Internal Combustion Engines Emissions Quiz

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Questions and Answers

What percentage of exhaust gases from gasoline and diesel engines is typically composed of carbon dioxide?

  • Approximately 14% (correct)
  • Approximately 5%
  • Approximately 25%
  • Approximately 35%

Which of the following is NOT a primary product of ideal, complete combustion of pure fuel?

  • H2O
  • CO2
  • N2
  • CO (correct)

What is the approximate range of nitrogen oxides (NOx) emitted by spark ignition (SI) engines?

  • 100 to 300 ppm
  • 10 to 100 ppm
  • 500 to 10000 ppm
  • 500 to 1000 ppm (correct)

What is the primary method of reducing the amount of carbon dioxide emissions from internal combustion engines?

<p>Reducing fuel consumption (C)</p> Signup and view all the answers

What is the primary composition of particulate matter emitted by diesel engines?

<p>Primarily soot with additional hydrocarbons (D)</p> Signup and view all the answers

What is the approximate reduction in tailpipe emissions achieved by catalytic converters?

<p>Over 90% (B)</p> Signup and view all the answers

Which of these is a significant source of organic compounds in the exhaust of spark ignition engines?

<p>Unburned hydrocarbons (A)</p> Signup and view all the answers

Which of the following is NOT typically a result of diesel engine emissions?

<p>Significant amounts of carbon monoxide. (B)</p> Signup and view all the answers

What is the primary role of greenhouse gases in relation to Earth's temperature?

<p>They increase the average temperature by absorbing and trapping heat. (D)</p> Signup and view all the answers

Which of the following greenhouse gases has the highest Global Warming Potential (GWP) over a 100-year timescale, according to the text?

<p>Halocarbons (C)</p> Signup and view all the answers

What contributes most significantly to the increase in carbon dioxide levels since the industrial age?

<p>The burning of coal and petroleum products. (A)</p> Signup and view all the answers

What is the reference gas used to determine the Global Warming Potential (GWP) of other greenhouse gases?

<p>Carbon dioxide (CO2) (B)</p> Signup and view all the answers

What does the term 'Carbon Dioxide Equivalent Emission' (CDE) refer to?

<p>The sum of mass emissions of all gases, evaluated by their individual GWP's (D)</p> Signup and view all the answers

Which greenhouse gas is noted for retaining substantial amounts of heat in the earth's atmosphere?

<p>Water vapor (A)</p> Signup and view all the answers

What is a common point of agreement despite differing opinions about the primary cause of climate change?

<p>The necessity to reduce energy consumption to lower carbon dioxide emissions. (D)</p> Signup and view all the answers

Over a 100-year timescale, which of the following greenhouse gases has a GWP that is approximately 28-36 times higher than that of carbon dioxide?

<p>Methane (CH4) (D)</p> Signup and view all the answers

What is the primary temperature requirement for catalytic converters to effectively reduce HC, CO, and NOx emissions?

<p>Approximately 250°C (B)</p> Signup and view all the answers

What is the main cause of carbon monoxide (CO) formation in internal combustion engines?

<p>Incomplete combustion in rich air/fuel mixtures. (B)</p> Signup and view all the answers

Which of these describes how unburned hydrocarbons (HC) are generated in an engine?

<p>From inadequate oxygen present for complete combustion. (C)</p> Signup and view all the answers

What condition primarily leads to the formation of Nitrogen Oxides (NOx)?

<p>Through secondary reactions in combustion processes where air containing nitrogen is burned. (D)</p> Signup and view all the answers

Which of these scenarios makes engine-out emissions particularly crucial?

<p>During the catalyst warm-up period, before it reaches effective temperature. (A)</p> Signup and view all the answers

How can fuel droplets contribute to carbon monoxide production?

<p>By failing to vaporize, creating areas of rich mixture which combust incompletely. (D)</p> Signup and view all the answers

Which statement best describes the efficiency of modern exhaust after-treatment devices?

<p>They remove over 90% of engine-out emissions. (C)</p> Signup and view all the answers

What distinguishes aliphatic hydrocarbons from cyclic aromatic hydrocarbons regarding odour?

