H2SO4 → 2NaHSO4 + SO2 + Br2 + 2H2O

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Halide Precipitate Color

The color of the precipitate formed when silver ions react with halide ions (Cl-, Br-, I-).

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Ammonia Effect on Silver Halides

Concentrated ammonia dissolves silver bromide, dilute ammonia dissolves silver chloride, and silver iodide does not dissolve in ammonia.

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Reducing Power of Halides

The ability of halide ions (F-, Cl-, Br-, I-) to donate electrons, increasing down the group.

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Halide Reaction with H2SO4 (Fluoride and Chloride)

Fluoride and Chloride ions react with sulfuric acid via acid-base reactions, not redox reactions.

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Reducing Agent

A substance that donates electrons in a chemical reaction.

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Acid-Base Reaction

A chemical reaction where an acid and a base neutralize each other.

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Redox Reaction

A chemical reaction involving the transfer of electrons between reactants.

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HF Reaction Observation

Formation of white steamy fumes of hydrogen fluoride (HF) gas during the reaction of fluoride with sulfuric acid.

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Redox Reaction in I2 production

A chemical reaction involving both oxidation and reduction. H2SO4, acts as both acid and oxidizing agent, oxidizing iodine and reducing itself to SO2, S, or H2S.

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Disproportionation Reaction

A reaction where a single substance is both oxidized and reduced.

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Chlorine and water reaction

Chlorine gas reacts with water to produce hypochlorous acid (HClO) and hydrochloric acid (HCl).

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Chlorine's use in water treatment

Chlorine is used to kill bacteria in water treatment systems.

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Oxidation half-reaction

The process where a substance loses electrons.

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Reduction half-reaction

The process where a substance gains electrons.

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Hydrogen Sulfide

A gas (H₂S) with a characteristic foul smell like rotten eggs

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Sulfur Dioxide

A colorless gas (SO2) containing sulfur.

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