Hardness of Water Quiz
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Questions and Answers

What is the primary cause of hard water?

  • Presence of sulfuric acid
  • High levels of carbon dioxide
  • Dissolved sodium ions
  • Dissolved calcium or magnesium ions (correct)
  • Which compound forms when soap is added to hard water?

  • Magnesium sulfate
  • Sodium hydrogen carbonate
  • Calcium stearate (correct)
  • Sodium sulfate
  • Which type of hardness can be removed by boiling water?

  • Permanent hardness
  • Both permanent and temporary hardness
  • Temporary hardness (correct)
  • Neither permanent nor temporary hardness
  • What is formed when calcium hydrogen carbonate is heated?

    <p>Calcium carbonate, water, and carbon dioxide</p> Signup and view all the answers

    What is the main disadvantage of distillation as a method to remove hardness from water?

    <p>It is too expensive for large scale use</p> Signup and view all the answers

    What is the role of washing soda in the context of hard water?

    <p>It reacts with calcium ions to form insoluble calcium carbonate</p> Signup and view all the answers

    What type of resin is used in the ion-exchange method to soften water?

    <p>Cation exchange resin</p> Signup and view all the answers

    What is the chemical formula for calcium sulfate, a contributor to permanent hardness?

    <p>CaSO4</p> Signup and view all the answers

    What is the purpose of rinsing the reagent bottle with deionised water?

    <p>To remove any contaminants</p> Signup and view all the answers

    Which reagent is added to the sample to react in the redox process?

    <p>Manganese(II) sulfate solution</p> Signup and view all the answers

    What is the indication that iodine has been released during the process?

    <p>The solution becomes golden brown</p> Signup and view all the answers

    What is the total suspended solids concentration in p.p.m?

    <p>1360 p.p.m</p> Signup and view all the answers

    What is the purpose of using starch indicator during titration?

    <p>To signal the end point of titration</p> Signup and view all the answers

    How should the concentrated sulfuric acid be added to the bottle?

    <p>By running it down the side of the bottle</p> Signup and view all the answers

    What does a high B.O.D indicate about the water quality?

    <p>Low oxygen levels</p> Signup and view all the answers

    What should be calculated from the titration results?

    <p>Dissolved oxygen in moles, grams, and p.p.m.</p> Signup and view all the answers

    Which method is used to measure the concentration of heavy metal ions in water?

    <p>Atomic absorption spectrometry (AAS)</p> Signup and view all the answers

    What causes eutrophication in water bodies?

    <p>Nitrates and phosphates from fertilizers and sewage</p> Signup and view all the answers

    What measurement technique is used to estimate the free iodine in the solution?

    <p>Titration with thiosulfate solution</p> Signup and view all the answers

    What is the purpose of keeping one bottle in darkness during B.O.D testing?

    <p>To stop photosynthesis from affecting the results</p> Signup and view all the answers

    What is essential to ensure during the inversion of the bottle filled with the sample?

    <p>To ensure no air is trapped inside the bottle</p> Signup and view all the answers

    What does a low concentration of total dissolved solids indicate?

    <p>Low levels of pollutants</p> Signup and view all the answers

    Which process is primarily used to remove heavy metal ions from water?

    <p>Precipitation</p> Signup and view all the answers

    Why is monitoring oxygen levels in water essential for aquatic habitats?

    <p>It ensures the survival of all aquatic plants and animals.</p> Signup and view all the answers

    What is the main aim of sewage treatment?

    <p>To prevent waste from contaminating water systems</p> Signup and view all the answers

    Which process is involved in primary treatment of sewage?

    <p>Mechanical removal of large solids</p> Signup and view all the answers

    What role do bacteria play in secondary sewage treatment?

    <p>They decompose sewage using nutrients and oxygen</p> Signup and view all the answers

    What does tertiary treatment primarily remove from sewage?

    <p>Phosphorous and nitrogen compounds</p> Signup and view all the answers

    What is the principle behind colorimetry?

    <p>The absorbance of light is proportional to the concentration of a coloured solution</p> Signup and view all the answers

    Which method is used to detect heavy metals in water?

    <p>Atomic Absorption Spectroscopy</p> Signup and view all the answers

    In the mandatory experiment, what is the purpose of adding ethanoic acid to the volumetric flasks?

    <p>To adjust the pH for reaction with free chlorine</p> Signup and view all the answers

    What is the primary outcome expected from the addition of sludge removed during sewage treatment?

    <p>To serve as nutrients for fertilizers or possible fuel</p> Signup and view all the answers

    What ions are exchanged by the cation-exchange resin when treating hard water?

    <p>Ca^2+^ ions for Na^+^ ions</p> Signup and view all the answers

    What happens to the Na^+^ ions in the cation-exchange resin after repeated use?

    <p>They are replaced and replenished with concentrated sodium chloride.</p> Signup and view all the answers

    Which ions are removed by the anion-exchange resin in a mixed-bed resin system?

    <p>Negative ions only</p> Signup and view all the answers

    How is deionised water produced according to the content provided?

    <p>By passing water through a mixed-bed resin of cation and anion exchange resins</p> Signup and view all the answers

    What characterizes distilled water compared to deionised water?

    <p>It has all suspended and dissolved solids removed.</p> Signup and view all the answers

    What is a disadvantage of hard water?