<p>Aliphatic hydrocarbons emit virtually no odour, while aromatic ones have a discernible smell. (B)</p> Signup and view all the answers

Which condition in diesel engines is most associated with the highest $NO_2/NO$ ratio?

<p>Low engine speed and light load (D)</p> Signup and view all the answers

Why does increased engine torque in SI engines generally lead to fewer unburned hydrocarbons?

<p>Because it results in higher combustion temperature which promotes more complete combustion. (C)</p> Signup and view all the answers

How does advancing the ignition timing affect $NO_x$ emissions in SI engines operating with lean mixtures?

<p>It increases $NO_x$ emissions due to higher peak combustion temperatures. (C)</p> Signup and view all the answers

What causes an increase in hydrocarbon (HC) emissions in gasoline engines as engine speed rises?

<p>The time available for preparing and combusting the mixture becomes shorter. (C)</p> Signup and view all the answers

At what equivalence ratio range do $NO_x$ emissions typically reach their maximum in SI engines?

<p>In the slightly lean range ($\phi = 1.05 \div 1.1$). (C)</p> Signup and view all the answers

Under which specific condition can soot be generated in gasoline direct-injection engines?

<p>During stratified-charge operation with localized rich mixtures or fuel droplets. (C)</p> Signup and view all the answers

What is the primary reason nitrogen dioxide ($NO_2$) is formed in flames, according to the text?

<p>From the oxidation of nitric oxide (NO). (C)</p> Signup and view all the answers

What is the approximate maximum value for the ratio ($NO_2/NO$) for SI engines according to the text?

<p>2 percent (D)</p> Signup and view all the answers

Why is stratified-charge mode operation limited to low and moderate engine speeds?

<p>To ensure adequate time for efficient mixture formation (C)</p> Signup and view all the answers

What is the primary focus of emission control in diesel engines considering their surplus of air in operation?

<p>Reducing $NO_x$ and particulate emissions (C)</p> Signup and view all the answers

What is the primary component of diesel particulate matter formed during combustion?

<p>Carbonaceous material (soot) (B)</p> Signup and view all the answers

What happens to the composition of diesel particulates as exhaust temperatures decrease below 500°C?

<p>The particles become coated with high molecular weight organic compounds. (B)</p> Signup and view all the answers

Which of the following best describes the main purpose of Exhaust Gas Recirculation (EGR) in engines?

<p>To dilute the intake charge, hence lowering combustion temperature and $NO_x$ formation. (B)</p> Signup and view all the answers

Besides dilution, what other effect contributes to reducing temperature in the combustion chamber when using EGR?

<p>Heat absorption for the dissociation of $CO_2$ and $H_2O$. (C)</p> Signup and view all the answers

What characteristic of the exhaust gasses used in EGR contributes to increased specific heat of the charge?

<p>The presence of carbon dioxide and water vapor. (A)</p> Signup and view all the answers

Which statement best summarizes the effectiveness of the different EGR effects on reducing $NO_x$ emissions?

<p>The dilution effect is the most important. (A)</p> Signup and view all the answers

What is the primary function of the Malfunction Indicator Lamp (MIL) in a vehicle's emission system?

<p>To alert the driver of a malfunction or deterioration causing emissions to exceed thresholds. (D)</p> Signup and view all the answers

According to the information, what is the significance of the European Commission's regulation (EC No. 443/2009)?

<p>It introduced a mandatory CO2 emission reduction program based on vehicle mass. (B)</p> Signup and view all the answers

Within the provided formula for calculating specific CO2 emissions, what does the variable 'a' represent?

<p>The slope of the curve, expressed in (g/km)/kg. (C)</p> Signup and view all the answers

What is the proposed target for CO2 reduction in trucks by 2040, as specified in the European proposal?

<p>90% reduction (C)</p> Signup and view all the answers

What does the variable 'M0' represent in the equation for calculating specific CO2 emissions?

<p>The average mass of all manufacturers' vehicle fleets. (D)</p> Signup and view all the answers

Flashcards

Greenhouse Effect

Greenhouse gases like water vapor, carbon dioxide, methane, ozone, and others trap heat in the Earth's atmosphere, raising average temperatures.

