Introduction to Environmental Chemistry
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Questions and Answers

What was the primary composition of the Earth's primitive atmosphere?

  • Hydrogen and helium with simple compounds (correct)
  • Nitrogen and oxygen
  • Methane and water vapor
  • Carbon dioxide and ammonia

Which event contributed significantly to the formation of the secondary atmosphere on Earth?

  • The formation of the ozone layer
  • The collision of Earth with asteroids
  • Volcanic activity releasing gases (correct)
  • The extinction of dinosaurs

What was the role of water vapor in the early secondary atmosphere?

  • To condense and form clouds and oceans (correct)
  • To contribute to climate change
  • To increase the levels of carbon monoxide
  • To create a protective layer against solar winds

Which gases were primarily produced from the breakdown of ammonia in the early atmosphere?

<p>Nitrogen and hydrogen (B)</p> Signup and view all the answers

How did the early Earth lose its primitive atmosphere?

<p>Due to the absence of a magnetic field and solar winds (D)</p> Signup and view all the answers

What process led to the formation of oxygen in the atmosphere?

<p>The photochemical dissociation of water vapor (B)</p> Signup and view all the answers

Which gases were present in trace amounts in the secondary atmosphere?

<p>Hydrogen sulfide, sulfur dioxide, and chlorine (C)</p> Signup and view all the answers

What primary factor contributed to the cooling of the atmosphere leading to the formation of oceans?

<p>The solidification of the Earth’s crust (D)</p> Signup and view all the answers

What was the primary by-product of the photosynthesis performed by cyanobacteria?

<p>Oxygen (A)</p> Signup and view all the answers

Which process led to the rise in oxygen levels in the atmosphere after the oxidation of surface rocks?

<p>Oxidation of metals (C)</p> Signup and view all the answers

What transformation occurs to O2 molecules in the atmosphere as they absorb UV radiation?

<p>They are converted to ozone (O3) (D)</p> Signup and view all the answers

What is the Karman Line known for?

<p>It marks the boundary between the atmosphere and outer space (C)</p> Signup and view all the answers

Who are credited with the discovery of oxygen in the 1770s?

<p>Joseph Priestly and Carl Wilhelm Scheele (C)</p> Signup and view all the answers

Which element was discovered in the 1840s and is associated with the ozone layer?

<p>Ozone (C)</p> Signup and view all the answers

What comprises the mixture of gases that makes up the atmosphere?

<p>Gases only (C)</p> Signup and view all the answers

What effect did the formation of the ozone layer have on life on Earth?

<p>It allowed for the sustainability of life (A)</p> Signup and view all the answers

What is the principal reason that hard water does not dissolve with soap effectively?

<p>It contains higher concentrations of magnesium ions. (A)</p> Signup and view all the answers

Which of the following best describes the impact of environmental soil chemistry?

<p>It investigates chemical reactions affecting ecological health. (B)</p> Signup and view all the answers

What is the smallest unit of soil that includes all horizons from the surface to the underlying geologic strata?

<p>Pedon (C)</p> Signup and view all the answers

Which of the following elements is the most prevalent in soils and the Earth's crust?

<p>Oxygen (B)</p> Signup and view all the answers

What defines a polypedon in soil science?

<p>It is a collection of similar pedons in a given area. (C)</p> Signup and view all the answers

Which cation is NOT typically associated with responsible hardness in water?

<p>Sodium (D)</p> Signup and view all the answers

In the context of soil chemistry, what are 'peds'?

<p>Aggregates formed from sand, silt, and clay particles. (A)</p> Signup and view all the answers

Hard water typically originates from which type of geographical area?

<p>Areas where limestone formations are prevalent. (A)</p> Signup and view all the answers

What is the primary consequence of high water temperatures on fish metabolism?

<p>Reduced survival due to higher metabolic demands (D)</p> Signup and view all the answers

Which of the following statements correctly describes the role of alkalinity in water bodies?

<p>Bicarbonates are primary contributors to water alkalinity (A)</p> Signup and view all the answers

What is the effect of thermal pollution on dissolved oxygen levels in water bodies?