    <p>It blocks pipes and leaves scale on kettles.</p> Signup and view all the answers

    During the EDTA experiment for determining water hardness, what is necessary for rinsing the burette?

    <p>Ethylenediaminetetraacetic acid solution</p> Signup and view all the answers

    In the cation exchange reaction represented as RH + Na+ RNa + H^+^, what does RH represent?

    <p>Cation-exchange resin in its unreacted form</p> Signup and view all the answers

    What causes hard water and how does it waste soap?

    <p>Presence of calcium hydrogencarbonate and it reacts with soap to form scum.</p> Signup and view all the answers

    How does the ion exchange process soften hard water?

    <p>By replacing calcium and magnesium ions with hydrogen and hydroxyl ions.</p> Signup and view all the answers

    What is the effect of adding chlorine in excessive amounts to water?

    <p>It can make the water taste of chlorine.</p> Signup and view all the answers

    What is the purpose of adding a fluorine-containing compound in water treatment?

    <p>To prevent tooth decay.</p> Signup and view all the answers

    Why are heavy metal ions such as Hg^2+ or Pb^2+ a concern in water pollution?

    <p>They pose serious health risks to humans and animals.</p> Signup and view all the answers

    Which instrumental technique is typically used to detect heavy metal ion concentrations in water?

    <p>Atomic Absorption Spectroscopy</p> Signup and view all the answers

    What is a common test for chloride ions (Cl^--^) in water?

    <p>Adding silver nitrate and dilute nitric acid.</p> Signup and view all the answers

    What is the biochemical oxygen demand (BOD) of a water sample?

    <p>The oxygen consumed over 5 days under specific conditions.</p> Signup and view all the answers

    Study Notes

    Hardness of Water

    • Hard water is water that does not easily form a lather with soap
    • Hardness is caused by dissolved Ca2+ or Mg2+ ions in the water
    • Soap reacts with calcium or magnesium ions in the water to form an insoluble compound (e.g., calcium stearate)
    • Hardness is categorized as temporary or permanent

    Temporary Hardness

    • Temporary hardness can be removed by boiling the water
    • It is caused by dissolved calcium hydrogen carbonate (Ca(HCO3)2) and magnesium hydrogen carbonate (Mg(HCO3)2)
    • Boiling the water decomposes the carbonates into insoluble calcium carbonate (CaCO3) and magnesium carbonate (MgCO3), which precipitate out of the solution
    • This removes the hardness-causing ions

    Permanent Hardness

    • Permanent hardness cannot be removed by boiling the water
    • It is caused by dissolved calcium sulfate (CaSO4) and magnesium sulfate (MgSO4)
    • Heating the water does not affect these salts; therefore, hardness remains even after boiling
    • These salts persist in the water even after boiling

    Methods of Removing Hardness

    • Distillation: Boiled water, removing dissolved solids
    • Washing Soda: Reacts with Ca2+ ions to form insoluble calcium carbonate
    • Ion-exchange resin: Exchanges Ca2+ and Mg2+ ions for Na+ ions, which do not cause hardness. This is a cation exchange resin. This process needs to be replenished using Sodium Chloride
    • Deionised water: Uses a mixture of cation and anion exchange resins. Cation resin removes positive ions (e.g., Ca2+), and anion resin removes negative ions (e.g., sulfate). This results in pure water (deionised) containing only H+ and OH- ions, which combine to form water.

    Advantages and Disadvantages of Hard Water

    • Advantages: Good for teeth and bones, better taste, good for brewing and tanning leather
    • Disadvantages: Blocks pipes, leaves scale in kettles, wastes soap, produces scum

    Water Treatment

    • Screening: Removal of floating debris (e.g., branches, plastic bags).
    • Flocculation: Small suspended particles are coagulated, forming larger particles for better sedimentation. This is done through use of flocculating chemicals (e.g., aluminum sulfate).
    • Sedimentation: Water is passed into a tank to allow for maximum sedimentation. Larger particles settle to the bottom.
    • Filtration: Water passes through beds of sand to remove remaining particles.
    • Chlorination: Chlorine is added to sterilise water and kill harmful microorganisms.
    • Fluoridation: Fluoride added to prevent tooth decay.
    • pH adjustment: Adjustment of pH of the water to the optimum pH of 7.2. This is done by adding acids or bases as necessary.

    Water Pollution

    • Water Pollution affects the amount of oxygen in water which leads to safety of aquatic life
    • BO.D. (Biochemical Oxygen Demand): The amount of dissolved oxygen consumed by biological activities in water over five days at 20°C. High BOD indicates low oxygen levels, which means a high level of microorganisms

    Water Pollution- Eutrophication

    • Excessive enrichment of water with nutrients (e.g., nitrates and phosphates)
    • Causes excessive growth of algae and other plants, leading to oxygen depletion and harming aquatic life.

    Heavy Metals in Water

    • Heavy metals (e.g., lead, mercury) can have serious consequences for organisms and affect human health
    • Atomic Absorption Spectroscopy (AAS) is used to detect heavy metals in water

    Dissolved Oxygen

    • Dissolved oxygen in water due to plants
    • is necessary for aquatic life, thus requiring BOD tests

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    Description

    Test your knowledge on the hardness of water, including its types, causes, and methods for removal. This quiz covers both temporary and permanent hardness, focusing on the chemical processes involved. Understand the implications of hard water and how it affects everyday life.

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