Hazardous Materials and Waste Overview

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Questions and Answers

Which of the following is NOT considered a hazardous material category?

  • Flammable/combustible materials
  • Radioactive materials (correct)
  • Toxic materials
  • Aerosol containers

What is the Navy's policy regarding hazardous waste on ships?

  • Ships are responsible for transporting hazardous waste to shore facilities.
  • Ships should minimize hazardous waste generation but it is unavoidable.
  • Ships should strive to completely eliminate hazardous waste generation. (correct)
  • Ships are allowed to generate hazardous waste as long as it is properly disposed of.

What is an example of incompatible materials mentioned in the text?

  • Compressed gases and flammable liquids
  • Acids and bases
  • Oil-based products and Liquid Oxygen (LOX) (correct)
  • Paint and water

What is the first step to take when a hazardous material spill is discovered?

<p>Verbally report the spill to supervisory personnel and the OOD/CDO. (B)</p> Signup and view all the answers

What information is NOT required to be reported when a hazardous material spill is discovered?

<p>Name and address of the person responsible for the spill (B)</p> Signup and view all the answers

Which of the following is NOT considered personal protective equipment required when handling hazardous materials?

<p>Fire extinguishers (C)</p> Signup and view all the answers

What is the definition of hazardous waste?

<p>Any discarded material that poses a risk to human health or the environment. (D)</p> Signup and view all the answers

Why is it important to minimize the generation of hazardous waste on ships?

<p>All of the above. (D)</p> Signup and view all the answers

Flashcards

Hazardous Material (HM)

Any material that poses a hazard to health or environment due to its characteristics or usage.

Hazardous Waste (HW)

Discarded material classified as HM or designated hazardous by authorities.

Six Categories of HM

Flammable, Aerosol, Toxic, Corrosive, Oxidizing, Compressed gases.

Incompatible Material

Safe materials that become hazardous when combined under certain conditions.

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HM/HW Spill Reporting

Immediate verbal report required upon discovery of spills, detailing time, location, and material.

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Initial Spill Response Information

Key details to report include time, location, material, behavior, and personnel involved.

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Personal Protection Equipment (PPE)

Protective gear required when handling HM/HW includes eye protection and respiratory devices.

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Environmental Protection Agency (EPA)

U.S. agency that designates hazardous waste materials.

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Study Notes

Hazardous Materials (HM) and Hazardous Waste (HW)

  • Hazardous Material (HM): Any material that, due to its quantity, concentration, or properties, poses a substantial risk to human health or the environment if mishandled, released intentionally, or spilled accidentally.
  • Hazardous Waste (HW): Any discarded material (solid, liquid, or gas) that meets the HM definition or is designated as hazardous waste by the Environmental Protection Agency (EPA) or a state authority. Ship policy is that ships do not generate HW.

Categories of Hazardous Materials

  • Flammable/Combustible Materials
  • Aerosol Containers
  • Toxic Materials
  • Corrosive Materials (acids and bases)
  • Oxidizing Materials
  • Compressed Gases

Incompatible Materials

  • Certain materials, typically safe individually, can become hazardous when in contact or close proximity.
  • Example: Oil-based products and Liquid Oxygen (LOX); Chemical conversion coatings and acids or combustibles (like paint, naphtha). HM in excess of a ship's needs.

HM/HW Spill Procedures

  • Discovery: Spills or potential spills may be found through routine inspections, detection devices (fire alarms, oxygen deficiency detectors), or normal operations.
  • Immediate Reporting: Any HM/HW spill or potential spill must be immediately reported verbally to supervisors and the Officer of the Deck (OOD) /Command Duty Officer (CDO).
  • Crew Restrictions: Crewmembers should not investigate the spill.
  • Reporting Information (if possible):
    • Time of discovery
    • Location
    • Spilled material's identity
    • Material's behavior (reactions observed)
    • Spill source (container, tank)
    • Personnel near the spill (names, departments)
    • Spill volume
    • Anticipated movement (e.g., from midship to galley)
    • Labeling/placarding information (from the container only after exposure is eliminated)

Personal Protective Equipment (PPE) for HM/HW Handling

  • Eye Protection
  • Respiratory Devices
  • Gloves
  • Apron
  • Coveralls
  • Rubber Boots

Underway and Import Discharge Limitations

  • Trash/Garbage (non-plastics): Pulped/comminuted (3-25) direct discharge permitted, exceeding 25 unsuitable for direct discharge.
  • Plastic: No discharge permitted.
  • Sewage: Discharge beyond 3 nautical miles.
  • Oily Waste: Discharge beyond 12 nautical miles if equipped with an Oil Content Monitor (OCM) <15ppm oil, or 50 nautical miles if equipped with an Oil Water Separator (OWS) and no OCM.
  • Paint/Mineral Spirits: No discharge permitted.

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