Inorganic Chemistry Lab Manual - First Stage

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Questions and Answers

What is the main purpose of the experiment that examines hydrated salts?

  • To produce barium compounds
  • To determine the volume of water content in hydrated salt (correct)
  • To investigate gas evolution
  • To explore acid-base reactions

Water of crystallization can be removed by sufficient heat.

True (A)

What chemical is used in the preparation stage to make barium chloride?

Barium carbonate

The gas evolved and precipitate are observed after adding _______ to BaO2.

<p>AgNO3</p> Signup and view all the answers

Match the following chemicals with their usage in the experiment:

<p>BaCO3 = Preparation of barium chloride H2O2 = Oxidizing agent in reactions KMnO4 = Indicator in redox reactions AgNO3 = Precipitate formation</p> Signup and view all the answers

Which of the following statements is true regarding water of crystallization?

<p>It is necessary for the maintenance of crystalline properties. (B)</p> Signup and view all the answers

Barium chloride can be formed directly from mixing BaO2 with water.

<p>False (B)</p> Signup and view all the answers

What is the role of hydrogen peroxide in the preparation method?

<p>It acts as an oxidizing agent.</p> Signup and view all the answers

What should you avoid doing when using a jumbo pipet with solvent?

<p>Getting any liquid on the inside of the stem (D)</p> Signup and view all the answers

Alums are only composed of one type of ion.

<p>False (B)</p> Signup and view all the answers

What type of action allows the solvent to travel up the chromatography paper?

<p>Capillary action</p> Signup and view all the answers

What does an RF value of 1 indicate about a solute's affinity for the stationary phase?

<p>The solute has no affinity for the stationary phase. (B)</p> Signup and view all the answers

Paper chromatography can be used to identify the purity of compounds.

<p>True (A)</p> Signup and view all the answers

What color change would you expect when chlorine gas is tested with moistened litmus paper?

<p>Blue to red (B)</p> Signup and view all the answers

Alum is commonly prepared from __________ aluminum.

<p>discarded</p> Signup and view all the answers

Iodine crystals produce colorless vapors when heated.

<p>False (B)</p> Signup and view all the answers

Match the following elements related to the synthesis of alum:

<p>K+ = Monovalent cation Al3+ = Trivalent cation SO4 = Sulfate anion</p> Signup and view all the answers

What is the formula to calculate the RF value?

<p>Distance traveled by the substance divided by the distance traveled by the solvent.</p> Signup and view all the answers

What is one of the uses of alum?

<p>To harden photographic film (D)</p> Signup and view all the answers

In paper chromatography, the stationary phase is typically a piece of high quality __________.

<p>filter paper</p> Signup and view all the answers

What can be used to examine the color of vapors produced by bromine water?

<p>Starch-iodide solution</p> Signup and view all the answers

Match the following terms with their definitions:

<p>Solvent front = The line the solvent reaches on the paper Solute = The substance being separated Stationary phase = The phase that does not move Mobile phase = The phase that carries the solute</p> Signup and view all the answers

True alums always crystallize in spherical shapes.

<p>False (B)</p> Signup and view all the answers

The reaction of iodine with potassium iodide solution is used to make it soluble in __________.

<p>water</p> Signup and view all the answers

Match the following halogens with their observable color when heated:

<p>Chlorine = Yellow-green gas Bromine = Red-brown liquid Iodine = Purple vapor</p> Signup and view all the answers

Which factor affects how components of a sample separate in paper chromatography?

<p>The solubility and affinity for the stationary phase. (C)</p> Signup and view all the answers

What shape do true alums typically crystallize into?

<p>Octahedral</p> Signup and view all the answers

Which of the following reactions is expected when potassium dichromate is reduced with potassium iodide?

<p>Iodine is formed (C)</p> Signup and view all the answers

Every molecule in a colored sample will have the same polarity.

<p>False (B)</p> Signup and view all the answers

A colored chemical sample will separate when the solvent __________ up the paper.

