Podcast
Questions and Answers
What percentage of exhaust gases from gasoline and diesel engines is typically composed of carbon dioxide?
What percentage of exhaust gases from gasoline and diesel engines is typically composed of carbon dioxide?
- Approximately 14% (correct)
- Approximately 5%
- Approximately 25%
- Approximately 35%
Which of the following is NOT a primary product of ideal, complete combustion of pure fuel?
Which of the following is NOT a primary product of ideal, complete combustion of pure fuel?
- H2O
- CO2
- N2
- CO (correct)
What is the approximate range of nitrogen oxides (NOx) emitted by spark ignition (SI) engines?
What is the approximate range of nitrogen oxides (NOx) emitted by spark ignition (SI) engines?
- 100 to 300 ppm
- 10 to 100 ppm
- 500 to 10000 ppm
- 500 to 1000 ppm (correct)
What is the primary method of reducing the amount of carbon dioxide emissions from internal combustion engines?
What is the primary method of reducing the amount of carbon dioxide emissions from internal combustion engines?
What is the primary composition of particulate matter emitted by diesel engines?
What is the primary composition of particulate matter emitted by diesel engines?
What is the approximate reduction in tailpipe emissions achieved by catalytic converters?
What is the approximate reduction in tailpipe emissions achieved by catalytic converters?
Which of these is a significant source of organic compounds in the exhaust of spark ignition engines?
Which of these is a significant source of organic compounds in the exhaust of spark ignition engines?
Which of the following is NOT typically a result of diesel engine emissions?
Which of the following is NOT typically a result of diesel engine emissions?
What is the primary role of greenhouse gases in relation to Earth's temperature?
What is the primary role of greenhouse gases in relation to Earth's temperature?
Which of the following greenhouse gases has the highest Global Warming Potential (GWP) over a 100-year timescale, according to the text?
Which of the following greenhouse gases has the highest Global Warming Potential (GWP) over a 100-year timescale, according to the text?
What contributes most significantly to the increase in carbon dioxide levels since the industrial age?
What contributes most significantly to the increase in carbon dioxide levels since the industrial age?
What is the reference gas used to determine the Global Warming Potential (GWP) of other greenhouse gases?
What is the reference gas used to determine the Global Warming Potential (GWP) of other greenhouse gases?
What does the term 'Carbon Dioxide Equivalent Emission' (CDE) refer to?
What does the term 'Carbon Dioxide Equivalent Emission' (CDE) refer to?
Which greenhouse gas is noted for retaining substantial amounts of heat in the earth's atmosphere?
Which greenhouse gas is noted for retaining substantial amounts of heat in the earth's atmosphere?
What is a common point of agreement despite differing opinions about the primary cause of climate change?
What is a common point of agreement despite differing opinions about the primary cause of climate change?
Over a 100-year timescale, which of the following greenhouse gases has a GWP that is approximately 28-36 times higher than that of carbon dioxide?
Over a 100-year timescale, which of the following greenhouse gases has a GWP that is approximately 28-36 times higher than that of carbon dioxide?
What is the primary temperature requirement for catalytic converters to effectively reduce HC, CO, and NOx emissions?
What is the primary temperature requirement for catalytic converters to effectively reduce HC, CO, and NOx emissions?
What is the main cause of carbon monoxide (CO) formation in internal combustion engines?
What is the main cause of carbon monoxide (CO) formation in internal combustion engines?
Which of these describes how unburned hydrocarbons (HC) are generated in an engine?
Which of these describes how unburned hydrocarbons (HC) are generated in an engine?
What condition primarily leads to the formation of Nitrogen Oxides (NOx)?
What condition primarily leads to the formation of Nitrogen Oxides (NOx)?
Which of these scenarios makes engine-out emissions particularly crucial?
Which of these scenarios makes engine-out emissions particularly crucial?
How can fuel droplets contribute to carbon monoxide production?
How can fuel droplets contribute to carbon monoxide production?
Which statement best describes the efficiency of modern exhaust after-treatment devices?
Which statement best describes the efficiency of modern exhaust after-treatment devices?
What distinguishes aliphatic hydrocarbons from cyclic aromatic hydrocarbons regarding odour?