<p>It decreases dissolved oxygen by promoting stratification (B)</p> Signup and view all the answers

Which factor is primarily responsible for the creation of CO2 acidity in water bodies?

<p>Dissolved carbon dioxide in the water (B)</p> Signup and view all the answers

What is a common result of low levels of dissolved oxygen in aquatic systems?

<p>Fish kills and decline of aquatic life (D)</p> Signup and view all the answers

What is a significant source of acidity in water from industrial activities?

<p>Sulfuric acid from metallurgical industries (D)</p> Signup and view all the answers

How does dissolved oxygen directly contribute to aquatic ecosystems?

<p>It supports respiration in aquatic organisms (A)</p> Signup and view all the answers

Which of the following best describes the impact of temperature on water chemistry?

<p>Higher temperatures decrease the solubility of gases (D)</p> Signup and view all the answers

What contributes to groundwater pollution in addition to sewage?

<p>Nitrogenous fertilizers and toxic wastes (B)</p> Signup and view all the answers

Why is it difficult to trace the source of groundwater pollution?

<p>Impurities can move over large distances. (B)</p> Signup and view all the answers

What is the effect of not having access to air on groundwater?

<p>It prevents the oxidation of pollutants. (D)</p> Signup and view all the answers

What is thermal stratification?

<p>The phenomenon of temperature variation between water layers. (B)</p> Signup and view all the answers

Which layer of water is exposed to sunlight and has a higher temperature?

<p>Epilimnion (D)</p> Signup and view all the answers

What is the role of the thermocline in a thermally stratified body of water?

<p>It separates the epilimnion from the hypolimnion. (D)</p> Signup and view all the answers

What is a consequence of warm temperatures on the density of a water body?

<p>It lowers the density of the epilimnion. (D)</p> Signup and view all the answers

Which of the following is NOT a factor that affects water quality?

<p>Depth of physical structure (A)</p> Signup and view all the answers

What is the primary function of a surfactant in the leaching process?

<p>To lower the surface tension of water for removing contaminants (C)</p> Signup and view all the answers

Which of the following non-in-situ techniques involves the use of extreme heat?

<p>Thermal Treatment (C)</p> Signup and view all the answers

How long can contaminants be immobilized using the vitrification method?

<p>Up to 10,000 years (B)</p> Signup and view all the answers

What is a significant drawback of the leaching method?

<p>It produces large volumes of wastewater and high disposal costs (B)</p> Signup and view all the answers

Which method involves adding contaminated soil to hot asphalt?

<p>Asphalt Incorporation (A)</p> Signup and view all the answers

What adjustment is made during land treatment to assist in the decontamination process?

<p>Adjust the soil pH to 7.0 (C)</p> Signup and view all the answers

What is the main concept behind solidification/stabilization techniques?

<p>Contaminants are encapsulated with additives (A)</p> Signup and view all the answers

Which of the following is a challenge posed by the thermal treatment method?

<p>High operational costs due to energy consumption (A)</p> Signup and view all the answers

Flashcards

Primitive Atmosphere

The early atmosphere of Earth, primarily composed of hydrogen and helium, and simple compounds like ammonia and methane.

Secondary Atmosphere

The Earth's atmosphere formed after the primitive atmosphere, mostly water vapor, carbon dioxide, and ammonia.

Oxidizing Atmosphere

Earth's atmosphere after oxygen began to accumulate, due to chemical processes such as photochemical dissociation.

Photochemical Dissociation

The breakdown of water molecules by strong ultraviolet radiation, a process that releases oxygen.

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Earth's Early Atmosphere Composition

Primarily Hydrogen and Helium, with Simple Compounds such as Ammonia and Methane.

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Reducing Atmosphere

An atmosphere rich in gases that can easily gain electrons (reducing agents).

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Volcanic Activity's Role

Volcanic eruptions release gases from Earth's interior, contributing to the formation of the secondary atmosphere.

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Formation of Oceans

Water vapor from volcanic eruptions condensed into clouds, eventually forming the oceans by precipitation.

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Ground Water Pollution Source

Nitrogenous fertilizers, toxic wastes and sewage contaminate ground water, especially in areas with high water tables.