Global Warming

The increase in Earth's average temperature due to the greenhouse effect, primarily caused by human activities like burning fossil fuels.

Anthropogenic Emissions

The primary cause of global warming, as human activities release greenhouse gases into the atmosphere.

Greenhouse Gases (GHGs)

Carbon dioxide, methane, nitrous oxide, and halocarbons are the main gases contributing to the greenhouse effect.

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Global Warming Potential (GWP)

A measure of how much a gas contributes to global warming compared to carbon dioxide.

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Carbon Release

The process of converting the carbon bound in fossil fuels into carbon dioxide, released into the atmosphere, primarily through burning.

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Carbon Dioxide Emission (CDE)

A metric used to evaluate the overall emissions of greenhouse gases, expressed in terms of equivalent carbon dioxide emissions.

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Increased Greenhouse Gas Concentrations

The increase in the concentration of certain greenhouse gases like carbon dioxide, primarily attributed to human activities like industrial processes, deforestation, and fossil fuel combustion.

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Ideal combustion products

In ideal combustion, the primary products are water (H2O), carbon dioxide (CO2), and nitrogen (N2). However, real-world combustion is not ideal, and many other pollutants are also produced.

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CO2 in exhaust

Carbon dioxide (CO2) makes up only about 14% of exhaust gases from gasoline and diesel engines. This means other gases are also significant contributors to pollution.

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NOx emissions

Nitrogen oxides (NOx) are a major pollutant emitted by both spark ignition and diesel engines.

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CO emissions

Carbon monoxide (CO) is another pollutant emitted by spark ignition engines. It is a colorless, odorless, and poisonous gas.

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HC emissions

Unburned hydrocarbons (HC) are emitted from spark ignition engines and can contribute to smog and other air quality issues.

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Catalytic converters

Catalytic converters are fitted to vehicles to reduce harmful emissions from the engine exhaust before they are released into the environment.

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Diesel PM emissions

Diesel engine exhaust contains significant amounts of particulate matter (PM), which are tiny particles that can contribute to respiratory problems and other health issues.

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Diesel CO emissions

Diesel engines are not a significant source of carbon monoxide (CO) compared to spark ignition engines.

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Exhaust Gas After-treatment

Catalytic converters and particulate traps remove pollutants from exhaust gases before they exit the vehicle.

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Catalyst Warm-up

Catalyst effectiveness relies on reaching a specific temperature, typically around 250 degrees Celsius.

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Carbon Monoxide (CO) Emissions

Incomplete combustion in a fuel-rich mixture leads to the production of carbon monoxide.

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Hydrocarbons (HC) Emissions

Unburned hydrocarbons, or HC, are released when there's insufficient oxygen for complete combustion.

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HC Compounds

Hydrocarbons encompass a wide range of compounds containing hydrogen and carbon.

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Aromatic vs. Aliphatic Hydrocarbons

Aliphatic hydrocarbons lack strong scents, while cyclic aromatic hydrocarbons like benzol and toluol have discernible odors.

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Nitrogen Oxides (NOx) Emissions

Nitrogen oxides form during combustion due to reactions involving nitrogen and oxygen in the air.

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Oxides of Nitrogen

Nitrogen oxides are a group of compounds containing nitrogen and oxygen, often generated as a byproduct of combustion.

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NO2/NO Ratio

The ratio of nitrogen dioxide (NO2) to nitrogen oxide (NO) in exhaust gases, typically higher in diesel engines than gasoline engines.

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Unburned Hydrocarbons (HC)

Unburned hydrocarbons in the exhaust gases are a result of incomplete combustion. They are reduced when torque (engine load) increases due to higher combustion temperatures.

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Secondary Reactions in Expansion Phase

Secondary reactions in the expansion phase of combustion convert unburned hydrocarbons (HC) into carbon dioxide (CO2) and water (H2O).

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Engine Speed and HC Emissions

Increased engine speed reduces the time for combustion, leading to more incomplete combustion and higher hydrocarbon emissions.

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NOx Emissions and Air-Fuel Ratio

Nitrogen oxides (NOx) emissions peak at a slightly lean air-fuel ratio (about 1.05 to 1.1).