What distinguishes aliphatic hydrocarbons from cyclic aromatic hydrocarbons regarding odour?
Which condition in diesel engines is most associated with the highest $NO_2/NO$ ratio?
Which condition in diesel engines is most associated with the highest $NO_2/NO$ ratio?
Why does increased engine torque in SI engines generally lead to fewer unburned hydrocarbons?
Why does increased engine torque in SI engines generally lead to fewer unburned hydrocarbons?
How does advancing the ignition timing affect $NO_x$ emissions in SI engines operating with lean mixtures?
How does advancing the ignition timing affect $NO_x$ emissions in SI engines operating with lean mixtures?
What causes an increase in hydrocarbon (HC) emissions in gasoline engines as engine speed rises?
What causes an increase in hydrocarbon (HC) emissions in gasoline engines as engine speed rises?
At what equivalence ratio range do $NO_x$ emissions typically reach their maximum in SI engines?
At what equivalence ratio range do $NO_x$ emissions typically reach their maximum in SI engines?
Under which specific condition can soot be generated in gasoline direct-injection engines?
Under which specific condition can soot be generated in gasoline direct-injection engines?
What is the primary reason nitrogen dioxide ($NO_2$) is formed in flames, according to the text?
What is the primary reason nitrogen dioxide ($NO_2$) is formed in flames, according to the text?
What is the approximate maximum value for the ratio ($NO_2/NO$) for SI engines according to the text?
What is the approximate maximum value for the ratio ($NO_2/NO$) for SI engines according to the text?
Why is stratified-charge mode operation limited to low and moderate engine speeds?
Why is stratified-charge mode operation limited to low and moderate engine speeds?
What is the primary focus of emission control in diesel engines considering their surplus of air in operation?
What is the primary focus of emission control in diesel engines considering their surplus of air in operation?
What is the primary component of diesel particulate matter formed during combustion?
What is the primary component of diesel particulate matter formed during combustion?
What happens to the composition of diesel particulates as exhaust temperatures decrease below 500°C?
What happens to the composition of diesel particulates as exhaust temperatures decrease below 500°C?
Which of the following best describes the main purpose of Exhaust Gas Recirculation (EGR) in engines?
Which of the following best describes the main purpose of Exhaust Gas Recirculation (EGR) in engines?
Besides dilution, what other effect contributes to reducing temperature in the combustion chamber when using EGR?
Besides dilution, what other effect contributes to reducing temperature in the combustion chamber when using EGR?
What characteristic of the exhaust gasses used in EGR contributes to increased specific heat of the charge?
What characteristic of the exhaust gasses used in EGR contributes to increased specific heat of the charge?
Which statement best summarizes the effectiveness of the different EGR effects on reducing $NO_x$ emissions?
Which statement best summarizes the effectiveness of the different EGR effects on reducing $NO_x$ emissions?
What is the primary function of the Malfunction Indicator Lamp (MIL) in a vehicle's emission system?
What is the primary function of the Malfunction Indicator Lamp (MIL) in a vehicle's emission system?
According to the information, what is the significance of the European Commission's regulation (EC No. 443/2009)?
According to the information, what is the significance of the European Commission's regulation (EC No. 443/2009)?
Within the provided formula for calculating specific CO2 emissions, what does the variable 'a' represent?
Within the provided formula for calculating specific CO2 emissions, what does the variable 'a' represent?
What is the proposed target for CO2 reduction in trucks by 2040, as specified in the European proposal?
What is the proposed target for CO2 reduction in trucks by 2040, as specified in the European proposal?
What does the variable 'M0' represent in the equation for calculating specific CO2 emissions?
What does the variable 'M0' represent in the equation for calculating specific CO2 emissions?
Flashcards
Greenhouse Effect
Greenhouse Effect
Greenhouse gases like water vapor, carbon dioxide, methane, ozone, and others trap heat in the Earth's atmosphere, raising average temperatures.
Global Warming
Global Warming
The increase in Earth's average temperature due to the greenhouse effect, primarily caused by human activities like burning fossil fuels.
Anthropogenic Emissions
Anthropogenic Emissions
The primary cause of global warming, as human activities release greenhouse gases into the atmosphere.