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Ground Water Movement

Ground water can flow long distances underground, making it difficult to trace pollution sources.

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Ground Water Oxidation

Lack of air in ground water prevents oxidation, making pollutant breakdown difficult.

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Thermal Stratification

The separation of water layers due to temperature differences, creating distinct environments.

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Epilimnion Layer

The upper layer of a stratified water body, warmer and exposed to sunlight, supporting abundant algae growth.

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Hypolimnion Layer

The lower layer of a stratified water body, colder and less oxygenated, supporting different life forms.

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Thermocline Layer

The transitional layer between the epilimnion and hypolimnion, characterized by rapid temperature change.

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Water Quality Factors

Physical factors like temperature significantly influence chemical and biological processes in water.

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Hypolimnion

The bottom layer of a lake or pond, characterized by low oxygen levels due to the decomposition of organic matter.

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Dissolved Oxygen (DO)

The amount of oxygen gas dissolved in water, essential for aquatic organisms to breathe.

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Alkalinity

The ability of water to neutralize acids, mainly due to the presence of bicarbonates.

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CO2 Acidity

Acidity in water caused by dissolved carbon dioxide.

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Thermal Pollution

The release of heated water into a water body, often from industrial processes, causing a rise in water temperature.

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Metabolic Rate

The rate at which an organism uses energy for essential life processes.

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What is the main cause of low dissolved oxygen (DO) in the hypolimnion?

The decomposition of organic matter consumes oxygen, leading to low DO levels in the deeper layers of water.

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Why is alkalinity important for water?

Alkalinity acts as a buffer, preventing sudden drops in pH due to acid addition, protecting aquatic life.

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Cyanobacteria

Microscopic organisms that were the first to perform photosynthesis, releasing oxygen as a byproduct.

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Photosynthesis Equation

The chemical reaction where plants use sunlight, carbon dioxide, and water to produce glucose (sugar) and oxygen: 6CO2 + 6H2O + sunlight → C6H12O6 + 6O2

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Oxidation of Metals

A chemical process where oxygen reacts with metals, causing them to lose electrons and form oxides. Early Earth's iron was oxidized by oxygen released from cyanobacteria.

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Ozone Layer Formation

Oxygen molecules (O2) in the atmosphere absorb UV radiation, splitting into single oxygen atoms which then combine with more O2 to form ozone (O3).

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Earth's Atmosphere

The layer of gases surrounding Earth, protecting life and making our planet unique in the solar system.

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Karman Line

An imaginary boundary between Earth's atmosphere and outer space, generally considered to be at an altitude of 100 kilometers (62 miles).

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Atmospheric Composition

The mixture of gases that make up the atmosphere, primarily Nitrogen (N2) and Oxygen (O2), with smaller amounts of other gases like Argon (Ar), Carbon Dioxide (CO2), and trace amounts of others.

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Discovery of Atmospheric Gases

Over time, scientists have discovered and identified the main components of Earth's atmosphere.

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pH Level of Water

A measurement of how acidic or basic water is, typically maintained between 6 and 9.5 for healthy ecosystems.

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Water Hardness

Caused by dissolved divalent metallic cations like calcium and magnesium, primarily found in areas with limestone formations.

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Soil Chemistry

The study of the chemical composition, properties, and reactions of soils.

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Environmental Soil Chemistry

A branch of soil chemistry that examines the interactions between soils and contaminants, like metals and organic chemicals.

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Soil Components

The solid portion of soil is made up of inorganic sand, silt, clay, and organic matter.

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Peds

Soil aggregates formed by the clumping of sand, silt, and clay particles, creating a larger soil structure.

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Soil Profiles

Horizontal layers in soil, showing differences in texture, structure, and other properties.

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Pedon

The smallest unit considered 'soil', including all horizons from the surface to the underlying rock.

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Leaching

A method of soil remediation where contaminants are removed using water and a surfactant that reduces surface tension. The contaminated water (leachate) is then collected and treated.

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Vitrification

A remediation method that uses electric current to solidify contaminants, immobilizing them for thousands of years.

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Land Treatment

Contaminated soil is spread over land to allow natural processes like biodegradation to break down pollutants. Soil pH is adjusted to help the process.