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Ignition Timing and NOx

Advancing ignition timing increases combustion temperature, which shifts chemical equilibrium towards greater NOx formation.

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Soot Formation in Gasoline Engines

Soot formation is minimal in gasoline engines with stoichiometric mixtures but can occur with direct injection and stratified charge due to localized rich zones or fuel droplets.

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NO2/NO Ratio in Diesel Engines

Diesel engines typically have a higher NO2/NO ratio, with the highest value at light load due to cooler regions that quench the conversion of NO2 back to NO.

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Malfunction Indicator Lamp (MIL)

A warning light on a vehicle's dashboard that indicates a malfunction in the emission system, potentially causing excessive emissions above legal limits.

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CO2 Emission Regulations for Passenger Cars

A set of regulations established by the European Union to limit the amount of carbon dioxide (CO2) emitted by new passenger cars.

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CO2 Emission Calculation Formula

A formula used to calculate the specific CO2 emissions of a vehicle based on its mass and the overall fleet target. This formula helps determine if a car meets the CO2 emission standards set by the EU.

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Average Mass of Manufacturer's Vehicle Fleet

The average mass of all new passenger cars produced by a manufacturer. This figure is used in the CO2 emission calculation formula to determine the specific emissions of each vehicle.

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CO2 Standards for Heavy-Duty Vehicles

A proposed revision to the European Union's regulations on CO2 emissions for heavy-duty vehicles like trucks and buses. The goal is to significantly reduce emissions by 2030 and 2040.

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Stratified-charge Combustion

A combustion mode where fuel is injected into a localized area of the combustion chamber, creating a rich mixture, leading to higher efficiency and lower emissions.

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Direct Injection (DI)

A type of engine operation where the fuel is injected into the cylinder close to the end of the compression stroke, resulting in a faster and more efficient combustion process.

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Exhaust Gas Recirculation (EGR)

The process of returning a portion of the exhaust gas back into the combustion chamber, lowering combustion temperatures and reducing NOx emissions.

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Homogeneous Charge Combustion

A type of combustion process where a small portion of the fuel mixes with air before entering the cylinder, resulting in a lean mixture and lower emissions.

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Diesel Particulates

The main byproducts of incomplete combustion in diesel engines, consisting primarily of soot particles with adsorbed organic compounds.

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How EGR Reduces NOx Emissions

Reducing NOx emissions in diesel and gasoline engines by returning a portion of the exhaust gas into the combustion chamber, diluting the charge and lowering combustion temperature.

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Dissociation

A chemical reaction where molecules are broken down into smaller particles, often requiring energy input.

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Specific Heat

The ability of a substance to absorb heat energy, measured as the amount of heat needed to raise the temperature of a specific amount of the substance by one degree.

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Study Notes

Exhaust Gas Emissions of ICE

  • Pollution is defined as the introduction of substances or energy into the environment by humans, causing hazards to health, harm to living resources, damage to structures, and interference with legitimate environmental uses.
  • Air pollutants can be gaseous or particulate.
  • Combustion of hydrocarbons removes oxygen from the air, releasing water (Hâ‚‚O) and carbon dioxide (COâ‚‚), along with other compounds like carbon monoxide (CO), hydrocarbons (CHâ‚„, Câ‚‚Hâ‚‚ Câ‚‚H₆), nitrogen oxides (NO and NOâ‚‚), and sulfur gases (SOâ‚‚).
  • Some of these are pollutants, hazardous to living beings, while others contribute to the greenhouse effect.

Primary and Secondary Pollutants

  • Primary pollutants are directly emitted from human activity or natural processes.

  • Secondary pollutants are formed from primary pollutants through transformations, naturally or artificially.

  • Primary pollutants can be generated from incomplete or non-ideal combustion processes (carbon monoxide, unburned hydrocarbons, nitrogen oxides, particulate matter (PM)), or from additives in fuel (like sulfur gases and metal compounds).

  • Primary pollutants can also come from lubricants, wear from machine components, and non-combustion processes in industry and non-exhaust emissions.

