General Chemistry I Exam Preparation
29 Questions
0 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Which halogen is present in 2-chloropropane?

  • Chlorine (correct)
  • Bromine
  • Fluorine
  • Iodine
  • What is the primary functional group in 3-hydroxyheptane?

  • Alkyne
  • Alcohol (correct)
  • Ester
  • Alkene
  • Which of the following accurately describes 1-bromobutane?

  • It has a double bond.
  • It is an alkyl halide. (correct)
  • It is a six-carbon compound.
  • It contains an alcohol group.
  • What type of compound is 2-fluoro-1-pentyne?

    <p>Alkyne</p> Signup and view all the answers

    Does ozonolysis of propyne yield acetic acid after reducing work-up?

    <p>False</p> Signup and view all the answers

    What percentage of the distilled solution is organic liquid?

    <p>73%</p> Signup and view all the answers

    What is the vapor pressure of water at $90^ heta C$?

    <p>526 mmHg</p> Signup and view all the answers

    If the vapor pressure of water is $526 mmHg$, which of the following cannot be the molecular weight of the organic liquid?

    <p>Vapor pressure greater than 526 mmHg</p> Signup and view all the answers

    What is the definition of a saturated solution?

    <p>A solution that has dissolved the maximum amount of solute possible at a given temperature.</p> Signup and view all the answers

    Which of the following statements is correct regarding the distilled solution?

    <p>It consists of 73% organic liquid.</p> Signup and view all the answers

    Which factor is crucial in determining the molecular weight of the organic liquid in the distilled solution?

    <p>Vapor pressure</p> Signup and view all the answers

    What does osmotic pressure refer to?

    <p>The pressure required to prevent the flow of solvent into a solution through a semipermeable membrane.</p> Signup and view all the answers

    Which of the following describes an ideal solution?

    <p>A solution that behaves according to Raoult's Law at all concentrations.</p> Signup and view all the answers

    What is the boiling point of an immiscible organic liquid and water in the given scenario?

    <p>$90^ ext{°C}$</p> Signup and view all the answers

    What does the equation $Wt = MxVx \frac{MxVx}{100}$ represent?

    <p>The relationship between molarity, volume, and weight of a solute.</p> Signup and view all the answers

    What type of isomerism is exhibited by 2-methyl-1-propanol and 2-methyl-2-propanol?

    <p>Position isomerism</p> Signup and view all the answers

    Which statement is true regarding 2-methyl-1-propanol and 2-methyl-2-propanol?

    <p>They can be interconverted through isomerization.</p> Signup and view all the answers

    Which of the following best describes the structural difference between 2-methyl-1-propanol and 2-methyl-2-propanol?

    <p>Different positions of the hydroxyl group</p> Signup and view all the answers

    Which property is likely to be different between 2-methyl-1-propanol and 2-methyl-2-propanol due to their isomeric forms?

    <p>Boiling point</p> Signup and view all the answers

    In organic chemistry, isomerization reactions typically involve changes in which of the following?

    <p>The arrangement of atoms</p> Signup and view all the answers

    What is the main factor contributing to the decrease in size from $Li₁₃$ to $Be₄$?

    <p>Increase in nuclear charge without significant electron shielding</p> Signup and view all the answers

    What can be inferred about the trend in atomic size as you move from $Li₁₃$ to $Be₄$?

    <p>Atomic size decreases due to increased nuclear charge.</p> Signup and view all the answers

    Which reason explains why $K₁₉$ to $Ca₂₀$ shows a smaller size decrease compared to $Li₁₃$ to $Be₄$?

    <p>There are added electron shells, increasing shielding.</p> Signup and view all the answers

    Which characteristic distinguishes $Li$ and $Be$ from $Na$ and $Mg$ in terms of size?

    <p>The less effective nuclear charge in $Na$.</p> Signup and view all the answers

    What is the value of the principal quantum number in the configuration described as $n=5, l=3, m=0, s=1/2$?

    <p>5</p> Signup and view all the answers

    Which configuration correctly describes a state with $n=3, l=2, m=2, s=1/2$?

    <p>$3d$</p> Signup and view all the answers

    How many unpaired electrons are present in the configuration $n=2, l=2, m=0, s=-1/2$?

