Intermolecular Forces Overview
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Questions and Answers

Which type of intermolecular force is considered the strongest?

  • Van der Waals Forces
  • Hydrogen Bonding (correct)
  • Dipole-Dipole Forces
  • London Dispersion Forces

London Dispersion Forces are present only in polar molecules.

False (B)

What effect do stronger intermolecular forces have on boiling and melting points?

They increase boiling and melting points.

The measure of a fluid's resistance to flow is called __________.

<p>viscosity</p> Signup and view all the answers

Match the type of intermolecular force to its description:

<p>London Dispersion Forces = Present in all molecules and caused by temporary dipoles Dipole-Dipole Forces = Attraction between polar molecules with positive and negative ends Hydrogen Bonding = Occurs between hydrogen and highly electronegative atoms Van der Waals Forces = A general term for weak intermolecular forces including London Dispersion</p> Signup and view all the answers

Flashcards

Intermolecular forces

Attractive forces between molecules influencing physical properties like boiling/melting point and viscosity.

London Dispersion Forces

Weakest intermolecular force present in all molecules due to temporary electron shifts.

Dipole-Dipole Forces

Attractive forces between polar molecules due to opposite charges on molecules.

Hydrogen bonding

Strongest intermolecular force; attraction between H atom and highly electronegative atom like N, O or F.

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Intermolecular forces and boiling/melting point

Stronger intermolecular forces result in higher boiling and melting points, requiring more energy to separate molecules.

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Study Notes

Intermolecular Forces

  • Intermolecular forces are attractive forces between molecules.
  • These forces influence properties like boiling/melting points, surface tension, and viscosity.

Types of Intermolecular Forces

London Dispersion Forces (Van der Waals Forces)

  • Present in all molecules.
  • Caused by temporary fluctuations in electron distribution, creating temporary dipoles.
  • Strength increases with molecular size and surface area.

Dipole-Dipole Forces

  • Occur between polar molecules.
  • Result from the attraction between a positive end of one molecule and the negative end of another.
  • Stronger than London dispersion forces, but weaker than hydrogen bonds.

Hydrogen Bonding

  • A special type of dipole-dipole force.
  • Occurs between a hydrogen atom bonded to a highly electronegative atom (N, O, or F) and a lone pair of electrons on another electronegative atom.
  • The strongest of the intermolecular forces.

Intermolecular Forces and Physical Properties

  • Boiling Point and Melting Point: Stronger intermolecular forces lead to higher boiling and melting points as more energy is required to overcome these attractive forces between molecules.
  • Surface Tension: Intermolecular forces cause liquids to have a high surface tension, where the surface contracts. Liquids with stronger intermolecular forces have higher surface tension.
  • Viscosity: Viscosity is a liquid's resistance to flow. Liquids with stronger intermolecular forces have higher viscosity.

Summary Table

Intermolecular Force Description Strength Example
London Dispersion Forces Temporary dipoles Weakest All molecules
Dipole-Dipole Forces Attraction between polar molecules Moderate HCl, HBr
Hydrogen Bonding Strong dipole-dipole force involving H and N, O, or F Strongest H₂O, NH₃, HF

Key Points

  • Intermolecular forces are weaker than intramolecular forces (bonds within molecules).
  • The strength of intermolecular forces affects the physical properties of substances.
  • Understanding intermolecular forces helps explain phenomena like evaporation, condensation, and the behavior of liquids and solids.

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Intermolecular Forces PDF

Description

Explore the fascinating world of intermolecular forces including London dispersion forces, dipole-dipole interactions, and hydrogen bonding. Understand how these forces affect the physical properties of substances like boiling points and viscosity. This quiz will test your knowledge of these essential concepts in chemistry.

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