Hydrogen Properties and Reactions Quiz

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Questions and Answers

What is the electron configuration of hydrogen?

  • 1s¹ (correct)
  • 2p¹
  • 2s¹
  • 1s²

Hydrogen's placement on the periodic table is definitively as an alkali metal.

False (B)

Name one method for producing hydrogen gas on a laboratory scale?

Reaction of zinc with hydrochloric acid

The steam reforming of methane produces carbon monoxide and ______.

<p>hydrogen</p> Signup and view all the answers

Match the following with their appropriate descriptions:

<p>Steam Reforming = A method for industrial hydrogen production. Laboratory Scale Hydrogen Production = Uses zinc and hydrochloric acid. Hydrogen's Periodic Table Placement = Questionable, could be an alkali metal or a halogen. Electron Affinity = Measured in kJ/mol</p> Signup and view all the answers

What is the driving force for the reaction of carbon with steam at 1000°C?

<p>Entropy (B)</p> Signup and view all the answers

The reaction of carbon with water to create hydrogen is exothermic.

<p>False (B)</p> Signup and view all the answers

In the steam reforming of methane, what acts as a catalyst?

<p>Nickel</p> Signup and view all the answers

The steam reforming of methane occurs at approximately ______ degrees Celsius.

<p>1000</p> Signup and view all the answers

What does the symbol 'ΔHrxn' represent?

<p>Enthalpy change of a reaction (B)</p> Signup and view all the answers

Which type of hydrides are characterized by reduced hydrogen, i.e., [M+H–]?

<p>Saline hydrides (B)</p> Signup and view all the answers

The formation of saline hydrides is generally endoergic.

<p>False (B)</p> Signup and view all the answers

What is the color of dilute solutions of alkali metals in liquid ammonia?

<p>dark blue</p> Signup and view all the answers

Lithium is used as a CO2 absorber in space capsules and submarines in the form of ______.

<p>LiOH</p> Signup and view all the answers

Which of these is NOT a typical type of reactivity pattern for hydrides?

<p>Oxidation (B)</p> Signup and view all the answers

The compounds SiH4 is less reactive than CH4

<p>False (B)</p> Signup and view all the answers

What method was used to discover Li, Na, and K?

<p>electrolysis</p> Signup and view all the answers

Crown ethers and cryptands are special Lewis bases designed to selectively bind ______.

<p>metal cations</p> Signup and view all the answers

Match the following hydrides with their descriptions:

<p>Metallic Hydrides = often non-stoichiometric and conducting Saline Hydrides = salt-like solids of alkali and alkaline earth metals Molecular Hydrides = include electron precise, basic, weak-acid, strong-acids and electron-deficient hydrides</p> Signup and view all the answers

Which of the following is a common use for Li2CO3?

<p>Hardening agent for glass (D)</p> Signup and view all the answers

Which of the following crown ethers is best suited for complexing with Na+?

<p>benzo-15-crown-5 (A)</p> Signup and view all the answers

Organolithium reagents are most stable when R is equal to a primary alkyl group.

<p>False (B)</p> Signup and view all the answers

What type of solvent is used to prevent aggregation in arene reduction reactions?

<p>ethereal solvents</p> Signup and view all the answers

In the formation of primary alcohols using Grignard reagents, the first step involves the reaction of RMgX with ____.

<p>O2</p> Signup and view all the answers

Match the following metal complexes with the corresponding cation they best complex:

<p>18-crown-6 = K+, Sr2+ dibenzo-14-crown-4 = Li+, Mg2+ benzo-15-crown-5 = Na+, Ca2+ [2.2.2] cryptand = K+</p> Signup and view all the answers

In the formation of organolithium reagents, which of the following reaction best describes the process?

<p>$2Li^0 + RX \rightarrow LiR + LiX$ (D)</p> Signup and view all the answers

The reactivity of organomagnesium reagents with alkyl halides is lower than their reactivity with aryl halides.

<p>False (B)</p> Signup and view all the answers

What is the general role of an organomagnesium (Grignard) reagent in a chemical reaction?

<p>nucleophile</p> Signup and view all the answers

In metal-halogen exchange, tBuLi reacts with PhI to form ______ and tBuX.