<p>diffuses</p> Signup and view all the answers

What type of solution is formed when iodine is dissolved in chloroform?

<p>Colored solution</p> Signup and view all the answers

Bromine water can oxidize iron (II) sulfate.

<p>True (A)</p> Signup and view all the answers

What is the primary use of calcium peroxide in agriculture?

<p>As a fertilizer (D)</p> Signup and view all the answers

Calcium peroxide is soluble in water.

<p>False (B)</p> Signup and view all the answers

What happens to calcium peroxide when it comes in contact with water?

<p>It decomposes releasing oxygen.</p> Signup and view all the answers

Calcium peroxide can be created by the interaction of calcium salt and __________.

<p>sodium peroxide</p> Signup and view all the answers

Match the following reagents with their roles in the preparation of calcium peroxide:

<p>Calcium Carbonate = Source of calcium Conc. HCl = Source of acid Hydrogen Peroxide = Oxidizing agent Conc. Ammonia = Neutralizing agent</p> Signup and view all the answers

What is the result of adding dilute H2SO4 to a test tube containing bromine and iodine crystals?

<p>Discoloration of the solution (C)</p> Signup and view all the answers

Calcium peroxide can be used for ecological restoration by stimulating aerobic microbial degradation.

<p>True (A)</p> Signup and view all the answers

What is the common name for K Al (SO4)2.12H2O?

<p>Potassium alum (A)</p> Signup and view all the answers

What is the E number for calcium peroxide as a food additive?

<p>E930</p> Signup and view all the answers

The primary use of S Odium aluminum sulfate is in water purification.

<p>False (B)</p> Signup and view all the answers

What is formed when sulfuric acid is added to the aluminum solution during the procedure?

<p>Solid precipitate</p> Signup and view all the answers

The chemical formula for potassium chromium (III) sulfate is K Cr(SO4)2._____H2O.

<p>12</p> Signup and view all the answers

Match the following types of alum with their primary uses:

<p>Ammonium alum = Picking cucumbers Ferric alum = Dyeing and printing textiles Potassium alum = Water purification Chrome alum = Tanning leather</p> Signup and view all the answers

Which alum is commonly used for mordant in dyeing textiles?

<p>Ammonium ferric sulfate (B)</p> Signup and view all the answers

The process of preparing alum includes heating the aluminum scrap until it is dry.

<p>False (B)</p> Signup and view all the answers

What is the role of potassium hydroxide in the procedure to prepare alum?

<p>Dissolve aluminum</p> Signup and view all the answers

Flashcards

Hydrated salt

A chemical compound that contains water molecules within its crystal structure, and these water molecules are essential for maintaining the crystal's shape.

Dehydration

The process of removing water molecules from a hydrated salt crystal.

Water of crystallization

The ratio of water molecules to salt molecules in a hydrated salt crystal.

Water content

The mass of water that is present in a hydrated salt.

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Formula of hydrated salt

The chemical formula that represents the composition of a hydrated salt, including the number of water molecules.

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Percentage of water in hydrated salt

The percentage of water by mass in a hydrated salt.

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Mass change

The change in mass of a hydrated salt after it has been heated to remove the water.

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Calculating Percentage of Water

A method used to experimentally determine the percentage of water in a hydrated salt.

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Alum

A compound that forms crystals with a specific structure, containing sulfate ions, a trivalent cation (like Al3+, Cr3+, or Fe3+), and a monovalent cation (like K+, Na+, or NH4+).

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Mordant

A substance that helps dyes stick to fabric. It contains metal ions that bind to the fabric fibers.

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Chromatography

The process of separating different components of a mixture based on their different affinities for a stationary phase (like chromatography paper) and a mobile phase (like a solvent).

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Capillary action

The ability of a liquid to move upwards in a narrow tube or space due to the forces of adhesion and cohesion.

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Solvent

A substance used to dissolve other substances, creating a solution.

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Mordant solution

A solution containing a metal ion that binds to a dye, making the dye adhere to the fabric.

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Crystallization

The process of forming crystals from a solution.

