Green Chemistry Metrics Overview

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to Lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

What is the purpose of atom economy in chemical processes?

  • To ensure most reactant atoms are incorporated into the final product. (correct)
  • To maximize the energy produced in reactions.
  • To increase the production of unwanted byproducts.
  • To simplify the number of stages in any chemical synthesis.

Which synthesis method exemplifies poor atom economy?

  • A multi-stage process generating numerous byproducts. (correct)
  • Single stage process with one product.
  • One-step synthesis with zero waste.
  • Using stoichiometric amounts of all reactants.

What is an advantage of the greener synthesis developed by BHC Company for ibuprofen?

  • It incorporates a majority of reactant atoms into the final product. (correct)
  • It generates large quantities of unwanted byproducts.
  • It requires fewer reagents than traditional methods.
  • It utilizes stoichiometric amounts of reactants.

Which of the following describes a single-stage process?

<p>A + B → C. (C)</p> Signup and view all the answers

In the context of ibuprofen synthesis, what does 'unwanted byproducts' refer to?

<p>Atoms that do not participate in the reaction. (A)</p> Signup and view all the answers

What does a multi-stage process typically indicate regarding atom economy?

<p>Potential for inefficient use of reactant atoms. (B)</p> Signup and view all the answers

What is the common characteristic of reactions with high atom economy?

<p>Most atoms from reactants are included in the final product. (C)</p> Signup and view all the answers

What was a major challenge addressed in the development of the new synthesis for ibuprofen?

<p>Decreasing the environmental impact of the synthesis. (B)</p> Signup and view all the answers

What is the formula for calculating percent yield?

<p>Percent yield = (actual yield/theoretical yield) x 100 (C)</p> Signup and view all the answers

Which metric specifically assesses the total waste generated relative to the product mass?

<p>E-factor (A)</p> Signup and view all the answers

What does atom economy measure?

<p>Mass of desired product divided by total mass of products (D)</p> Signup and view all the answers

What is the purpose of Process Mass Intensity (PMI)?

<p>To evaluate the mass of materials used to isolate the product (C)</p> Signup and view all the answers

How is atom utilization related to atom economy?

<p>It represents a variation focused on the molecular weight of products (C)</p> Signup and view all the answers

Which metric assesses the environmental impacts throughout all stages of a product's life?

<p>Life Cycle Assessment (LCA) (A)</p> Signup and view all the answers

What aspect does reaction mass efficiency (RME) mainly focus on?

<p>Relation between the mass of product and reactants used (D)</p> Signup and view all the answers

Which of the following is NOT typically considered when assessing conventional metrics in chemistry?

<p>Ecological footprint (D)</p> Signup and view all the answers

What does a smaller E-factor indicate about a chemical process?

<p>Closer to zero waste (A)</p> Signup and view all the answers

Which reaction class is considered atom economic?

<p>Diels-Alder reactions (A)</p> Signup and view all the answers

Which of the following methods has a poor atom economy due to byproduct production?

<p>Wittig reactions (C)</p> Signup and view all the answers

The atom economy (AE) calculation is essential for evaluating what aspect of synthetic methodologies?

<p>Resource efficiency (C)</p> Signup and view all the answers

How is the E-factor calculated?

<p>Total waste (g) / amount of product (g) (A)</p> Signup and view all the answers

Which type of reaction can potentially be carried out in water or ionic liquids?

<p>Diels-Alder reactions (A)</p> Signup and view all the answers

What is a key characteristic of inherent atom economy in reactions?

<p>Formation of desired products (A)</p> Signup and view all the answers

What does the term 'green chemistry' primarily emphasize?

<p>Reduction of hazardous substances (B)</p> Signup and view all the answers

Flashcards

Atom Economy

The percentage of the total mass of reactants that is converted into the desired product. It measures the efficiency of a chemical reaction in terms of how much of the starting materials ends up as the desired product.

E-factor

The mass of all waste generated during a chemical process divided by the mass of the desired product. A lower E-factor indicates a more environmentally friendly process.

Atom Utilization

Similar to atom economy, it measures the percentage of the total mass of products that is the desired product. It considers all the products formed, not just the reactants.