<p>PhLi</p> Signup and view all the answers

Match the following organometallic compounds with their respective applications:

<p>Organolithium Reagents = Strong base and for nucleophilic addition Grignard Reagents = Carbanion nucleophile to attack an electrophile Alkalides = Encapsulate a metal cation Electrides = Encapsulate an electron</p> Signup and view all the answers

What is the delta H (ΔH) for the water-gas shift reaction?

<p>-9.8 kcal/mol (D)</p> Signup and view all the answers

The production of ammonia is an endothermic process.

<p>False (B)</p> Signup and view all the answers

Besides ammonia production, what is another use of hydrogen mentioned in the text?

<p>Medicinal chemistry / Food chemistry</p> Signup and view all the answers

Hydrogen is considered an attractive fuel because it has a high heat of ________ and produces zero pollution.

<p>combustion</p> Signup and view all the answers

Match the following reactions with their $\Delta$H values:

<p>CH4 (g) + H2O (g) -&gt; CO (g) + 3H2 (g) = 49.3 kcal/mol N2 (g) + 3H2 (g) -&gt; 2NH3 (g) = -11 kcal/mol H2 (g) + 1/2O2 (g) -&gt; H2O (g) = -57.8 kcal/mol CO (g) + H2O (g) -&gt; CO2 (g) + H2 (g) = -9.8 kcal/mol</p> Signup and view all the answers

What is the delta H (ΔH) for the reaction: CH4(g) + 2O2(g) → CO2(g) + 2H2O(g)?

<p>-192 kcal/mol (A)</p> Signup and view all the answers

The water-gas shift reaction produces hydrogen and water as products.

<p>False (B)</p> Signup and view all the answers

What are the two main products of the reaction that forms hydrogen from methane and water?

<p>CO and H2 / carbon monoxide and hydrogen</p> Signup and view all the answers

The main problem with hydrogen production is that it currently relies on __________.

<p>fossil fuels</p> Signup and view all the answers

Which of these reactions has the most negative value for $\Delta$H?

<p>4H2 (g) + 2O2 (g) -&gt; 4H2O (g) (C)</p> Signup and view all the answers

Flashcards

Hydrogen's Position on the Periodic Table

The simplest element with a 1s1 electron configuration. Its placement on the Periodic Table is debated - is it an alkali metal, a halogen, or should it be placed above carbon?

Ionization Energy

The energy required to remove an electron from a gaseous atom in its ground state. It is measured in kJ/mol.

Electron Affinity

The energy change that occurs when an electron is added to a gaseous atom in its ground state. It is measured in kJ/mol.

Electronegativity

A measure of an atom's ability to attract electrons in a chemical bond. It is a relative scale, with fluorine being the most electronegative element.

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Hydrogen Production

A reaction that produces hydrogen gas. Common methods include the reaction of zinc with hydrochloric acid (laboratory scale) and the steam reforming of methane (industrial scale).

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Hydrogen Production: Zinc and Hydrochloric Acid

A method of producing hydrogen gas in the laboratory by reacting zinc with hydrochloric acid. This reaction produces zinc chloride and hydrogen gas as products.

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Hydrogen Production: Steam Reforming

An industrial process that uses methane and steam to produce hydrogen and carbon monoxide as products. The reaction is driven by entropy and occurs at high temperatures.

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Entropy in Steam Reforming

The tendency of a system to increase its disorder or randomness. In the steam reforming process, the reaction is driven by entropy because the products are more disordered than the reactants.

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Enthalpy Change (ΔHrxn)

The change in enthalpy (heat content) that occurs during a chemical reaction. A positive value indicates an endothermic reaction where heat is absorbed, while a negative value indicates an exothermic reaction where heat is released.

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Carbon and Steam Reaction

The reaction between carbon and steam at high temperatures, which produces carbon monoxide and hydrogen gas as products. This reaction is driven by entropy and is part of the overall steam reforming process.

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Hydrogen Compounds

These compounds are formed when hydrogen combines with other elements.

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Metallic Hydrides

Metallic hydrides are formed by the reaction of hydrogen with transition metals. They are good conductors of electricity.

