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Questions and Answers
Which type of intermolecular force is the strongest?
Which type of intermolecular force is the strongest?
What type of intermolecular force is primarily responsible for the attraction between two molecules of $CH_3OH$?
What type of intermolecular force is primarily responsible for the attraction between two molecules of $CH_3OH$?
Which of the following molecules can only participate in dispersion forces?
Which of the following molecules can only participate in dispersion forces?
Which statement accurately describes the relationship between electronegativity and dipole-dipole forces?
Which statement accurately describes the relationship between electronegativity and dipole-dipole forces?
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What is the main reason why water is a liquid at room temperature, while methane ($CH_4$) is a gas?
What is the main reason why water is a liquid at room temperature, while methane ($CH_4$) is a gas?
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Which of the following statements is TRUE about van der Waals forces?
Which of the following statements is TRUE about van der Waals forces?
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Which of the following factors primarily influences the strength of dispersion forces?
Which of the following factors primarily influences the strength of dispersion forces?
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Which of the following is an example of a substance that would be MOST soluble in water?
Which of the following is an example of a substance that would be MOST soluble in water?
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What effect does increasing the temperature have on the equilibrium vapor pressure of a liquid?
What effect does increasing the temperature have on the equilibrium vapor pressure of a liquid?
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Which of the following statements about intermolecular forces and viscosity is TRUE?
Which of the following statements about intermolecular forces and viscosity is TRUE?
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What is the definition of a solution?
What is the definition of a solution?
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What is the defining characteristic of colligative properties in solutions?
What is the defining characteristic of colligative properties in solutions?
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A solution is prepared by dissolving 25.0 g of glucose ($C_6H_{12}O_6$) in 250 g of water. What is the molality of the solution?
A solution is prepared by dissolving 25.0 g of glucose ($C_6H_{12}O_6$) in 250 g of water. What is the molality of the solution?
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Which of the following pairs of liquids would be considered miscible?
Which of the following pairs of liquids would be considered miscible?
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What is the relationship between the solubility of a gas and the partial pressure of the gas above the solution, according to Henry's Law?
What is the relationship between the solubility of a gas and the partial pressure of the gas above the solution, according to Henry's Law?
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Which of the following is NOT a colligative property?
Which of the following is NOT a colligative property?
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What happens to the rate of condensation as vapor pressure increases?
What happens to the rate of condensation as vapor pressure increases?
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Which type of intermolecular force is the weakest?
Which type of intermolecular force is the weakest?
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Which of the following is TRUE regarding the relationship between intermolecular forces and boiling point?
Which of the following is TRUE regarding the relationship between intermolecular forces and boiling point?
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What does the enthalpy of vaporization ($\Delta H_{vap}$) represent?
What does the enthalpy of vaporization ($\Delta H_{vap}$) represent?
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Which of these substances would have the highest vapor pressure at a given temperature?
Which of these substances would have the highest vapor pressure at a given temperature?
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A liquid is in a closed container. Which of the following statements is TRUE about the vapor pressure in the container after reaching equilibrium?
A liquid is in a closed container. Which of the following statements is TRUE about the vapor pressure in the container after reaching equilibrium?
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A substance with strong intermolecular forces will typically have...
A substance with strong intermolecular forces will typically have...
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Which of the following does NOT directly impact the vapor pressure of a liquid?
Which of the following does NOT directly impact the vapor pressure of a liquid?
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Flashcards
Intermolecular Forces
Intermolecular Forces
Forces that attract molecules to each other, including van der Waals forces.
Weak Intermolecular Attraction
Weak Intermolecular Attraction
Attractions that occur between molecules due to charges, including polar and nonpolar interactions.
Dipole-Dipole Forces
Dipole-Dipole Forces
Attractive forces between molecules that have permanent dipoles, caused by differences in electronegativity.
Hydrogen Bonding (H-Bond)
Hydrogen Bonding (H-Bond)
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Dispersion Forces
Dispersion Forces
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Permanent Dipoles
Permanent Dipoles
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Electronegativity
Electronegativity
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Solubility Principle
Solubility Principle
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Intermolecular Forces Strength
Intermolecular Forces Strength
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Enthalpy of Vaporization (ΔHvap)
Enthalpy of Vaporization (ΔHvap)
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Vaporization Process
Vaporization Process
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Vapor Pressure
Vapor Pressure
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Volatility
Volatility
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Boiling Point
Boiling Point
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Viscosity
Viscosity
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Surface Tension
Surface Tension
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Equilibrium Vapor Pressure
Equilibrium Vapor Pressure
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Solution
Solution
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Colligative Properties
Colligative Properties
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Molality (m)
Molality (m)
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Miscible Liquids
Miscible Liquids
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Henry's Law
Henry's Law
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Study Notes
Intermolecular Forces and Liquids
- Intermolecular forces are attractions between molecules
- All forces between molecules are called van der Waals forces
- Covalent bonds are stronger than intermolecular forces
Covalent Bonding vs. Intermolecular Forces
- Intermolecular forces are weaker than covalent bonds that hold compounds together
- Covalent bonds are strong
Polarity
- Polar molecules have partial positive and negative charges due to electronegativity differences
- Nonpolar molecules have bonds that cancel out due to geometry
Dipole-Dipole Forces
- Molecules with permanent dipoles are attracted to each other
- Molecules with permanent dipoles have a positive and negative end
Hydrogen Bonds
- A special type of dipole-dipole force
- Occurs when hydrogen is covalently bonded to nitrogen, oxygen, or fluorine in one molecule
- Hydrogen is attracted to a more electronegative atom in another molecule
Dispersion Forces
- Temporary dipoles are created by fluctuations in electron distribution
- All molecules exhibit dispersion forces
- Dispersion forces are the weakest intermolecular force
Properties of Liquids
- Vaporization: Molecules escape from the liquid surface to gas phase; endothermic
- Condensation: Gas molecules turn into liquid molecules, exothermic
- Vapor pressure: Equilibrium between liquid and gas; pressure exerted by vapor over a liquid; increases with temperature
- Volatility: Tendency of a molecule to escape liquid phase; higher volatility-higher vapor pressure
- Boiling point: Temperature at which vapor pressure of liquid equals external atmospheric pressure
Viscosity
- Resistance of a liquid to flow
- Stronger intermolecular forces=higher viscosity
Solutions
- Homogeneous mixture of two or more substances
- Solvent: Component in largest amount
- Solute: Other component
- Colligative properties: Depend on the number of solute particles, not their identity
- Molality (m): Moles of solute per kilogram of solvent
The Solution Process
- Solubility: Concentration of solute in a saturated solution at equilibrium with undissolved solute
- Miscible Liquids: Mix completely
- Immiscible Liquids: Do not mix completely
- "Like dissolves like": Polar substances dissolve polar substances, and nonpolar substances dissolve nonpolar substances
- Henry's Law: Solubility of a gas is directly proportional to the partial pressure of the gas above the solution
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Description
This quiz covers essential concepts related to intermolecular forces, including covalent bonds, polarity, and various types of intermolecular attractions such as dipole-dipole forces and hydrogen bonds. Test your understanding of these fundamental topics in chemistry and their implications for molecular behavior in liquids.