Greenhouse Gases (GHGs)
Greenhouse Gases (GHGs)
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Global Warming Potential (GWP)
Global Warming Potential (GWP)
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Carbon Release
Carbon Release
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Carbon Dioxide Emission (CDE)
Carbon Dioxide Emission (CDE)
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Increased Greenhouse Gas Concentrations
Increased Greenhouse Gas Concentrations
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Ideal combustion products
Ideal combustion products
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CO2 in exhaust
CO2 in exhaust
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NOx emissions
NOx emissions
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CO emissions
CO emissions
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HC emissions
HC emissions
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Catalytic converters
Catalytic converters
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Diesel PM emissions
Diesel PM emissions
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Diesel CO emissions
Diesel CO emissions
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Exhaust Gas After-treatment
Exhaust Gas After-treatment
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Catalyst Warm-up
Catalyst Warm-up
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Carbon Monoxide (CO) Emissions
Carbon Monoxide (CO) Emissions
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Hydrocarbons (HC) Emissions
Hydrocarbons (HC) Emissions
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HC Compounds
HC Compounds
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Aromatic vs. Aliphatic Hydrocarbons
Aromatic vs. Aliphatic Hydrocarbons
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Nitrogen Oxides (NOx) Emissions
Nitrogen Oxides (NOx) Emissions
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Oxides of Nitrogen
Oxides of Nitrogen
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NO2/NO Ratio
NO2/NO Ratio
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Unburned Hydrocarbons (HC)
Unburned Hydrocarbons (HC)
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Secondary Reactions in Expansion Phase
Secondary Reactions in Expansion Phase
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Engine Speed and HC Emissions
Engine Speed and HC Emissions
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NOx Emissions and Air-Fuel Ratio
NOx Emissions and Air-Fuel Ratio
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Ignition Timing and NOx
Ignition Timing and NOx
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Soot Formation in Gasoline Engines
Soot Formation in Gasoline Engines
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NO2/NO Ratio in Diesel Engines
NO2/NO Ratio in Diesel Engines
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Malfunction Indicator Lamp (MIL)
Malfunction Indicator Lamp (MIL)
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CO2 Emission Regulations for Passenger Cars
CO2 Emission Regulations for Passenger Cars
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CO2 Emission Calculation Formula
CO2 Emission Calculation Formula
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Average Mass of Manufacturer's Vehicle Fleet
Average Mass of Manufacturer's Vehicle Fleet
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CO2 Standards for Heavy-Duty Vehicles
CO2 Standards for Heavy-Duty Vehicles
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Stratified-charge Combustion
Stratified-charge Combustion
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Direct Injection (DI)
Direct Injection (DI)
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Exhaust Gas Recirculation (EGR)
Exhaust Gas Recirculation (EGR)
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Homogeneous Charge Combustion
Homogeneous Charge Combustion
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Diesel Particulates
Diesel Particulates
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How EGR Reduces NOx Emissions
How EGR Reduces NOx Emissions
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Dissociation
Dissociation
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Specific Heat
Specific Heat
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Study Notes
Exhaust Gas Emissions of ICE
- Pollution is defined as the introduction of substances or energy into the environment by humans, causing hazards to health, harm to living resources, damage to structures, and interference with legitimate environmental uses.
- Air pollutants can be gaseous or particulate.
- Combustion of hydrocarbons removes oxygen from the air, releasing water (H₂O) and carbon dioxide (CO₂), along with other compounds like carbon monoxide (CO), hydrocarbons (CH₄, C₂H₂ C₂H₆), nitrogen oxides (NO and NO₂), and sulfur gases (SO₂).
- Some of these are pollutants, hazardous to living beings, while others contribute to the greenhouse effect.
Primary and Secondary Pollutants
-
Primary pollutants are directly emitted from human activity or natural processes.
-
Secondary pollutants are formed from primary pollutants through transformations, naturally or artificially.
-
Primary pollutants can be generated from incomplete or non-ideal combustion processes (carbon monoxide, unburned hydrocarbons, nitrogen oxides, particulate matter (PM)), or from additives in fuel (like sulfur gases and metal compounds).
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Primary pollutants can also come from lubricants, wear from machine components, and non-combustion processes in industry and non-exhaust emissions.
