General Chemistry I Exam Preparation
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Questions and Answers

Which halogen is present in 2-chloropropane?

  • Chlorine (correct)
  • Bromine
  • Fluorine
  • Iodine

What is the primary functional group in 3-hydroxyheptane?

  • Alkyne
  • Alcohol (correct)
  • Ester
  • Alkene

Which of the following accurately describes 1-bromobutane?

  • It has a double bond.
  • It is an alkyl halide. (correct)
  • It is a six-carbon compound.
  • It contains an alcohol group.

What type of compound is 2-fluoro-1-pentyne?

<p>Alkyne (A)</p> Signup and view all the answers

Does ozonolysis of propyne yield acetic acid after reducing work-up?

<p>False (A)</p> Signup and view all the answers

What percentage of the distilled solution is organic liquid?

<p>73% (A)</p> Signup and view all the answers

What is the vapor pressure of water at $90^ heta C$?

<p>526 mmHg (C)</p> Signup and view all the answers

If the vapor pressure of water is $526 mmHg$, which of the following cannot be the molecular weight of the organic liquid?

<p>Vapor pressure greater than 526 mmHg (D)</p> Signup and view all the answers

What is the definition of a saturated solution?

<p>A solution that has dissolved the maximum amount of solute possible at a given temperature. (D)</p> Signup and view all the answers

Which of the following statements is correct regarding the distilled solution?

<p>It consists of 73% organic liquid. (D)</p> Signup and view all the answers

Which factor is crucial in determining the molecular weight of the organic liquid in the distilled solution?

<p>Vapor pressure (A)</p> Signup and view all the answers

What does osmotic pressure refer to?

<p>The pressure required to prevent the flow of solvent into a solution through a semipermeable membrane. (B)</p> Signup and view all the answers

Which of the following describes an ideal solution?

<p>A solution that behaves according to Raoult's Law at all concentrations. (C)</p> Signup and view all the answers

What is the boiling point of an immiscible organic liquid and water in the given scenario?

<p>$90^ ext{°C}$ (B)</p> Signup and view all the answers

What does the equation $Wt = MxVx \frac{MxVx}{100}$ represent?

<p>The relationship between molarity, volume, and weight of a solute. (C)</p> Signup and view all the answers

What type of isomerism is exhibited by 2-methyl-1-propanol and 2-methyl-2-propanol?

<p>Position isomerism (D)</p> Signup and view all the answers

Which statement is true regarding 2-methyl-1-propanol and 2-methyl-2-propanol?

<p>They can be interconverted through isomerization. (A)</p> Signup and view all the answers

Which of the following best describes the structural difference between 2-methyl-1-propanol and 2-methyl-2-propanol?

<p>Different positions of the hydroxyl group (D)</p> Signup and view all the answers

Which property is likely to be different between 2-methyl-1-propanol and 2-methyl-2-propanol due to their isomeric forms?

<p>Boiling point (C)</p> Signup and view all the answers

In organic chemistry, isomerization reactions typically involve changes in which of the following?

<p>The arrangement of atoms (A)</p> Signup and view all the answers

What is the main factor contributing to the decrease in size from $Li₁₃$ to $Be₄$?

<p>Increase in nuclear charge without significant electron shielding (A)</p> Signup and view all the answers

What can be inferred about the trend in atomic size as you move from $Li₁₃$ to $Be₄$?

<p>Atomic size decreases due to increased nuclear charge. (C)</p> Signup and view all the answers

Which reason explains why $K₁₉$ to $Ca₂₀$ shows a smaller size decrease compared to $Li₁₃$ to $Be₄$?

<p>There are added electron shells, increasing shielding. (C)</p> Signup and view all the answers

Which characteristic distinguishes $Li$ and $Be$ from $Na$ and $Mg$ in terms of size?

<p>The less effective nuclear charge in $Na$. (D)</p> Signup and view all the answers

What is the value of the principal quantum number in the configuration described as $n=5, l=3, m=0, s=1/2$?

<p>5 (A)</p> Signup and view all the answers

Which configuration correctly describes a state with $n=3, l=2, m=2, s=1/2$?

<p>$3d$ (C)</p> Signup and view all the answers

How many unpaired electrons are present in the configuration $n=2, l=2, m=0, s=-1/2$?

<p>0 (A)</p> Signup and view all the answers

What term is used to describe the energy required to remove an electron from an atom or ion?

<p>Ionization energy (A)</p> Signup and view all the answers

Which of the following describes the term 'atomic size'?

<p>The average distance of the nucleus from the outermost electron (A)</p> Signup and view all the answers

Flashcards

Molar Mass of Na

Atomic weight of sodium is 23 g/mol.

Wt Formula

Wt = MxVx(MxVx/100)

Saturated Solution

A solution in which no more solute can dissolve at a given temperature and pressure.

Ideal Solution

A solution in which the interactions between solute and solvent molecules are similar in strength to those within the pure components.

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Boiling Point of Mixture

The temperature at which a mixture boils at a given pressure; Example: mixture of immiscible organic liquid and water boils at 90°C, 734 mmHg.

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Percent Composition

The percentage of a specific substance in a mixture.

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Organic Liquid

A liquid substance containing carbon atoms.

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Vapor Pressure

Pressure exerted by vapor in equilibrium with a liquid.

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Molecular Weight

Mass of a molecule, important for substance identification.

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73% Organic Liquid

A solution with 73% concentration of organic liquid.