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Saline Hydrides

These compounds are formed by the reaction of hydrogen with alkali or alkaline earth metals. They are non-conductors of electricity.

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Electron Precise Hydrides

These hydrides have a fixed number of electrons that form covalent bonds.

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Basic Covalent Hydrides

These hydrides have lone pairs of electrons that can accept protons, making them basic.

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Electron Deficient Hydrides

These hydrides have a central atom surrounded by less than 8 electrons, leading to electron deficiency.

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Strong Acids

These hydrides are formed by elements that have a high electronegativity difference with hydrogen, making them acidic.

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Hydride Stability

The change in free energy (∆G) associated with the formation of hydrides from their elements.

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Hydride Synthesis

The process of creating hydrides. It can occur through direct reaction, protonation, or metathesis.

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Hydride Reactivity

The breaking down of hydrides into other compounds. It can happen through homolytic cleavage, hydride transfer, or proton transfer.

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Water-Gas Shift Reaction

A chemical reaction that involves the conversion of carbon monoxide (CO) and water vapor (H2O) into carbon dioxide (CO2) and hydrogen gas (H2).

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Ammonia Production

A chemical reaction that involves the combination of nitrogen gas (N2) and hydrogen gas (H2) under high temperature and pressure to produce ammonia (NH3).

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Exothermic Reaction

A chemical reaction that releases or absorbs energy.

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Endothermic Reaction

A chemical reaction that absorbs energy.

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Enthalpy Change (ΔH)

The amount of energy released or absorbed during a chemical reaction.

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Hydrogen Economy

A hypothetical future energy system based on the production, storage, and use of hydrogen as a primary energy carrier.

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Hydrogen Combustion

A chemical reaction that involves the combustion of hydrogen gas (H2) with oxygen gas (O2) to produce water vapor (H2O) and release a significant amount of energy.

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Fossil Fuel-Based Hydrogen Production

A process that uses fossil fuels to produce hydrogen gas. It involves the reaction of methane with water vapor, producing carbon monoxide and hydrogen.

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Overall Energy Change

The total amount of energy released or absorbed during a chemical reaction.

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Heat of Combustion

A measure of energy content, often expressed in kilocalories (kcal).

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Crown Ethers and Cryptands

A class of compounds that include crown ethers and cryptands, which can bind to specific cations based on their size and charge.

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18-crown-6

A crown ether with six oxygen atoms and a cavity size that is best suited for binding potassium cations.

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Arene Reduction

A process that involves the reduction of an arene using an alkali metal as a reducing agent in ethereal solvents.

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Organolithium Reagents

A type of organometallic compound that is formed by the reaction of an alkyl or aryl halide with lithium metal.

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Metal-Halogen Exchange

A method of preparing aryl lithium compounds by reacting an aryl halide with an alkyl lithium reagent.

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Transmetallation

A method of preparing unsaturated organolithium compounds by reacting an organolithium reagent with a vinyl derivative of tin.

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Organomagnesium (Grignard) Reagents

A type of organometallic compound that is formed by the reaction of an alkyl or aryl halide with magnesium metal.

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Formation of Primary Alcohols from Grignard Reagents

The process of forming primary alcohols from Grignard reagents by reacting them with oxygen followed by an acidic workup.

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Formation of Substituted Alcohols from Grignard Reagents

The process of forming substituted alcohols from Grignard reagents by reacting them with ketones or aldehydes followed by an acidic workup.

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Study Notes

Chemistry of the Main Group Elements: Hydrogen, Alkali and Alkaline Earth Metals

  • Main group elements include hydrogen, alkali metals, and alkaline earth metals.
  • The placement of hydrogen on the periodic table is debated. Options include above carbon or amongst the alkali or halogen families.

Hydrogen

  • Hydrogen has the simplest electron configuration (1s¹).
  • Its placement on the periodic table is uncertain.
  • It could be classified as an alkali metal, a halogen, or positioned above carbon.

