General Chemistry I, Lecture 1: Atomic Models
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Questions and Answers

What limitation does Rutherford's model have regarding atomic stability?

  • It fails to explain the stability of atoms based on classical physics. (correct)
  • It explains the energy levels of electrons adequately.
  • It incorrectly states that electrons orbit the nucleus in fixed paths.
  • It does not account for the radiation emitted by electrons.
  • According to Bohr’s model, what happens when an electron transitions from a high energy state to a lower energy state?

  • The electron moves closer to the nucleus without energy change.
  • The atom absorbs a quantum of energy.
  • The atom emits a quantum of radiation. (correct)
  • The atom does not emit any radiation.
  • What condition must be met for the electron's orbit to be mechanically stable according to Bohr's model?

  • The angular momentum must be an integral multiple of h/2π. (correct)
  • Electrons must radiate energy continuously.
  • The electron must be stationary in its orbit.
  • The centrifugal force must be greater than the Coulombic force.
  • Which aspect of Bohr’s model is considered entirely incorrect?

    <p>Electrons move in circular orbits around the nucleus.</p> Signup and view all the answers

    How did Bohr attempt to resolve the paradox presented by Rutherford's model?

    <p>By using quantum theory to analyze atomic structure.</p> Signup and view all the answers

    What significant observation was made during Rutherford's gold foil experiment?

    <p>Most alpha particles passed straight through the gold foil.</p> Signup and view all the answers

    Which of the following conclusions was drawn from Rutherford's model of the atom?

    <p>The nucleus holds most of the atom's mass.</p> Signup and view all the answers

    According to Thomson’s model of the atom, how are protons and electrons arranged?

    <p>Electrons and protons are randomly distributed throughout the atom.</p> Signup and view all the answers

    What was a key idea in both Thomson’s and Rutherford's models regarding the structure of the atom?

    <p>Atoms consist of subatomic particles.</p> Signup and view all the answers

    How did Rutherford test the validity of Thomson's model?

    <p>By conducting the gold foil experiment.</p> Signup and view all the answers

    Study Notes

    General Chemistry I, Lecture No. 1: Models of Atom

    •  The lecture covers atomic models, beginning with Thomson's model.
    •  By 1911, atomic components (protons and electrons) were discovered.
    •  Thomson's model proposed electrons and protons uniformly mixed within the atom.
    •  Rutherford's model challenged Thomson's via the gold foil experiment.
    •  Rutherford bombarded a gold foil with alpha particles (Helium nuclei).  - Most alpha particles passed straight through, some were deflected slightly, and a few were deflected greatly or bounced back.  - This suggested most of the atom was empty space with a dense, positively charged nucleus. 
    •  The nucleus contains the positive charge and most of the atom's mass.
    •  The nucleus is significantly smaller than the atom (approximately 100,000 times smaller).
    •  Rutherford's model, however, couldn't explain atomic stability or atomic spectra using classical physics.
    •  Bohr's model addressed this instability by proposing quantized stationary states of electron motion within the atom.
    •  Electrons exist in specific energy levels and don't radiate energy while in these levels or when unchanging.
    •  Transition between energy levels involves emitting or absorbing a quantum of energy.
    •  Electron motion in quantized states involves circular orbits around the nucleus.
    •  Bohr's first two postulates are correct and fundamental to modern quantum theory.
    •  His fourth postulate (about angular momentum) is partially correct.
    •  Third postulate is incorrect and not used in current quantum theory.
    •  Bohr derived the energy expression of electron states in an atom, balancing Coulombic and centrifugal forces.

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    Description

    This lecture explores early atomic models, starting with Thomson's model and leading to Rutherford's groundbreaking gold foil experiment. It analyzes how the discovery of atomic components changed our understanding of atomic structure and introduces Bohr's model as a solution to stability issues. Join us as we delve into the evolution of atomic theory.

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