Homologous Series of Alkanes and Alkenes
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Homologous Series of Alkanes and Alkenes

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@JoyfulDerivative

Questions and Answers

What is the difference in the molecular formulas between propane (C3H8) and butane (C4H10)?

  • They differ by a -C2H4 unit
  • They differ by a -CH2 unit (correct)
  • They have the same molecular formula
  • They differ by a -CH3 unit
  • Which is the correct general formula for alkenes?

  • CnH2n (correct)
  • CnH2n+2
  • CnH2n-2
  • CnH2n+1
  • How does molecular mass affect the physical properties of compounds in homologous series?

  • Higher molecular mass generally increases melting and boiling points (correct)
  • Higher molecular mass leads to lower melting and boiling points
  • molecular mass only affects solubility
  • Molecular mass has no effect on physical properties
  • What is the second member of the alkene series following ethene?

    <p>Propene (C3H6)</p> Signup and view all the answers

    What remains similar across members of a homologous series despite changes in molecular mass?

    <p>The chemical properties determined by functional groups</p> Signup and view all the answers

    Which of the following is NOT a characteristic of homologous series?

    <p>Variability in chemical properties</p> Signup and view all the answers

    For the compounds CH3OH and C2H5OH, what is the difference in their molecular masses?

    <p>18 u</p> Signup and view all the answers

    What is the molecular formula for the first member of the alkane series?

    <p>CH4</p> Signup and view all the answers

    What is the term for compounds that have the same molecular formula but different structures?

    <p>Isomers</p> Signup and view all the answers

    Which of the following hydrocarbons is classified as an alkane?

    <p>C4H10</p> Signup and view all the answers

    What type of bond do alkenes contain that distinguishes them from alkanes?

    <p>Double bonds</p> Signup and view all the answers

    Considering the molecular mass, which of the following hydrocarbons has the highest mass?

    <p>Hexane (C6H14)</p> Signup and view all the answers

    Which compound has a cyclic structure?

    <p>Cyclohexane</p> Signup and view all the answers

    What is the main characteristic of saturated hydrocarbons?

    <p>They contain only single bonds.</p> Signup and view all the answers

    In the homologous series of alkanes, each subsequent member differs by how many carbon and hydrogen atoms?

    <p>1 carbon and 2 hydrogen atoms</p> Signup and view all the answers

    What is the formula for benzene?

    <p>C6H6</p> Signup and view all the answers

    What is the primary reason compounds like ethanol and methane do not conduct electricity?

    <p>They lack mobile electrons.</p> Signup and view all the answers

    What configuration of electrons is necessary for carbon to attain noble gas configuration?

    <p>It must share four electrons.</p> Signup and view all the answers

    What type of bond formation allows carbon to overcome the challenges of gaining or losing electrons?

    <p>Covalent bonding with other atoms.</p> Signup and view all the answers

    Which molecule represents a simple example of carbon sharing its valence electrons?

    <p>Methane (CH4).</p> Signup and view all the answers

    How many valence electrons does a carbon atom have?

    <p>Four.</p> Signup and view all the answers

    Why is it energetically unfavorable for carbon to form a C4- anion?

    <p>The nucleus cannot hold excess electrons.</p> Signup and view all the answers

    Which property of carbon compounds allows for the formation of larger molecules?

    <p>The ability to form covalent bonds.</p> Signup and view all the answers

    Which characteristic of carbon's outer shell influences its reactivity?

    <p>A partial fill of valence electrons.</p> Signup and view all the answers

    Study Notes

    Homologous Series of Alkanes

    • Succession in alkanes shows that each compound differs by a –CH2– unit:
      • CH4 (Methane) and C2H6 (Ethane)
      • C2H6 (Ethane) and C3H8 (Propane)
    • Propane (C3H8) and Butane (C4H10) also differ by a –CH2– unit.
    • Molecular masses differ by 14 u between successive alkanes (12 u for C and 1 u for H).

    Homologous Series of Alkenes

    • Ethene (C2H4) is the first member, followed by C3H6 (Propene), C4H8 (Butene), and C5H10 (Pentyne).
    • Each succeeding alkene differs by a –CH2– unit.
    • General formula for alkenes: CnH2n, where n = 2, 3, 4, etc.

    Homologous Series General Formulas

    • General formula for alkanes: CnH2n+2.
    • General formula for alkynes: CnH2n-2.

    Physical and Chemical Properties

    • As molecular mass increases in a homologous series, melting and boiling points rise.
    • Physical properties such as solubility vary with molecular mass.
    • Chemical properties are dictated by the functional group, remaining consistent across a homologous series.

    Alcohols Comparison

    • Differences in formulae and molecular masses are observed among:
      • CH3OH (Methanol) and C2H5OH (Ethanol)
      • C2H5OH (Ethanol) and C3H7OH (Propanol)
      • C3H7OH (Propanol) and C4H9OH (Butanol)
    • All compounds are non-conductors of electricity, indicating a lack of ions.

    Carbon's Electronic Configuration

    • Atomic number of carbon is 6, having the electronic configuration of 2, 4.
    • Four valence electrons make carbon unique in forming covalent bonds rather than ionic.
    • Carbon shares electrons with itself or other elements to achieve noble gas configuration.

    Molecular Structures of Alkanes

    • Common alkanes include:
      • Methane: CH4
      • Ethane: C2H6
      • Propane: C3H8
      • Butane: C4H10
      • Pentane: C5H12
      • Hexane: C6H14

    Structural Isomers

    • Butane exhibits structural isomerism with different arrangements of carbon atoms but the same molecular formula (C4H10).
    • Isomers include straight-chain and branched forms.

    Cyclic Hydrocarbons

    • Cyclohexane has the formula C6H12.
    • Cyclohexane can be represented with different structural formats.

    Hydrocarbons Classification

    • Hydrocarbons consist solely of carbon and hydrogen.
    • Saturated hydrocarbons (alkanes) have single bonds; unsaturated hydrocarbons (alkenes) possess one or more double bonds, illustrated by benzene (C6H6).

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    Description

    This quiz covers the homologous series of alkanes and alkenes, including their general formulas and molecular mass differences. Explore how compounds in these series differ by -CH2- units and their physical and chemical properties. Test your knowledge on the key concepts related to hydrocarbons.

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