Grade 11/12 General Chemistry 1 Final Review

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Questions and Answers

Forces exist whether a substance is polar or nonpolar.

London

Because carbon monoxide is a polar molecule, forces exist between their molecules.

dipole-dipole

Which of the following options include only intermolecular forces?

  • Intramolecular and Hydrogen Bond
  • London Force and Intramolecular
  • Ion-Dipole and Intramolecular
  • London Force and Dipole-Dipole (correct)

What type of intermolecular force will $NaF (aq)$ exhibit?

<p>ion-dipole</p> Signup and view all the answers

Because carbon dioxide is a nonpolar molecule, _____ forces exist between their molecules.

<p>London</p> Signup and view all the answers

Forces are attractive forces that exist within a molecule of a compound.

<p>Intramolecular</p> Signup and view all the answers

The phase change of solid naphthalene turning into gas is called ______.

<p>sublimation</p> Signup and view all the answers

A ______ is defined as a point of temperature and pressure where all common states of matter intersect or coexist.

<p>triple point</p> Signup and view all the answers

_______ is the minimum energy required for a reaction to occur.

<p>Activation energy</p> Signup and view all the answers

The overall reaction order of $r = k[A][B][C]$ is _______.

<p>third</p> Signup and view all the answers

Atmospheric pressure is a colligative property.

<p>False (B)</p> Signup and view all the answers

Collision Theory states that reactions occur if particles collide with proper energy and orientation.

<p>True (A)</p> Signup and view all the answers

A catalyst increases the activation energy of a reaction.

<p>False (B)</p> Signup and view all the answers

Above the critical temperature, you can still apply pressure to condense a gas back into liquid.

<p>False (B)</p> Signup and view all the answers

In a saturated solution, you cannot dissolve anymore solid solute.

<p>True (A)</p> Signup and view all the answers

At equilibrium, the rates of forward and reverse reactions are always equal.

<p>True (A)</p> Signup and view all the answers

Endothermic phase changes that absorb energy include melting, evaporation, and sublimation.

<p>True (A)</p> Signup and view all the answers

If temperature increases, the average kinetic energy, on the other hand, decreases.

<p>False (B)</p> Signup and view all the answers

Pressure does not affect the equilibrium of reactions involving solid reactants and products.

<p>True (A)</p> Signup and view all the answers

Ions and water molecules attract together in a force called ion-dipole interaction.

<p>True (A)</p> Signup and view all the answers

On the provided phase diagram, at which point do all three states of the substance coexist?

<p>A (B)</p> Signup and view all the answers

On the provided phase diagram, what are the phases of the substance at point C?

<p>Liquid and Gas (C)</p> Signup and view all the answers

On the provided phase diagram, what is the phase of the substance at 1 atm and 80°C?

<p>Liquid (B)</p> Signup and view all the answers

Analyze the statements according to the criteria below: X: As a liquid becomes a gas, its particles move slower. Y: The particles move slower during evaporation because the phase change is exothermic.

<p>Both statements are false. (C)</p> Signup and view all the answers

When you grind solid materials into powder, you are increasing the ________ to speed up the reaction.

<p>Surface area (A)</p> Signup and view all the answers

The reaction A ⇌ B is in equilibrium if ________.

<p>the rate of conversion of A to B is equal to that of B to A. (A)</p> Signup and view all the answers

Which phase transitions can increase the molecular order?

<p>All of the above (D)</p> Signup and view all the answers

During melting or evaporation, the particles behave in which of the following ways?

<p>Becomes more organized (A)</p> Signup and view all the answers

Calculate the percent by mass of a potassium (KI) iodide solution containing 38 grams of KI and 100 grams of water.

<p>27.54%</p> Signup and view all the answers

Determine the freezing point of a 3.6-m magnesium fluoride ($MgF_2$) solution. (Kf = 1.86°C/m) Round to the nearest tenth.

<p>-20.1°C</p> Signup and view all the answers

Which of the following would be observed if an endothermic reaction is increased in temperature?

<p>Increased product formation (D)</p> Signup and view all the answers

Which of the processes can be increased by putting an enzyme into the reaction.

<p>Product formation (D)</p> Signup and view all the answers

Which of the following solutions would have the highest boiling point?

<p>1.0 m $Na_3PO_4$ (C)</p> Signup and view all the answers

Which of the following statement relates to the theory that explains the effect of changing concentration of a substance in equilibrium?

<p>Le Chatelier's Principle (C)</p> Signup and view all the answers

Match the following terms with their descriptions:

<p>Intermolecular Forces = Attractive forces between molecules. Phase Change = Process involving transition between solid, liquid, or gas. Chemical Kinetics = Study of reaction rates and mechanisms. Chemical Equilibrium = Condition where forward and reverse reaction rates are equal.</p> Signup and view all the answers

When a reaction has reached equilibrium, which of the following will be true?

<p>The rates of the forward and reverse reactions are equal. (B)</p> Signup and view all the answers

What is the effect of adding an inert gas to a reaction at equilibrium?

<p>No effect on the equilibrium (A)</p> Signup and view all the answers

Increasing the pressure in a reaction will favor product formation.

<p>False (B)</p> Signup and view all the answers

Which of the following is the term for the amount of substance that can disolve in an given amount of solvent?

