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What causes hard water to form a grey insoluble compound when soap is added?
What causes hard water to form a grey insoluble compound when soap is added?
The calcium or magnesium ions in hard water react with stearate ions from soap to form calcium stearate.
How can temporary hardness be removed from water?
How can temporary hardness be removed from water?
Temporary hardness can be removed by boiling the water.
What is the primary difference between temporary and permanent hardness in water?
What is the primary difference between temporary and permanent hardness in water?
Temporary hardness can be removed by boiling, while permanent hardness cannot be eliminated through boiling.
Explain the role of carbon dioxide in creating temporary hardness in rainwater.
Explain the role of carbon dioxide in creating temporary hardness in rainwater.
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What reaction occurs when boiling temporarily hard water?
What reaction occurs when boiling temporarily hard water?
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What is one disadvantage of using distillation to remove hardness from water?
What is one disadvantage of using distillation to remove hardness from water?
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How does washing soda help in softening hard water?
How does washing soda help in softening hard water?
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What is the function of a cation exchange resin in removing hardness from water?
What is the function of a cation exchange resin in removing hardness from water?
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What is the role of Na^+^ ions in cation-exchange resin during water softening?
What is the role of Na^+^ ions in cation-exchange resin during water softening?
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How does cation-exchange resin regenerate after exhausting its Na^+^ ions?
How does cation-exchange resin regenerate after exhausting its Na^+^ ions?
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What is the difference between deionised water and distilled water?
What is the difference between deionised water and distilled water?
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In the mixed-bed resin used for deionisation, what ions does the cation-exchange resin replace?
In the mixed-bed resin used for deionisation, what ions does the cation-exchange resin replace?
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List one advantage and one disadvantage of hard water.
List one advantage and one disadvantage of hard water.
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What transactions occur when Cl^-^ ions interact with the anion-exchange resin?
What transactions occur when Cl^-^ ions interact with the anion-exchange resin?
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During the experiment to determine total hardness, what should be done with the pipette before use?
During the experiment to determine total hardness, what should be done with the pipette before use?
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What type of water does the ion-exchange resin process aim to produce?
What type of water does the ion-exchange resin process aim to produce?
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How should the burette be prepared before starting the titration?
How should the burette be prepared before starting the titration?
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What color indicates that the endpoint of the titration has been reached?
What color indicates that the endpoint of the titration has been reached?
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Calculate the concentration of total hardness in the water based on the titration result of 15.2 cm^3 of 0.01 M EDTA.
Calculate the concentration of total hardness in the water based on the titration result of 15.2 cm^3 of 0.01 M EDTA.
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What is the function of the buffer solution added during the titration of hard water?
What is the function of the buffer solution added during the titration of hard water?
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Describe the flocculation process in water treatment.
Describe the flocculation process in water treatment.
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What is the role of chlorine in the water treatment process?
What is the role of chlorine in the water treatment process?
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What are the components remaining in the water after the sedimentation process?
What are the components remaining in the water after the sedimentation process?
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Why is it important to carry out multiple accurate titrations until two titres agree to within 0.1 cm^3?
Why is it important to carry out multiple accurate titrations until two titres agree to within 0.1 cm^3?
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What is the purpose of rinsing the reagent bottle with deionised water before filling it with the sample?
What is the purpose of rinsing the reagent bottle with deionised water before filling it with the sample?
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Why is it necessary to add sulfuric acid after creating the brown precipitate?
Why is it necessary to add sulfuric acid after creating the brown precipitate?
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What is the significance of using sodium thiosulfate in the titration process?
What is the significance of using sodium thiosulfate in the titration process?
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What is meant by 'taking the average of two accurate titration results'?
What is meant by 'taking the average of two accurate titration results'?
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Why are air bubbles a concern during the initial filling of the reagent bottle?
Why are air bubbles a concern during the initial filling of the reagent bottle?
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What role does the starch indicator play during the titration with thiosulfate?
What role does the starch indicator play during the titration with thiosulfate?
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How is dissolved oxygen concentration calculated from the results obtained?
How is dissolved oxygen concentration calculated from the results obtained?
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In the context of sewage treatment, why is measuring dissolved oxygen important?
In the context of sewage treatment, why is measuring dissolved oxygen important?
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What volumes of solution are added to the third, fourth, and fifth flasks?
What volumes of solution are added to the third, fourth, and fifth flasks?
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What is the purpose of using a colorimeter in this experiment?
What is the purpose of using a colorimeter in this experiment?
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What is the first step in preparing the working standards after adding the solution to the flasks?
What is the first step in preparing the working standards after adding the solution to the flasks?
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Explain how to prepare flask F for measuring chlorine concentration.
Explain how to prepare flask F for measuring chlorine concentration.
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What is the formula to convert total suspended solids to parts per million (ppm)?
What is the formula to convert total suspended solids to parts per million (ppm)?
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How do you determine the concentration of free chlorine in the sample from flask F?
How do you determine the concentration of free chlorine in the sample from flask F?
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How do you determine the Biochemical Oxygen Demand (B.O.D) of a water sample?
How do you determine the Biochemical Oxygen Demand (B.O.D) of a water sample?
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What negative impact does eutrophication have on aquatic life?
What negative impact does eutrophication have on aquatic life?