Reaction Mass Efficiency (RME)

The ratio of the mass of the desired product to the total mass of all reactants used in a chemical reaction. It emphasizes the efficiency of converting reactants into the desired product.

Signup and view all the flashcards

Process Mass Intensity (PMI)

The total mass of materials used in a process divided by the mass of the product. A lower PMI indicates a more efficient process.

Signup and view all the flashcards

Life Cycle Assessment (LCA)

A tool for assessing the environmental impacts of a product throughout its entire life cycle, from raw material extraction to manufacturing, use, and disposal.

Signup and view all the flashcards

Ecological Indicator/Footprint

A set of metrics that measure the environmental impact of a process or product.

Signup and view all the flashcards

Single-Stage Process

A chemical reaction where all reactants are converted into desired product, maximizing the use of atoms.

Signup and view all the flashcards

Multi-Stage Process

A series of chemical reactions where reactants are converted into products through multiple steps.

Signup and view all the flashcards

Good Atom Economy

A higher atom economy indicates more efficient use of atoms, reducing waste and byproducts.

Signup and view all the flashcards

Poor Atom Economy

A lower atom economy indicates less efficient use of atoms, leading to more waste and byproducts.

Signup and view all the flashcards

Greener Synthesis

A chemical reaction designed to minimize waste and maximize the use of atoms in the desired product.

Signup and view all the flashcards

Chemical Byproducts

Unwanted substances produced during a chemical reaction.

Signup and view all the flashcards

Convergent Synthesis

A method of synthesizing a molecule using a series of reactions that converge on a common intermediate. This approach can help reduce waste by minimizing the number of steps and byproducts.

Signup and view all the flashcards

Rearrangement Reaction

A reaction in which the atoms of the reactants are rearranged to form a new product. There is minimal loss of atoms in the process, resulting in high atom economy.

Signup and view all the flashcards

Addition Reaction

A reaction where a new chemical bond is formed between two molecules by adding atoms or groups to the reacting molecules. These reactions often exhibit high atom economy, especially when considering the products formed.

Signup and view all the flashcards

Elimination Reaction

A reaction in which a chemical bond is broken, leading to the removal of a molecule or group. Elimination reactions typically have lower atom economy due to the production of byproducts.

Signup and view all the flashcards

Substitution Reaction

A group of reactions that involve the transfer of an atom other than hydrogen (e.g., halogens, oxygen) to an unsaturated hydrocarbon molecule. These reactions often produce unwanted byproducts and generally have lower atom economy.

Signup and view all the flashcards

Nucleophilic Reaction

A type of chemical reaction where an electron-rich molecule (nucleophile) attacks an electron-deficient molecule (electrophile), resulting in the formation of a new chemical bond. These reactions can have varying levels of atom economy depending on the specifics of the reaction.

Signup and view all the flashcards

Study Notes

Green Chemistry Metrics

  • E-factor: total waste (grams)/product (grams). This metric measures the amount of waste generated per unit of product. Higher values indicate greater waste.
  • Atom utilization: (MW of desired product/MW of all products) x 100. This metric assesses how effectively atoms from reactants are incorporated into the desired product. High values indicate better atom economy.
  • Reaction mass efficiency (RME): (mass of product C/(mass of A + mass of B)) x 100. This metric measures the efficiency of a reaction in producing the desired product from the input materials. Higher values indicate better efficiency.
  • Process mass intensity (PMI): total mass of materials/mass of isolated product. This metric measures the total amount of materials used to create a product.
  • Life Cycle Assessment (LCA): assessment of environmental impacts throughout a product's lifespan.

Conventional Metrics

  • Percent yield: (actual yield/theoretical yield) x 100. This metric measures the efficiency of chemical reactions in producing a desired product.

Established Metrics in Green Chemistry

  • Atom economy
  • Atom utilization

Additional Metrics Used in Green Chemistry

  • Process mass intensity
  • Life cycle assessment
  • Ecological indicator/ecological footprint

Atom Economy Example: Ibuprofen Synthesis

  • In ibuprofen synthesis, most reactant atoms are incorporated into the desired product.
  • This leads to low levels of unwanted byproducts
  • There are also environmental benefits

Topics Covered

  • Ecological indicator/ecological footprint

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Related Documents

More Like This

Use Quizgecko on...
Browser
Browser