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Thermal Treatment

Soil is heated in a thermal incinerator to break down pollutants. The released gases can be burned or recovered.

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Asphalt Incorporation

Contaminated soil is mixed with hot asphalt, causing pollutants to volatilize or decompose. The remaining pollutants are immobilized in the asphalt.

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Solidification/Stabilization

An additive is mixed with contaminated soil, encapsulating contaminants and preventing their spread. The treated soil is then landfilled.

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What is a surfactant?

A surfactant is a chemical compound that reduces the surface tension of a liquid, allowing it to spread and mix more easily with other substances.

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What is biodegradation?

A process where microorganisms break down organic compounds into simpler substances, often releasing energy and carbon dioxide.

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Study Notes

Introduction to Environmental Chemistry

  • Our environment, comprising air, land, water, and climate, is complex.
  • Chemistry is crucial for understanding, monitoring, protecting, and improving the environment.
  • Chemists develop tools and techniques to analyze and measure pollutants in air and water.
  • They also study how climate changes over time.

The Formation of the Atmosphere

  • Primitive Atmosphere: Early Earth, a molten rock, had an atmosphere primarily composed of hydrogen and helium, along with ammonia and methane.
  • Secondary Atmosphere: As Earth cooled, volcanic activity released gases (primarily water vapor, carbon dioxide, and ammonia) forming a reducing atmosphere, similar to that of Mars and Venus today.
  • Oxidizing Atmosphere: Photochemical dissociation of water vapor by ultraviolet radiation produced oxygen, but the amount was negligible.
  • Photosynthesis: Most of Earth's oxygen was produced by cyanobacteria via photosynthesis.

Atmospheric Chemistry

  • Atmosphere: The thick mixture of gases surrounding Earth.
  • Air: A term for the mixture of gases in the atmosphere, held near the surface by gravity.
  • Karman Line: The imaginary line marking the boundary between Earth's atmosphere and outer space.
  • Important Discoveries: Various elements and compounds were discovered over time (e.g., nitrogen, oxygen, carbon dioxide, argon, etc.) by different scientists.

Water Chemistry

  • Water: A chemical compound (Hâ‚‚O) with strong covalent bonds, a bond angle of 105 degrees in liquid water.
  • Water's Properties:
    • Excellent solvent due to its high dielectric strength.
    • Cohesive & adhesive properties due to hydrogen bonds, leading to a high surface tension.
    • High specific heat capacity.
    • Expands when freezing, making ice less dense than liquid water.
    • High latent heat of fusion and vaporization, enabling various phase changes.

Soil Chemistry

  • Soil: A heterogeneous mixture of air, water, inorganic and organic solids, plus microorganisms.
  • Inorganic Components: Primarily sand, silt, and clay particles, which aggregate to form larger soil structures and contribute to soil formation.
  • Organic Components (Humus): Undecayed plant and animal remains plus their decomposition products, which are vital for soil chemistry.
  • Soil Properties affected by temperature: The amount of gas that can be dissolved in water, the rate of photosynthetic action, metabolism of aquatic organisms.
  • pH level of Water: The pH level of bodies of water is usually maintained between 6 and 9.5.

Water Pollution

  • Surface Water Pollution: Point sources (directly affecting water bodies) and non-point sources (indirectly affecting water bodies) including natural and anthropogenic (human-made).
  • Ground Water Pollution: Raw sewage, septic tanks, and other water pollutants that seep into aquifers. Sources of groundwater pollution are difficult to trace due to the large spaces below the Earth's surface.
  • Water Pollutants (Types): Pathogens, organic pollutants (oils, greases, pesticides, plastics, detergents), inorganic pollutants (fertilizers, nitrates, acids), Radioactive materials, heat, and sediments.

Factors Affecting Water Quality

  • Temperature impacts various chemical and biological processes in water.
  • Thermal stratification (distinct layers based on temperature) affects oxygen levels, aquatic life, and other aspects of the water.

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Explore the interactions between chemistry and the environment in this quiz. Delve into the formation of the atmosphere and understand the role of chemists in monitoring pollutants and studying climate changes. Test your knowledge on these foundational concepts in environmental chemistry.

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