Intro to Thermodynamics

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Questions and Answers

An office worker claims their cold coffee warmed to 80°C by absorbing energy from the 25°C air. Is this plausible? Does it violate thermodynamic laws?

This is not plausible and violates the second law of thermodynamics, which states that heat cannot spontaneously flow from a colder body to a warmer body without external work being done.

What is the net force acting on a car moving at a constant velocity on a level road and on an uphill road?

On a level road, the net force is zero. On an uphill road, assuming constant velocity, the net force is also zero. This implies the driving force equals the gravitational force component acting downhill.

A car engine's radiator rejects heat to the air via circulating water. Should the radiator be modeled as a closed or open system? Explain.

The radiator should be analyzed as an open system because mass (water) crosses the system boundary as it circulates to remove heat.

To understand a reciprocating air compressor, what type of thermodynamic system is most appropriate? Why?

<p>A closed system (control mass) is appropriate because the same mass of air is being compressed within the piston-cylinder device. While energy crosses the boundary, no mass does.</p> Signup and view all the answers

A room-temperature soft drink can is placed in a refrigerator. Should it be modeled as a closed or open system to analyze its cooling process? Explain.

<p>It is best modeled as a closed system. The mass of the soft drink remains constant (no mass flow in or out), while energy (heat) is transferred out of the can.</p> Signup and view all the answers

What are intensive and extensive properties? Give an example of each.

<p>Intensive properties are independent of system size (e.g., temperature, pressure). Extensive properties depend on system size (e.g., mass, volume).</p> Signup and view all the answers

Is the weight of a system an intensive or extensive property? Explain why.

<p>Weight is an extensive property because it depends on the mass of the system, which is an extensive property. Weight = mass * gravitational acceleration ($W = mg$).</p> Signup and view all the answers

A rigid container is filled with a mixture of air and fuel. Is the density of the mixture an intensive or extensive property? Explain.

<p>Density is an intensive property. Even though it's calculated using mass (extensive) and volume (extensive), the ratio itself does not depend on the system's size.</p> Signup and view all the answers

Describe the difference between a steady-flow process and a transient process. Give an example of each.

<p>In a steady-flow process, properties within the control volume do not change with time (e.g., a turbine operating at constant conditions). In a transient process, properties change with time (e.g., inflating a balloon).</p> Signup and view all the answers

A pressure cooker is sealed and heated on a stove. Is this best modeled as a closed system or an open system? Explain.

<p>It is best modeled as a closed system because no mass is allowed to cross the boundary of the pressure cooker. Energy in the form of heat is transferred into the system.</p> Signup and view all the answers

Define thermodynamic equilibrium. What conditions must be met for a system to be in thermodynamic equilibrium?

<p>Thermodynamic equilibrium implies a state where there are no changes in macroscopic properties. It requires thermal, mechanical, phase, and chemical equilibrium.</p> Signup and view all the answers

During a hot summer day, you notice water droplets forming on the outside of a cold beverage can. Is this an example of a closed or open system interaction? Explain.

<p>This demonstrates an open system interaction. Water vapor from the surroundings (the air) is condensing and depositing mass onto the can.</p> Signup and view all the answers

Explain the zeroth law of thermodynamics and its significance.

<p>The zeroth law states that if two systems are each in thermal equilibrium with a third system, then they are in thermal equilibrium with each other. It provides the basis for temperature measurement.</p> Signup and view all the answers

Describe how a thermometer works in terms of achieving thermal equilibrium.

<p>A thermometer works by coming into thermal contact with the object being measured. It exchanges energy until both the thermometer and object reach the same temperature (thermal equilibrium), which then the thermometer displays.</p> Signup and view all the answers

Why is it important to define a system boundary when analyzing a thermodynamic problem?

<p>Defining a system boundary is crucial because it identifies the region of interest for analysis and determines what interactions (mass, energy) occur between the system and its surroundings.</p> Signup and view all the answers

What is the difference between gauge pressure and absolute pressure? How are they related?

