History of Atomic Theory

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Questions and Answers

What is the main principle behind the arrangement of electrons in an atom?

  • Electrons occupy fixed orbits like planets around the sun.
  • Electrons always move randomly around the nucleus.
  • Electrons fill energy levels and sublevels based on energy levels. (correct)
  • Electrons are arranged based on their charge only.

Which of the following represents an example of an electron configuration?

  • ¹⁰Ne = 1s² 2s² 2p⁶ (correct)
  • ¹⁰Ne = 1s² 2s² 2p⁴
  • ¹⁰Ne = 2s² 2p⁶ 3s²
  • ¹⁰Ne = 3s² 3p²

According to the Aufbau principle, how do electrons fill the orbitals?

  • Electrons fill the highest energy orbitals first.
  • Electrons can fill any available orbital without a specific order.
  • Electrons fill orbitals based on their mass.
  • Electrons fill orbitals starting from the lowest energy levels. (correct)

What does Hund's rule state about electron distribution in orbitals?

<p>All orbitals must be filled before any pairing occurs. (B)</p> Signup and view all the answers

How many electrons can each orbital accommodate?

<p>2 electrons regardless of their energy level. (A)</p> Signup and view all the answers

What term did Democritus use to describe the smallest piece of matter?

<p>Atomos (C)</p> Signup and view all the answers

According to John Dalton's theory, what is true about atoms of the same element?

<p>They are exactly alike. (D)</p> Signup and view all the answers

What did J.J. Thomson discover in 1897?

<p>The existence of electrons. (D)</p> Signup and view all the answers

Which model of the atom is associated with J.J. Thomson?

<p>Plum Pudding model (D)</p> Signup and view all the answers

What was Ernest Rutherford's key contribution to atomic theory?

<p>Atoms consist of a nucleus containing positively charged particles. (A)</p> Signup and view all the answers

In the Bohr model, electrons are said to move in a manner analogous to which of the following?

<p>Planets orbiting the sun (B)</p> Signup and view all the answers

What improvement did Arnold Sommerfeld make to the Bohr model?

<p>Added the concept of elliptical orbits. (D)</p> Signup and view all the answers

What is the significance of Erwin Schrödinger in atomic theory?

<p>Introduced the wave mechanics approach to atoms. (C)</p> Signup and view all the answers

Flashcards

Atom

The smallest particle of an element; the smallest amount of a substance that can take part in a chemical reaction.

Democritus' Atom

Democritus's idea of the atom, proposing indivisible and different-shaped particles.

Dalton's Atomic Theory

All elements are composed of atoms; atoms of the same element are identical; compounds form from atoms combining.

Thomson's Model

Proposed a "plum pudding" model of the atom: a positively charged substance with negatively charged electrons scattered about.

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Rutherford's Experiment

An experiment demonstrating the existence of a small dense, positively charged nucleus with electrons spread outside.

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Bohr Model

Electrons orbit the nucleus in specific energy levels, like planets around a star.

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Sommerfeld's Modification

Electrons orbit the nucleus in elliptical as well as circular paths.

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Electron

Negatively charged particles found orbiting the nucleus of an atom.

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Electron Configuration

The arrangement of electrons in energy levels around an atom's nucleus, represented as a shorthand of electron distribution among orbitals, energy levels, and sublevels.

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Electron Orbital

A space where electrons are most likely to be found around the nucleus.

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Aufbau Principle

Electrons fill orbitals starting with the lowest energy level and moving upwards.

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Pauli Exclusion Principle

No two electrons can have the same set of quantum numbers, meaning no two electrons in an atom can have the same spin in the same orbital.

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Hund's Rule

Each orbital in a sublevel is singly filled with one electron before any orbital receives a second electron.

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Study Notes

Atomic Theory History

  • Atoms are the smallest particles of an element.
  • Atoms are the smallest amount of a substance that participates in chemical reactions.
  • Democritus, a Greek philosopher, searched for a description of matter.
  • He named the smallest piece of matter "atomos" (indivisible).
  • These atoms were small, hard particles, all made of the same material, but different shapes and sizes.
  • John Dalton (English chemist) performed experiments leading to the acceptance of the atomic theory.
  • He deduced that all elements are composed of atoms.
  • Atoms of the same element are exactly alike.
  • Atoms of different elements are different.
  • Compounds are formed when atoms of different elements combine.
  • J.J. Thomson (English scientist) discovered the electron and suggested the "Plum Pudding" model.
  • Atoms have structure—a positively charged substance, with negatively charged electrons embedded in it, like plums in a pudding.
  • Ernest Rutherford (English physicist) conducted experiments to understand the atom's structure.
  • He found that atoms contain a small, dense, positively charged nucleus.
  • Negatively charged electrons orbit around this nucleus.
  • Niels Bohr (Danish scientist) refined Rutherford's model.
  • Electrons orbit the nucleus in specific energy levels.
  • Arnold Sommerfeld refined Bohr's model to include elliptical orbits for electrons.
  • Erwin Schrödinger (physicist and biologist) considered the Father of Quantum Mechanics; today's atomic model is based on the principles of wave mechanics.
  • Electrons do not move in fixed paths like planets around the sun; instead, space in which electrons are likely to be found is termed electron cloud.
  • The arrangement of electrons in energy levels around the atom's nucleus is called electron configuration. The energy levels are further divided into sublevels (s, p, d, and f). Each sublevel contains specific number of orbitals.

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