Air Pollutants and Sources

  • Global transport is a major source of air pollution, especially nitrogen oxides (NOx).
  • The impact of a pollution source depends on the location, stack height, and the affected population distribution.
  • Vehicles release pollution directly into the air, often concentrated in cities.
  • Industrial sources are often located outside cities, diluting pollution before affecting large populations.
  • Population density and energy use intensity are major contributing factors to pollution in urban areas.

Greenhouse Effect

  • Short-wave solar radiation penetrates the Earth's atmosphere and warms the ground. The ground radiates heat, or infrared energy.
  • A portion of this radiation is reflected by the atmosphere, heating the Earth.
  • Greenhouse gases in the atmosphere trap some of the escaping heat, slowing energy loss to space and thus acting like a blanket around the Earth.
  • This effect is increased by human activities.
  • The primary greenhouse gases are carbon dioxide (COâ‚‚). methane (CHâ‚„), nitrous oxide (Nâ‚‚O), and halocarbons.

Pollutants of ICE

  • Ideal combustion of pure fuel in ICEs produces only water (Hâ‚‚O), carbon dioxide (COâ‚‚), and nitrogen (Nâ‚‚).
  • Non-ideal conditions in combustion produce additional toxic components.
  • The amount of COâ‚‚ in exhaust gases is a measure of fuel consumption.

Spark Ignition (SI) Engine Emissions

  • SI engines have exhaust gasses including nitrogen oxides (NOx), carbon monoxide (CO), and unburned hydrocarbons.
  • Catalytic converters are used to dramatically reduce exhaust emissions.
  • Early engine-out emissions must be considered for proper catalyst warm up and function.

Diesel Engine Emissions

  • Diesel engines also have NOx emissions comparable to SI engines.
  • Diesel engines have significant hydrocarbon emissions, although in lower concentrations than SI engines.
  • Hydrocarbon emissions can condense into smoke during start-up and warm-up periods.
  • Diesel engines are a notable source of particulate emissions, mainly soot and hydrocarbon material.
  • Diesel engines are not a significant source of carbon monoxide.

After-treatment of Exhaust Gases

  • Catalytic converters and particulate traps reduce NOx, CO, and hydrocarbons in the exhaust gases.
  • High temperatures are needed for these methods to be effective.
  • The catalysts must reach a working temperature rapidly, and consistent fuel/air ratios and temperatures are essential for optimal efficiency.

Main Pollutants from ICEs

  • Carbon Monoxide (CO): Incomplete combustion in fuel/air mixtures with low oxygen.
  • Hydrocarbons (HC): Insufficient oxygen for complete combustion.
  • Nitrogen Oxides (NOx): High temperatures during combustion.
  • Particulates (soot): Incomplete fuel combustion, especially in diesel engines.

Ozone and Smog

  • Exposure to solar radiation breaks down nitrogen dioxide (NOâ‚‚).
  • Ozone (O₃) and smog formation are dependent on factors like hot, windless summer days with high air pollution and atmospheric temperature inversions.

Influence of Engine Parameters on Emissions

  • Exhaust emissions are affected by fuel and air ratios (fuel-air ratios), engine load, and ignition timing.
  • High temperatures promote NOx, while lean mixtures minimize CO and hydrocarbons.
  • Emission reductions are achieved through exhaust gas recirculation (EGR).

Emission Control Regulations

  • Different countries have specific emission standards (e.g., California, USA, EU, Japan).
  • The regulations are segmented by vehicle type and class. (Passenger cars, Light and Heavy-duty commercial vehicles).
  • Testing cycles mimic real-world driving conditions.
  • Emission control systems are critical to comply with standards and reduce pollutant emission levels.

After-treatment Systems

  • Three-way catalysts and NOx traps reduce exhaust emissions of pollutants in SI engines.
  • Diesel-specific emission control systems include catalyzed continuously regenerating technology (CCRT) which incorporates a diesel oxygenation catalyst (DOC) and a diesel particulate filter (DPF).
  • Selective catalytic reduction (SCR) systems are also used in some advanced diesel engines.

Emission Control Regulations

  • The regulations are divided into categories: Passenger cars, Light and Heavy-duty commercial vehicles.
  • Testing procedures assess vehicle compliance with standards and are based on real-world driving conditions.

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