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What is essential to do between measuring different samples in the colorimeter?
What is essential to do between measuring different samples in the colorimeter?
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What type of light should be used when comparing colors in the comparator?
What type of light should be used when comparing colors in the comparator?
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What methods can be used to detect heavy metals in water?
What methods can be used to detect heavy metals in water?
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What is the role of the DPD No.1 tablet in the chlorine test?
What is the role of the DPD No.1 tablet in the chlorine test?
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Why is it essential to monitor oxygen levels in water systems?
Why is it essential to monitor oxygen levels in water systems?
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What is the significance of conducting a B.O.D test in the dark?
What is the significance of conducting a B.O.D test in the dark?
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What is the relationship between high B.O.D levels and microbial presence in water?
What is the relationship between high B.O.D levels and microbial presence in water?
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How does precipitation help in the removal of heavy metal ions from water?
How does precipitation help in the removal of heavy metal ions from water?
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Study Notes
Hardness of Water
- Hard water is water that does not easily create a lather with soap.
- Hardness is caused by dissolved calcium (Ca²⁺) or magnesium (Mg²⁺) ions in the water.
- Temporary hardness can be removed by boiling the water.
- Temporary hardness is caused by calcium hydrogencarbonate (Ca(HCO₃)₂) and magnesium hydrogencarbonate (Mg(HCO₃)₂).
- Boiling these compounds decomposes them into calcium carbonate (CaCO₃), carbon dioxide (CO₂), and water (H₂O), removing the hardness.
- Permanent hardness cannot be removed by boiling.
- Permanent hardness is caused by calcium sulfate (CaSO₄) or magnesium sulfate (MgSO₄) in the water.
- Heating water containing these substances does not cause a chemical reaction to precipitate the Ca²⁺ or Mg²⁺ ions, so the hardness remains.
Methods of Removing Hardness
- Distillation: Water is boiled, and the dissolved solids causing hardness are left behind in the residue. This is not usually practical for large scale use.
- Using Washing Soda: This reacts with Ca²⁺ ions in the water to form calcium carbonate (insoluble in water)
- Ion-exchange resin: Exchanges Ca²⁺ and Mg²⁺ ions for Na⁺ ions.
- Cation-exchange resin: Replaces positive ions in the water with Na⁺ ions.
- Deionised water: Produced by passing ordinary water through a water deioniser containing a mixture of cation and anion exchange resins to remove all positive and negative ions. This produces water with only H⁺ and OH⁻ ions.
Advantages and Disadvantages of Hard Water
-
Advantages:
- Provides calcium for teeth and bones.
- Better taste and flavor.
- Good for brewing and tanning leather.
-
Disadvantages:
- Blocks pipes (scales on kettles), impacting plumbing.
- Wastes soap, producing more suds.
- Produces scum.
Mandatory Experiment: Total Hardness
- Instructions are given for a lab experiment to determine total hardness in a water sample using EDTA.
Water Treatment
- Screening: Removing floating debris like branches and plastic bags.
- Flocculation: Coagulating small suspended particles into larger ones for easier settling.
- Sedimentation: Passing water through tanks to allow suspended particles to settle to the bottom.
- Filtration: Passing water through beds of sand to remove remaining particles.
- Chlorination: Adding chlorine to sterilize water and kill harmful microorganisms.
- Fluoridation: Adding fluoride to prevent tooth decay as required by law.
- pH Adjustment: Maintaining optimal pH (7.2) by adding acids or bases.
Water Pollution
- Biochemical Oxygen Demand (BOD): Amount of dissolved oxygen consumed by biological action in water over 5 days at 20°C in the dark.
- Eutrophication: Enrichment of water with nutrients causing excessive growth of algae and other plants, often resulting from fertilizers and sewage, which leads to depletion in oxygen levels.
Pollution Caused by Heavy Metals
- Lead (Pb²⁺) ions are heavy metal ions which can be removed via precipitation and have harmful consequences for organisms.
- Atomic absorption spectrometry (AAS) can be used to detect these metals in water.
Mandatory Experiment: Dissolved Oxygen
- Procedure for measuring dissolved oxygen in a water sample using a redox reaction.
Sewage Treatment
- Sewage treatment involves removing materials from sewage to maintain a healthy water system.
- Primary treatment: Removing large solids (screening) and suspended solids (settling).
- Secondary treatment: Biological oxidation process to reduce suspended and dissolved organic materials using bacteria.
- Tertiary treatment: Removal of phosphorous (precipitating) and nitrogen (ion-exchange). This prevents eutrophication.
Instrumental Methods of Water Analysis
- pH Analysis: Using a pH sensor.
- Atomic Absorption Spectroscopy (AAS): Detects the concentration of heavy metals in water by measuring the amount of light absorbed by the metal.
Mandatory Experiment: Free Chlorine
- Procedures for determining free chlorine concentration in swimming pool water using a comparator or a colorimeter.
Exam Questions - 2012
- Questions with explanations to calculate total hardness in a water sample or determine total suspended and dissolved solids, calculate pH, or determine free chlorine in a water sample
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Description
This quiz covers the concepts of water hardness, including the types of hardness, their causes, and methods of removal. Learn about temporary and permanent hardness and understand how boiling and distillation can address these issues. Test your knowledge on the chemistry behind hard water.