IR Spectra of Functional Groups
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Questions and Answers

What is the wavenumber range (cm-1) for the C=O bond in infrared spectroscopy?

  • 3200-3600
  • 1450-1600
  • 1650-1850 (correct)
  • 2100-2200
  • Which bond has a characteristic IR range of 2800-3000 cm-1?

  • C=O
  • O–H
  • sp C–H (correct)
  • N–H
  • Which of the following bonds can be identified by a wavenumber range of 2200-2300 cm-1?

  • C=O
  • C=C (alkene)
  • C≡N (correct)
  • N–H
  • At which wavenumber range would you expect to find the characteristic signal for sp2 C–H bonds?

    <p>3000-3100</p> Signup and view all the answers

    What is the approximate wavenumber range for the C≡C bond in IR spectroscopy?

    <p>2100-2200</p> Signup and view all the answers

    What is the characteristic wavenumber range for an N–H bond in infrared spectroscopy?

    <p>3350-3500 cm-1</p> Signup and view all the answers

    Which bond would be indicated by a range of 2100-2200 cm-1 in infrared spectroscopy?

    <p>C≡C</p> Signup and view all the answers

    At approximately what wavenumber range would you observe an aromatic C=C bond in infrared spectroscopy?

    <p>1450-1600 cm-1</p> Signup and view all the answers

    Which of the following represents the range for the sp C–H bond?

    <p>3267-3333 cm-1</p> Signup and view all the answers

    What is the range that indicates the C=O bond in infrared spectroscopy?

    <p>1650-1850 cm-1</p> Signup and view all the answers

    Study Notes

    Characteristic IR Band Ranges

    • The IR spectra of organic molecules can be used to identify the presence of different functional groups.
    • C=C bonds, both aromatic and alkene, have a characteristic IR absorption in the region of 1450-1700 cm-1.
    • C=O bonds, commonly found in ketones, aldehydes, and carboxylic acids, have a strong absorption in the region of 1650-1850 cm-1.
    • C≡C bonds have a characteristic IR absorption in the region of 2100-2200 cm-1.
    • C≡N bonds have a characteristic IR absorption in the region of 2200-2300 cm-1.
    • sp3 C–H bonds have a characteristic IR absorption in the region of 2800-3000 cm-1.
    • sp2 C–H bonds have a characteristic IR absorption in the region of 3000-3100 cm-1.
    • sp C–H bonds have a characteristic IR absorption in the region of 3267-3333 cm-1.
    • N–H bonds have a characteristic IR absorption in the region of 3350-3500 cm-1.
    • O–H bonds have a characteristic IR absorption in the region of 3200-3600 cm-1.

    Characteristic 1H NMR Chemical Shifts

    • The 1H NMR spectrum of a molecule can be used to identify the types of protons present in the molecule.
    • Protons attached to sp3 hybridized carbons typically appear in the region of 0-3 ppm.
    • Protons attached to sp2 hybridized carbons typically appear in the region of 4-7 ppm.
    • Protons attached to aromatic rings typically appear in the region of 6-8 ppm.
    • Protons attached to aldehydes typically appear in the region of 9-10 ppm.
    • Protons attached to carboxylic acids typically appear in the region of 10-12 ppm.

    Characteristic IR Band Ranges

    • C=C (aromatic) bonds are present between 1450-1600 cm-1
    • C=C (alkene) bonds are present between 1600-1700 cm-1
    • C=O bonds are present between 1650-1850 cm-1
    • C≡C bonds are present between 2100-2200 cm-1
    • C≡N bonds are present between 2200-2300 cm-1
    • sp3 C–H bonds are present between 2800-3000 cm-1
    • sp2 C–H bonds are present between 3000-3100 cm-1
    • sp C–H bonds are present between 3267-3333 cm-1
    • N–H bonds are present between 3350-3500 cm-1
    • O–H bonds are present between 3200-3600 cm-1

    Characteristic 1H NMR Chemical Shifts

    • Proton chemical shifts provide insights into the chemical environment of protons in a molecule.
    • The values are expressed in parts per million (ppm).

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    Description

    This quiz explores the characteristic IR band ranges used to identify functional groups in organic molecules. Participants will test their knowledge of the absorption ranges for various bonds, including C=C, C=O, and N–H. It's an essential quiz for students studying organic chemistry and spectroscopy.

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