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Synthesis

The process of chemically changing a substance into a different substance.

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What is the RF value in Chromatography?

A measure of how strongly a solute interacts with the stationary phase in chromatography. RF values range from 0 to 1, where 1 indicates no affinity for the stationary phase and the solute travels with the solvent front.

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What is paper chromatography?

A technique used to separate mixtures of compounds based on their different affinities for a stationary phase and a mobile phase. It's commonly used to test the purity of compounds and identify substances.

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What is the stationary phase in paper chromatography?

The component of a chromatography system that remains stationary, typically a piece of filter paper in paper chromatography. The stationary phase interacts differently with various components of the mixture being analyzed.

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What is the mobile phase in paper chromatography?

The component of a chromatography system that moves, typically a solvent in paper chromatography. The mobile phase carries the mixture components along the stationary phase, with different components interacting differently and therefore migrating at different speeds.

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Explain how polarity affects separation in paper chromatography.

The difference in how readily various molecules in a mixture dissolve in the mobile phase. This difference leads to the separation of components as they move at different speeds through the stationary phase.

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What is spotting in paper chromatography?

The process of applying a small sample onto the stationary phase in chromatography. This is often done with a capillary tube to ensure a small, concentrated spot.

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What is the Distance Traveled by a Compound in Chromatography?

The distance traveled by a component in a chromatography system, divided by the distance travelled by the solvent front during the same time. It's a measure of how far a component has moved relative to the solvent front.

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What is the Solvent Front in Chromatography?

The point at which the solvent front reaches the top of the stationary phase in chromatography. It's used as a reference point to calculate the RF values of the components in the mixture.

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Reduction

A chemical reaction that involves the gain of electrons by a reactant, resulting in a decrease in its oxidation state.

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Electronegativity

The tendency of an atom, ion, or molecule to attract electrons towards itself.

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Halocarbon

A chemical compound containing a halogen atom (F, Cl, Br, or I) bonded to a carbon atom.

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Oxidation

A chemical reaction that occurs when a substance gains oxygen atoms or loses hydrogen atoms, resulting in an increase in its oxidation state.

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Lewis Acid

A compound that can accept an electron pair to form a coordinate bond. This results in a 'new' bond between the two atoms.

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Lewis Base

A chemical compound that can donate an electron pair to form a coordinate bond. The electron pair is transferred from the lone pair to the Lewis acid.

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Oxidation reaction

A reaction where a substance reacts with another substance to form a new compound with a higher oxidation state. The reactant undergoing oxidation loses electrons, while the oxidizing agent gains electrons.

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Reduction reaction

A reaction where a substance reacts with another substance to form a new compound with a lower oxidation state. The reactant undergoing reduction gains electrons, while the reducing agent loses electrons.

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What is calcium peroxide?

Calcium peroxide (CaO2) is a solid peroxide with a white or yellowish color. It is insoluble in water but can dissolve in acid, forming hydrogen peroxide. When in contact with water, it decomposes releasing oxygen.

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How is calcium peroxide prepared?

Calcium peroxide can be prepared by reacting solutions of calcium salts and sodium peroxide, followed by crystallization. The octahydrate can be synthesized by reacting calcium hydroxide with dilute hydrogen peroxide.

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What are the applications of calcium peroxide?

Calcium peroxide has various uses in different industries. In agriculture, it acts as an oxygen fertilizer and is used in rice seed treatments. It's also used to oxygenate and disinfect water in aquaculture and for soil treatment in environmental restoration.

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How does calcium peroxide help clean up contaminated soil?

Calcium peroxide is used in a similar way to magnesium peroxide in environmental restoration programs. By stimulating aerobic microbial degradation of contaminants, it helps restore soils and groundwater polluted with petroleum hydrocarbons.

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What is the role of calcium peroxide in food production?

Calcium peroxide is a food additive with the E number E930. It acts as a flour bleaching agent and improves flour quality.

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How is calcium peroxide octahydrate synthesized?