Air Pollutants and Sources
- Global transport is a major source of air pollution, especially nitrogen oxides (NOx).
- The impact of a pollution source depends on the location, stack height, and the affected population distribution.
- Vehicles release pollution directly into the air, often concentrated in cities.
- Industrial sources are often located outside cities, diluting pollution before affecting large populations.
- Population density and energy use intensity are major contributing factors to pollution in urban areas.
Greenhouse Effect
- Short-wave solar radiation penetrates the Earth's atmosphere and warms the ground. The ground radiates heat, or infrared energy.
- A portion of this radiation is reflected by the atmosphere, heating the Earth.
- Greenhouse gases in the atmosphere trap some of the escaping heat, slowing energy loss to space and thus acting like a blanket around the Earth.
- This effect is increased by human activities.
- The primary greenhouse gases are carbon dioxide (COâ‚‚). methane (CHâ‚„), nitrous oxide (Nâ‚‚O), and halocarbons.
Pollutants of ICE
- Ideal combustion of pure fuel in ICEs produces only water (Hâ‚‚O), carbon dioxide (COâ‚‚), and nitrogen (Nâ‚‚).
- Non-ideal conditions in combustion produce additional toxic components.
- The amount of COâ‚‚ in exhaust gases is a measure of fuel consumption.
Spark Ignition (SI) Engine Emissions
- SI engines have exhaust gasses including nitrogen oxides (NOx), carbon monoxide (CO), and unburned hydrocarbons.
- Catalytic converters are used to dramatically reduce exhaust emissions.
- Early engine-out emissions must be considered for proper catalyst warm up and function.
Diesel Engine Emissions
- Diesel engines also have NOx emissions comparable to SI engines.
- Diesel engines have significant hydrocarbon emissions, although in lower concentrations than SI engines.
- Hydrocarbon emissions can condense into smoke during start-up and warm-up periods.
- Diesel engines are a notable source of particulate emissions, mainly soot and hydrocarbon material.
- Diesel engines are not a significant source of carbon monoxide.
After-treatment of Exhaust Gases
- Catalytic converters and particulate traps reduce NOx, CO, and hydrocarbons in the exhaust gases.
- High temperatures are needed for these methods to be effective.
- The catalysts must reach a working temperature rapidly, and consistent fuel/air ratios and temperatures are essential for optimal efficiency.
Main Pollutants from ICEs
- Carbon Monoxide (CO): Incomplete combustion in fuel/air mixtures with low oxygen.
- Hydrocarbons (HC): Insufficient oxygen for complete combustion.
- Nitrogen Oxides (NOx): High temperatures during combustion.
- Particulates (soot): Incomplete fuel combustion, especially in diesel engines.
Ozone and Smog
- Exposure to solar radiation breaks down nitrogen dioxide (NOâ‚‚).
- Ozone (O₃) and smog formation are dependent on factors like hot, windless summer days with high air pollution and atmospheric temperature inversions.
Influence of Engine Parameters on Emissions
- Exhaust emissions are affected by fuel and air ratios (fuel-air ratios), engine load, and ignition timing.
- High temperatures promote NOx, while lean mixtures minimize CO and hydrocarbons.
- Emission reductions are achieved through exhaust gas recirculation (EGR).
Emission Control Regulations
- Different countries have specific emission standards (e.g., California, USA, EU, Japan).
- The regulations are segmented by vehicle type and class. (Passenger cars, Light and Heavy-duty commercial vehicles).
- Testing cycles mimic real-world driving conditions.
- Emission control systems are critical to comply with standards and reduce pollutant emission levels.
After-treatment Systems
- Three-way catalysts and NOx traps reduce exhaust emissions of pollutants in SI engines.
- Diesel-specific emission control systems include catalyzed continuously regenerating technology (CCRT) which incorporates a diesel oxygenation catalyst (DOC) and a diesel particulate filter (DPF).
- Selective catalytic reduction (SCR) systems are also used in some advanced diesel engines.
Emission Control Regulations
- The regulations are divided into categories: Passenger cars, Light and Heavy-duty commercial vehicles.
- Testing procedures assess vehicle compliance with standards and are based on real-world driving conditions.
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