    <p>0</p> Signup and view all the answers

    What term is used to describe the energy required to remove an electron from an atom or ion?

    <p>Ionization energy</p> Signup and view all the answers

    Which of the following describes the term 'atomic size'?

    <p>The average distance of the nucleus from the outermost electron</p> Signup and view all the answers

    Study Notes

    Chemistry Exam Study Notes

    • Final Exam: General Chemistry I, Molecular Biology students (1st year)
    • Date: 21 Dec 2022

    Definitions

    • Excluded volume: A concept in real gas equations, acknowledging that gas molecules occupy space.
    • Effusion of gases: The process where gas molecules pass through a small opening.
    • Mean free path: The average distance a gas molecule travels between collisions.

    Real Gas Equation

    • The real gas equation is (P + a/V²) (V − b) = RT
      • Where:
        • P = pressure
        • V = volume
        • a and b are constants specific to the gas
        • R = ideal gas constant
        • T = temperature

    Calculations

    • Calculate the weight of NaOH needed to prepare 500ml of 2M NaOH solution:
      • Atomic weights: Na = 23, H = 1, O = 16
      • Formula weight of NaOH ≈ 40 g/mol
      • Calculate using the formula: Wt = MxVX=

    Solutions

    • Saturated Solution: A solution in which no more solute can be dissolved at a given temperature and pressure.
    • Osmotic Pressure: The pressure required to prevent the flow of solvent across a semipermeable membrane.
    • Ideal Solution: A solution that obeys Raoult's law.

    Organic Liquid and Water Mixture

    • An immiscible organic liquid and water mixture boils at 90°C and 734 mmHg pressure.
    • The solution is 73% organic liquid. Calculate the MW of the organic liquid given that the vapor pressure of water at 90°C is 526 mmHg.

    Organic Chemistry Structures

    • 2-chloropropane: Chemical structure needs to be drawn
    • 1-bromobutane: Chemical structure needs to be drawn
    • 3-hydroxyheptane: Chemical structure needs to be drawn
    • 2-fluoro-1-pentyne: Chemical structure needs to be drawn

    True/False Statements (Organic Chemistry)

    • Ozonolysis of propyne: Followed by reduction gives acetic acid (True/False)
    • Hybridization of propyne: SP, linear shape (True/False)
    • Trans-2-butene stability: More stable than cis-2-butene (True/False)
    • Alkene polarity: More than alkanes (True/False)
    • n-butane/iso-butane isomerism: Chain isomerism (True/False)
    • Pentane/2-methylbutane Boiling point: Pentane has a higher boiling point (True/False)
    • Ozonolysis of 2-butene: Gives acetaldehyde (True/False)
    • 2-methyl-1-propanol/2-methyl-2-propanol isomerization: Position isomerism (True/False)

    Additional Topics (Part III)

    • Bond angles in CH₄ and NH₃: Check correct answer options.
    • Linear molecules: Identify which are linear
    • Carbon atom hybridization in CO₂: Determine hybridization type
    • Element classifications (Noble Gases, Representative, Transition Metals): Classify provided elements.
    • Quantum numbers: Determine permissible and impermissible sets of quantum numbers.
    • Ionization energy & Atomic size: Define and explain
    • Electronic configuration of Ti²⁺: Answer correct configuration for Titanium ion.
    • Orbital occupancies: Identify the correct orbital occupied by an electron given the quantum numbers.
    • Atomic size variations in periodic table: Explain how atomic size changes across periods and down groups, and why.
    • Size change between elements (e.g., Li₂ & Be₄): Explain why the decrease in size is greater in one case than the other.

    Studying That Suits You

    Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

    Quiz Team

    Related Documents

    Description

    Prepare for your General Chemistry I final exam with this comprehensive quiz. Covering key concepts such as excluded volume, effusion of gases, and the real gas equation, this quiz is perfect for first-year Molecular Biology students. Brush up on your calculations and definitions to excel in your exam.

    More Like This

    Real Gas Behavior vs Ideal Gas Laws
    5 questions

    Real Gas Behavior vs Ideal Gas Laws

    ManeuverableWilliamsite9726 avatar
    ManeuverableWilliamsite9726
    Real Gases and Van der Waals Isotherms Quiz
    5 questions
    Use Quizgecko on...
    Browser
    Browser