Calcium peroxide can be synthesized by reacting calcium hydroxide with dilute hydrogen peroxide. The resulting solution is then cooled and concentrated ammonia solution is added to precipitate calcium peroxide octahydrate.

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What are the key applications of calcium peroxide?

Calcium peroxide has many applications in industries like agriculture, aquaculture, environmental restoration, and food production.

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What are the primary methods for preparing calcium peroxide?

The main methods for preparing calcium peroxide include reacting calcium salts with sodium peroxide and reacting calcium hydroxide with dilute hydrogen peroxide.

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Study Notes

Inorganic Chemistry Lab Manual

  • This manual is for first-stage chemistry, second course, at Al-Nahrain University's College of Science.
  • It's edited by Lec. Hadeel Adel, As.lec. Marwa Fawzi, As.lec Kawther Adeeb, and As.lec Safa Ismaiel.

Contents

  • The manual includes a list of experiments, each with a title, page number, and description:

    • Laboratory Report (pg. 3)
    • Laboratory safety practices (pg. 4)
    • Glasses and laboratory equipment (pg. 6)
    • Preparation of sodium hydroxide (Exp. 1, pg. 8)
    • Purification of table salt (Exp. 2, pg. 10)
    • Preparation and reaction of barium peroxide (Exp. 3, pg. 13)
    • Calculate the percentage of water in hydrated salt (Exp. 4, pg. 15)
    • Paper chromatography (Exp. 5, pg. 17)
    • Synthesis of alum from aluminum (Exp. 6, pg. 20)
    • Halogens (Group VII B) (Exp. 7, pg. 23)
    • Preparation of Calcium Peroxide CaO2 (Exp. 8, pg. 25)
    • Preparation of Copper Iodate and Determination of Its Solubility Product in Water (Exp. 9, pg. 27)
    • Identification of Oxalate in their Complex (Exp. 10, pg. 29)
  • Each experiment includes:

    • A purpose/objectives
    • A theory/background
    • A procedure/steps
    • Details about chemicals and glassware used
    • And potential questions to be answered

Laboratory Safety Procedures

  • Emphasizes the importance of safety precautions in laboratories.
  • Covers key areas like:
    • Eye protection (safety glasses)
    • Footwear (shoes)
    • Prohibited activities (eating, drinking, smoking)
    • Hazard awareness (chemicals as potentially hazardous)
    • First aid and safety equipment locations
    • Proper handling of chemicals
    • Use of fume hoods for certain reactions
    • Avoiding pointing heated test tubes directly at oneself or others
    • Safe handling of glassware and broken glass cleanup
    • Proper pouring of acids into water
    • Proper reagent handling

Lab Report Format

  • Outlines the components of a lab report:
    • Title
    • Objective
    • Introduction
    • Procedure
    • Discussion (data analysis, learning points, areas for improvement)

Laboratory Equipment

  • Provides a visual guide and descriptions for various laboratory equipment (beaker, flask, pipettes, test tubes, crucible, etc.).
  • Describes the functions of each item.

Specific Experiment Details (selected examples)

  • Experiment No. 1 (Preparation of Sodium Hydroxide):

    • Sodium hydroxide (NaOH) is a metallic base.
    • It's hygroscopic and should be stored in airtight containers.
    • It's corrosive and can cause burns to skin and eyes.
  • Experiment No. 4 (Calculating Water Percentage in Hydrated Salts):

    • Water of crystallization/hydration is the water present in crystals.
    • It's crucial for maintaining crystal properties.
    • It's present in specific ratios for some salts.
  • Experiment No. 5 (Paper Chromatography):

    • A technique to separate and identify mixtures (e.g., ink pigments, amino acids).
    • It involves separating substances based on differing solubilities in a solvent.
    • Used to determine retention factors (Rf values) which help identify compounds based on the distance they've travelled within the solvent.
  • Experiment No. 6 (Synthesis of Alum):

    • Alum is an ionic compound.
    • It crystallizes as octahedral shapes, often with specific colours.
    • Has historically seen use in dyeing, fabric treatments and other industrial applications.

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