Hydrogen Production

  • One method is a reaction between zinc and hydrochloric acid
  • Zn(s)+2HCl(aq)→ZnCl2(aq)+ H₂(g)
  • Steam reforming breaks down methane and water to produce hydrogen
  • CH₄(g)+H₂O(g) 1000°C →CO(g)+3H2(g) ΔΗ = +49.3 kcal/mol
  • Water gas shift produces carbon monoxide and hydrogen
  • C(s)+ H₂O(g) 1000°C →CO(g)+ H₂(g) ΔΗ = +31.4 kcal/mol
  • Water-gas shift converts carbon monoxide to carbon dioxide
  • CO(g)+H₂O(g) 300°C → CO2 (g)+ H2(g) ΔΗ = −9.8 kcal/mol

Hydrogen Use

  • Hydrogen is crucial in ammonia production.
  • N2(g)+3H2(g) 450°C → 2NH3(g) ΔH = −11 kcal/mol
  • Also used in medicinal and food chemistry, with examples like reactions involving L-DOPA and specific fatty acid processing.

The Hydrogen Economy

  • Hydrogen is an attractive fuel because of its high heat of combustion and zero pollution when combusted with oxygen (H₂(g)+ O2(g) → H₂O(g)).
  • The challenge is that using hydrogen from fossil fuels creates the same pollution and energy output as burning methane (CH₄(g)+2O2(g)→CO₂(g)+2H₂O(g))
    • This means hydrogen needs to derive from non-fossil fuel sources for clean energy.

Types of Hydrogen Compounds

  • Metallic hydrides are often non-stoichiometric, meaning they have a non-fixed ratio of metals and hydrogen. Examples include MgH2 and NiHx.
  • Saline hydrides are salt-like compounds formed from alkali and alkaline earth metals with reduced hydrogen, such as MH.
  • Molecular hydrides consist of electron-precise compounds like CH4 and SiH4. Other examples include those with basic covalent bonds like NH3 or weak acid covalent bonds like H2O

Hydride Stability

  • Formation of saline hydrides is generally exothermic (ΔG < 0)
  • Formation of covalent hydride compounds can be exothermic or endothermic.
  • Compounds in the second row and below show a tendency for endothermic formation, and these are highly reactive.

Hydride Synthesis and Reactivity

  • Synthesis methods include direct reaction and protonation
  • Reactivity patterns commonly involve homolytic cleavage, hydride transfer, and proton transfer.

Alkali and Alkaline Earth Metals

  • These metals occur naturally in various minerals, found in structures like rock salt (NaCl), carnallite (KCl∙MgCl₂ • 6 H₂O), beryl (Be₃Al₂(SiO₃)₆), limestone (CaCO₃), and dolomite (CaCO₃∙MgCO₃).
  • Alkali metals (Li, Na, K) were discovered via electrolysis.
  • Cesium and Rubidium were discovered spectroscopically in mineral spa water.
  • Lithium is used in, for example, ceramic fluxes, specific psychiatric treatments and as an ingredient in lightweight alloys.
  • Some alkali metals dissolve in liquid ammonia, forming solvated electron solutions. This is visually apparent because the solutions become a deep blue color.

Alkalides and Electrides

  • Crown ethers are special Lewis bases that selectively bind metal cations (like sodium).
  • Cryptands are larger molecules that can also bind metal ions
  • Electrides are formed when alkali metals react with these types of structures in particular environments.

Organometallic Chemistry

  • Arene Reduction: Ethereal solvents are used to stop metallic reductions from forming aggregates, such as by adding Na/ or Na+. The resultant reduced arene is deep green to deep blue due to solvated electrons.
  • Organolithium Reagents: LiR reagents are formed with alkyl halides (RX) in the presence of alkali metals (Li) and solvents. LiR reagents are strongest when R is alkyl (like methyl, n-butyl or tert-butyl). They exhibit nucleophilic properties.
  • More Organolithium Chemistry: Aryl derivatives can be synthesized by metal-halogen exchange. Unsaturated derivatives are created with transmetallation methods. These organolithium reagents have very broad reactivity profiles.

Organomagnesium Chemistry

  • Organomagnesium (Grignard): RMgX (Grignard reagents) are formed through a reaction between Mg⁰ and RX. Grignard reagents primarily react as carbanions (nucleophiles), thus are strong bases.
  • Reactivity Patterns: Grignard reagents primarily react with electrophiles, including primary and substituted alcohols, and with certain organic halides, compounds with sulfur atoms and nitrogen.

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