Introduction to Mass Spectrometry

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Questions and Answers

What happens when molecules in gas state are bombarded with high energy electrons?

  • They gain an electron and form a radical cation
  • They break down into smaller molecules
  • They lose an electron and form a molecular ion (M+) (correct)
  • They remain unchanged

What does mass spectrometry provide information about?

  • Physical state of the molecule
  • Isotopic composition of the molecule
  • Chemical reactions of the molecule
  • Exact molecular weight and molecular formula (correct)

What does the intensity of each signal in mass spectrometry represent?

  • Molecular weight of the cations
  • Relative abundance of the radicals
  • Molecular weight of the radicals
  • Relative abundance of the cations (correct)

What is a molecular ion (M+)?

<p>A radical cation with a positive charge and one unpaired electron, representing the mass of the original molecule (D)</p> Signup and view all the answers

What is separated by magnetic deflection in mass spectrometry?

<p>Cations based on their (m/z) ratio (C)</p> Signup and view all the answers

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Study Notes

Mass Spectrometry

  • When molecules in a gas state are bombarded with high-energy electrons, they break into charged particles called ions.
  • Mass spectrometry provides information about the mass-to-charge ratio of ions, which helps identify the structure of molecules.

Signal Intensity

  • The intensity of each signal in mass spectrometry represents the abundance of ions with a specific mass-to-charge ratio.

Molecular Ion

  • A molecular ion (M+) is a molecule that has lost or gained one or more electrons to form an ion with a single charge.

Ion Separation

  • In mass spectrometry, ions are separated by magnetic deflection according to their mass-to-charge ratio.

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