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Questions and Answers
What is a primary feature that distinguishes intrinsic semiconductors from conductors?
What is a primary feature that distinguishes intrinsic semiconductors from conductors?
Which type of semiconductor is formed by adding elements with fewer valence electrons than the semiconductor material?
Which type of semiconductor is formed by adding elements with fewer valence electrons than the semiconductor material?
What effect do impurities have on semiconductor materials?
What effect do impurities have on semiconductor materials?
Which of the following is a common doping technique for creating N-type semiconductors?
Which of the following is a common doping technique for creating N-type semiconductors?
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What primarily determines the conduction mechanism in semiconductors?
What primarily determines the conduction mechanism in semiconductors?
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What characteristic of a semiconductor allows it to be conditioned to behave like a conductor or an insulator?
What characteristic of a semiconductor allows it to be conditioned to behave like a conductor or an insulator?
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How does doping affect the electron flow in semiconductors?
How does doping affect the electron flow in semiconductors?
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Which element is considered the best and most widely used semiconductor material?
Which element is considered the best and most widely used semiconductor material?
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What is the primary effect of doping semiconductors with donor dopants?
What is the primary effect of doping semiconductors with donor dopants?
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Which element is commonly used as a donor dopant in silicon?
Which element is commonly used as a donor dopant in silicon?
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What type of semiconductor is formed when silicon is doped with boron?
What type of semiconductor is formed when silicon is doped with boron?
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In terms of conductivity, how does an increase in the number of donor dopants affect a semiconductor?
In terms of conductivity, how does an increase in the number of donor dopants affect a semiconductor?
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What charge does boron assume after acting as an acceptor dopant?
What charge does boron assume after acting as an acceptor dopant?
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What is a hole in the context of semiconductor materials?
What is a hole in the context of semiconductor materials?
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Which of the following statements about N-type semiconductors is true?
Which of the following statements about N-type semiconductors is true?
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What is the relationship between the amount of doping and the resistance of a semiconductor?
What is the relationship between the amount of doping and the resistance of a semiconductor?
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What is the defining characteristic of an intrinsic semiconductor?
What is the defining characteristic of an intrinsic semiconductor?
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Which statement correctly describes doping in semiconductors?
Which statement correctly describes doping in semiconductors?
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Which type of semiconductor is primarily characterized by the presence of excess holes?
Which type of semiconductor is primarily characterized by the presence of excess holes?
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What is the role of an impurity element like arsenic in a semiconductor?
What is the role of an impurity element like arsenic in a semiconductor?
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What type of crystal structure does a monocrystal semiconductor possess?
What type of crystal structure does a monocrystal semiconductor possess?
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What is the effect of tightly bound valence electrons in intrinsic semiconductors?
What is the effect of tightly bound valence electrons in intrinsic semiconductors?
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In the context of semiconductor theory, what is meant by electron-hole pairs?
In the context of semiconductor theory, what is meant by electron-hole pairs?
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What occurs when a semiconductor crystal is doped primarily with elements that have fewer valence electrons than silicon?
What occurs when a semiconductor crystal is doped primarily with elements that have fewer valence electrons than silicon?
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Study Notes
Introduction to Semiconductors
- Electronic materials aim to generate and control electrical current flow.
- Types of electronic materials include:
- Conductors: low resistance, allow current flow easily
- Insulators: high resistance, suppress current flow
- Semiconductors: can either allow or suppress current flow, depending on conditions
Conductors
- Good conductors have low resistance, allowing easy electron flow.
- Best elemental conductors include copper, silver, gold, aluminum, and nickel.
- Alloys like brass and steel are also good conductors.
- Some conductors can be liquid, such as salt water.
Conductor Atomic Structure
- Good conductors' atomic structure usually has only one electron in their outer shell.
- This outer electron, called a valence electron, is easily stripped from the atom, facilitating current flow.
Insulators
- Insulators have high resistance, preventing current flow.
- Common insulators include glass, ceramics, plastics, and wood.
- Most insulators are compounds of multiple elements.
- Atoms are tightly bound in insulators, making it hard to strip electrons for current flow.
Semiconductors
- Semiconductors can be controlled to act as either good conductors or good insulators.
- Common semiconductor elements include carbon, silicon, and germanium.
- Silicon is the most widely used semiconductor.
Periodic Table of Elements
- The provided periodic table highlights semiconductor materials.
Semiconductor Valence Orbit
- The defining characteristic of a semiconductor element is its four valence electrons in the outer orbit. (Silicon is shown as an example.)
Crystal Lattice Structure
- Semiconductors have a unique capability to link atoms together to form a physical structure called a crystal lattice.
- Atoms link together by sharing outer electrons forming covalent bonds.
- This creates a 2D and 3D crystal lattice structure.
Semiconductor Structure
- Semiconductors can have a crystalline or polycrystalline structure.
Semiconductors Can Be Insulators
- Pure semiconductors, like silicon, resist current flow due to tightly bound atoms in their crystal lattice.
- These pure, intrinsic semiconductors are good insulators.
Intrinsic Material
- A perfect semiconductor crystal without impurities or lattice defects is called an intrinsic semiconductor.
Doping
- Doping is the addition of impurities to semiconductors to alter their electrical properties.
- Impurities are different elements to those already present.
- Doping allows semiconductors to either conduct electricity more easily (n-type) or resist electricity more easily (p-type)
Semiconductors Can Be Conductors
- Impurity atoms, such as arsenic, with five valence electrons can be added to silicon to create an abundance of free electrons, becoming n-type semiconductors.
- By adding these impurities, an abundance of 'free' electrons can move around to conduct current.
Improving Conduction by Doping
- Adding impurities, also called dopants, can change the conductivity of semiconductors.
- Elements with 5 outer electrons (donor dopants) contribute extra electrons, increasing conductivity (n-type).
- Elements with 3 outer electrons (acceptor dopants) accept an electron from the silicon, creating holes for increased conductivity (p-type).
Doping - Phosphorus and Arsenic
- Phosphorus and arsenic, added as impurities (dopants), introduce extra electrons, resulting in n-type.
- The extra electron is free to move around and contribute to electric current.
- The phosphorus becomes a positive ion after giving up an electron.
Doping - Boron
- Boron, with three valence electrons, creates holes in the silicon crystal lattice, producing p-type.
- The space left is identified as a hole, behaving like a positive charge and attracting electrons.
- Boron becomes a negative ion after accepting an electron.
Resistance Effects of Doping
- Higher doping concentration generally leads to lower resistance and greater conductivity in semiconductors.
- Doping amount controls semiconductor resistance.
Another Way to Dope
- Impurities with fewer than 4 valence electrons create a hole.
- Creating holes gives them the capability to attract and conduct current.
Types of Semiconductor Materials
- Silicon doped with extra electrons forms N-type semiconductors (N for negative due to the electron charge).
- Silicon with electron-missing "holes" forms P-type semiconductors (P for positive due to the positive charge of the hole).
Current Flow in Semiconductors
- A DC voltage source with a positive terminal attracts free electrons in a semiconductor, creating a positive charge.
- Electrons flow from the negative terminal to the positive in conventional current flow.
- In the semiconductor, 'hole' movement is an important conductor.
In Summary
- Pure semiconductors are insulators.
- Doping changes conductivity, creating N-type (extra electrons) and P-type (missing electrons/holes).
- Increased doping increases conductivity.
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