<p>Gauge pressure is the pressure relative to atmospheric pressure, while absolute pressure is the total pressure. Absolute pressure equals gauge pressure plus atmospheric pressure.</p> Signup and view all the answers

Describe the concept of specific volume. How is it related to density?

<p>Specific volume is the volume per unit mass ($ u = V/m$). It is the inverse of density ($ u = 1/ ho$).</p> Signup and view all the answers

Explain what is meant by the term 'state postulate'.

<p>The state postulate states that the state of a simple compressible system is completely specified by two independent, intensive properties.</p> Signup and view all the answers

What is the difference between energy transfer by heat and energy transfer by work? Give an example of each.

<p>Heat is energy transfer due to a temperature difference (e.g., heat transfer from a hot stove to a pan). Work is energy transfer not caused by a temperature difference (e.g., a piston compressing a gas).</p> Signup and view all the answers

Explain the concept of quasi-equilibrium process. Why is it important in thermodynamics?

<p>A quasi-equilibrium process is one that occurs slowly enough that the system remains infinitesimally close to equilibrium at all times. It simplifies analysis because properties are uniform and well-defined.</p> Signup and view all the answers

Flashcards

Cold coffee warming up claim

No, this claim is not true, as it violates the second law of thermodynamics, which states that heat cannot spontaneously flow from a colder to a hotter body.

Net force on a car at constant velocity

The net force is zero when cruising at a constant velocity, as there is no acceleration in either scenario.

Radiator as a thermodynamic system

The radiator should be analysed as an open system, as mass (air) crosses the boundary.

Reciprocating air compressor (piston-cylinder)

This is an example of a closed system, where energy can be transferred, but mass cannot.

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Cooling a soft drink can

Model the can as a closed system, as no mass is exchanged, with heat transfer to the fridge.

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Intensive vs. Extensive Properties

Intensive properties do not depend on the size or extent of the system (e.g., temperature, pressure), while extensive properties do (e.g., mass, volume).

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Weight: Intensive or Extensive?

Weight is an extensive property because it depends on the mass of the system.

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Study Notes

  • A1 - Introduction to Thermodynamics

Question 1

  • An office worker claims their cold coffee warmed up to 80°C by absorbing energy from the 25°C surrounding air.
  • There is no truth to this claim.
  • This process violates the second law of thermodynamics.
  • Heat transfer occurs from a higher temperature to a lower temperature.
  • The surrounding air at 25°C cannot spontaneously heat the coffee to 80°C.

Question 2

  • Net force on a car cruising at a constant velocity on a level road: zero.
  • Net force on a car cruising at a constant velocity on an uphill road: zero.
  • Constant velocity implies no acceleration according to Newton's First Law.
  • If there is no acceleration, the net force acting on the car is zero.

Question 3

  • A car radiator should be analyzed as an open system.
  • A large fraction of thermal energy is rejected to the air by the radiator using circulating water.
  • The radiator exchanges both energy (heat) and mass (circulating water) with its surroundings.
  • An open system allows both mass and energy transfer across its boundaries.

Question 4

  • A reciprocating air compressor (piston-cylinder device) should be analyzed as a closed system.
  • The air inside the cylinder is compressed, but no mass crosses the system boundary (the cylinder walls).
  • A closed system allows energy transfer (work, heat), but no mass transfer across its boundaries.

Question 5

  • A can of soft drink being cooled in a refrigerator can be modeled as a closed system.
  • The mass of the soft drink remains constant.
  • Only energy (heat) is transferred from the can to the refrigerator compartment.
  • A closed system involves energy transfer, but not mass transfer.

Question 6

  • Intensive properties: do not depend on the size or extent of the system (e.g., temperature, pressure, density).
  • Extensive properties: depend on the size or extent of the system (e.g., mass, volume, total energy).

Question 7

  • The weight of a system is an extensive property.
  • Weight depends on the mass of the system.
  • The greater the mass of the system, the higher the weight.
  • Extensive properties are additive; weight increases with system size.

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