Hydrogen Nuclear Spin Isomers
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Questions and Answers

What is the key difference between parahydrogen and orthohydrogen?

  • Number of protons
  • Electron arrangement
  • Number of neutrons
  • Nuclear spin direction (correct)

What happens to the ratio of para form to ortho form in hydrogen gas when cooled to 20K?

  • 25% para, 75% ortho
  • Stays the same
  • Becomes almost pure parahydrogen (correct)
  • Becomes almost pure orthohydrogen

How are the two nuclei in a dihydrogen molecule different?

  • They have different nuclear spin directions (correct)
  • They are antiparallel
  • They are parallel
  • They have different number of protons

Which type of nuclear spin does the proton of a hydrogen atom possess?

<p>+1/2 or -1/2 (C)</p> Signup and view all the answers

What defines isotopes in chemistry?

<p>Same number of protons and neutrons (B)</p> Signup and view all the answers

What is the nuclear spin isomer called in dihydrogen where the two nuclei may be parallel or opposed?

<p>Para-dihydrogen (D)</p> Signup and view all the answers

Which element is the most abundant in the universe?

<p>Hydrogen (B)</p> Signup and view all the answers

At room temperature, dihydrogen is relatively unreactive because:

<p>It requires large amounts of energy for homolysis of H–H (B)</p> Signup and view all the answers

Which element does hydrogen NOT form compounds with?

<p>Noble gases (D)</p> Signup and view all the answers

What is the percentage of hydrogen in the Earth's crust on an atom basis?

<p>15.4% (A)</p> Signup and view all the answers

Which property describes the angular momentum of electrons in a molecule?

<p>Spin projection (A)</p> Signup and view all the answers

What is the main factor determining the chemical behaviour of hydrogen isotopes?

<p>Electronic structure (A)</p> Signup and view all the answers

Which isotope of hydrogen is radioactive with a half-life of 12 years?

<p>Tritium T (B)</p> Signup and view all the answers

In which physical property do deuterium and tritium show a quantitative difference compared to protium?

<p>Density (D)</p> Signup and view all the answers

What is the term for the phenomenon where rats can distinguish between D2O and H2O, preferring the latter?

<p>Parahydrogen effect (C)</p> Signup and view all the answers

Which of the following hydrogen isotopes has the highest boiling point?

<p>$T_{2}$ (D)</p> Signup and view all the answers

What does the difference in mass between hydrogen isotopes mainly lead to?

<p>Quantitative differences in physical properties (D)</p> Signup and view all the answers
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