<p>Solubility (B)</p> Signup and view all the answers

Flashcards

London Force

A weak attractive force that exists between all molecules, whether polar or nonpolar.

Ion-dipole force

An intermolecular attraction between a polar molecule and an ion.

Dipole-dipole forces

Attractive forces between polar molecules where the positive end of one molecule is attracted to the negative end of another.

Sublimation

Occurs when a substance changes directly from the solid to the gaseous phase without passing through the intermediate liquid phase.

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Triple Point

The specific temperature and pressure at which the solid, liquid, and gaseous phases of a substance coexist in equilibrium.

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Activation Energy

The minimum energy that must be overcome for a chemical reaction to occur.

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Reaction Order

For the rate law r = k[A][B][C], the overall reaction order is the sum of the exponents on the concentration terms.

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Collision Theory

Reactions occur when particles collide with sufficient energy (activation energy) and proper orientation.

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Catalyst's effect

A catalyst increases the rate of a reaction by lowering the activation energy.

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Chemical Equilibrium

At equilibrium, the rate of the forward reaction equals the rate of the reverse reaction.

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Endothermic phase changes

Endothermic phase changes (melting, evaporation, sublimation) absorb energy.

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Ion-dipole Interaction

Ions and water molecules attract each other through ion-dipole interactions.

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Liquid to gas

As a liquid becomes a gas, its particles speed up not slow down.

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Grinding solids

When grinding solid materials into powder, surface area is increased.

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Equilibrium Condition

The conditions in which the rate of conversion of A to B is equal to that of B to A.

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Solid to liquid transition

The solid to liquid phase transition increases the molecular order.

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During melting or evaporation

During melting or evaporation, particles become more disorganized.

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Study Notes

General Chemistry Final Review

  • The review covers STEM Grade 11/12 General Chemistry 1, S.Y. 2024-2025

Key Concepts to Review

  • Attractive Forces: Focus on intermolecular forces, phase changes, and phase diagrams.
  • Solutions: Includes types of solutions (unsaturated, saturated, supersaturated), percent by mass calculation, boiling point elevation, and freezing point depression.
  • Chemical Kinetics: Includes factors affecting reaction rates and collision theory, and the orders of reactions.
  • Chemical Equilibrium: Includes the definition of chemical equilibrium and Le Chatelier's Principle.

Exam Reminders

  • You should bring ballpens and scientific calculators only
  • Periodic tables and scratch papers are NOT allowed
  • Cellphones are strictly prohibited during the exam.
  • You should strictly follow time allotted for the exam.
  • Erasures on the exam paper are prohibited.

Attractive Forces Identification

  • London Force: Exists regardless of a substance's polarity (polar or nonpolar).
  • Dipole-Dipole Forces: Exist between polar molecules, for example, carbon monoxide.
  • Intermolecular Forces: London force, Dipole-dipole, Ion-dipole and Hydrogen bond.
  • Ion-Dipole Force: The intermolecular force that NaF (aq) exhibits.
  • Intramolecular Force: It is the the attractive force within a molecule of a compound.

Phase Changes

  • Sublimation: The phase transition of solid naphthalene turning into gas.
  • Triple Point: This is where all common states of matter coexist.
  • Activation Energy: Energy is required for a reaction to occur.
  • Third Order: This is the overall reaction order of r = k[A][B][C].

True or False Questions

  • FALSE Atmospheric pressure is colligative property.
  • TRUE Collision Theory indicates reactions require particles colliding with proper energy and orientation.
  • FALSE A catalyst increases the activation energy of a reaction.
  • FALSE Above the critical temperature, pressure cannot condense gas into a liquid.
  • TRUE Saturated solutions cannot dissolve more solid solute.
  • TRUE Equilibrium is achieved when forward and reverse reaction rates are equal.
  • TRUE Melting, evaporation, and sublimation are endothermic phase changes.
  • FALSE Increasing temperature decreases average kinetic energy.
  • TRUE Pressure does not affect the the equilibrium of reactions involving solid reactants and products.
  • TRUE Ion-dipole interaction is the attraction between ions and water molecules.

Analyzing Phase Diagrams

  • On a phase diagram, all states coexist at the Triple Point.
  • Point C on the phase diagram represents the Liquid and Gas phases.
  • At 1 atm and 80°C, the substance is in the Liquid phase.

Multiple choice questions

  • Both statements are false:
  • X: As a liquid becomes a gas, particles move slower
  • Y: The particles move slower during evaporation because the phase change is exothermic
  • To speed up reaction rates when grinding solid materials increases the surface area
  • The reaction A ⇌ B equilibrium is reached when conversion rate of A to B equals that of B to A
  • Molecular order decreases during solid to liquid transitions
  • During melting/evaporation, the molecules become more organized.

Problem Solving

  • Percent by mass (% m/m) of a solution is calculated using the formula: (Mass of solute / (Mass of solute + Mass of solvent)) × 100
  • The percent by mass of a potassium iodide solution containing 38g KI in 100g water is 82.46%
  • Freezing point depression is calculated using ΔTf = iKf m and Tf solution = FP of water - ΔTf
  • The freezing point of a 3.6 m magnesium fluoride solution is -20.09°C.

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