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2-chloropropane structure

A branched alkane with a chlorine atom at the second carbon.

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1-bromobutane structure

A straight-chain alkane with a bromine atom at the first carbon.

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3-hydroxyheptane structure

A seven-carbon chain with a hydroxyl group at the third carbon.

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2-fluoro-1-pentyne structure

A five-carbon chain with a fluorine at carbon 2 and a triple bond at carbon 1.

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Ozonolysis of propyne, reducing workup, acetic acid?

False. Ozonolysis of propyne gives carboxylic acids (not specifically acetic).

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Isomerization type

A rearrangement of atoms within a molecule, creating a different structural isomer without changing its molecular formula.

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2-methyl-1-propanol

A specific chemical compound with a particular arrangement of atoms and bonds.

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2-methyl-2-propanol

A specific chemical compound with a particular arrangement of atoms and bonds.

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Position Isomerism

A type of isomerism where the atoms are arranged differently on a chain or ring, but still form the same overall molecule.

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Bond Angle in CH₄

The angle between two adjacent bonds in a methane molecule (CH₄).

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Li to Be size difference

The change in atomic radius between Lithium and Beryllium is greater than that between elements like Sodium and Magnesium due to the increasing nuclear charge and the lack of significant shielding by the added electron shell.

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Atomic Radius Trend

Atomic radius generally decreases across a period due to increasing nuclear charge and less shielding, although exceptions exist.

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Shielding Effect

Inner electrons partially block the attractive force of the nucleus on outer electrons, reducing the effective nuclear charge experienced by outer electrons.

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Nuclear Charge

The positive charge of an atom's nucleus, determined by the number of protons.

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Why significant difference between Li and Be?

The jump between Lithium and Beryllium is larger because the addition of the second electron shell results in less shielding to overcome the increased nuclear charge, hence a great decrease in atomic size.

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Electron Configuration $n=5, l=3, m=0, s=1/2$

Describes the location and spin of an electron in an atom, specifically in the 5th shell, 3rd subshell with a zero magnetic quantum number and positive 1/2 spin.

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Electron Configuration $n=3, l=2, m=2, s=1/2$

Describes an electron in the 3rd shell, 2nd subshell, with a magnetic quantum number (space orientation) of +2 and spin (direction of rotation) of 1/2

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Ionization Energy

Energy required to remove an electron from an atom or ion in the gaseous state.

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Atomic Size

Average distance from the center of an atom to its outermost electron.

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$Ti^{2+}_{22}$ electron configuration

Titanium ion with a +2 charge, with electron configuration of the ion. The information is missing from the prompt.

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Study Notes

Chemistry Exam Study Notes

  • Final Exam: General Chemistry I, Molecular Biology students (1st year)
  • Date: 21 Dec 2022

Definitions

  • Excluded volume: A concept in real gas equations, acknowledging that gas molecules occupy space.
  • Effusion of gases: The process where gas molecules pass through a small opening.
  • Mean free path: The average distance a gas molecule travels between collisions.

Real Gas Equation

  • The real gas equation is (P + a/V²) (V − b) = RT
    • Where:
      • P = pressure
      • V = volume
      • a and b are constants specific to the gas
      • R = ideal gas constant
      • T = temperature

Calculations

  • Calculate the weight of NaOH needed to prepare 500ml of 2M NaOH solution:
    • Atomic weights: Na = 23, H = 1, O = 16
    • Formula weight of NaOH ≈ 40 g/mol
    • Calculate using the formula: Wt = MxVX=

Solutions

  • Saturated Solution: A solution in which no more solute can be dissolved at a given temperature and pressure.
  • Osmotic Pressure: The pressure required to prevent the flow of solvent across a semipermeable membrane.
  • Ideal Solution: A solution that obeys Raoult's law.

Organic Liquid and Water Mixture

  • An immiscible organic liquid and water mixture boils at 90°C and 734 mmHg pressure.
  • The solution is 73% organic liquid. Calculate the MW of the organic liquid given that the vapor pressure of water at 90°C is 526 mmHg.

Organic Chemistry Structures

  • 2-chloropropane: Chemical structure needs to be drawn
  • 1-bromobutane: Chemical structure needs to be drawn
  • 3-hydroxyheptane: Chemical structure needs to be drawn
  • 2-fluoro-1-pentyne: Chemical structure needs to be drawn

True/False Statements (Organic Chemistry)

  • Ozonolysis of propyne: Followed by reduction gives acetic acid (True/False)
  • Hybridization of propyne: SP, linear shape (True/False)
  • Trans-2-butene stability: More stable than cis-2-butene (True/False)
  • Alkene polarity: More than alkanes (True/False)
  • n-butane/iso-butane isomerism: Chain isomerism (True/False)
  • Pentane/2-methylbutane Boiling point: Pentane has a higher boiling point (True/False)
  • Ozonolysis of 2-butene: Gives acetaldehyde (True/False)
  • 2-methyl-1-propanol/2-methyl-2-propanol isomerization: Position isomerism (True/False)

Additional Topics (Part III)

  • Bond angles in CH₄ and NH₃: Check correct answer options.
  • Linear molecules: Identify which are linear
  • Carbon atom hybridization in CO₂: Determine hybridization type
  • Element classifications (Noble Gases, Representative, Transition Metals): Classify provided elements.
  • Quantum numbers: Determine permissible and impermissible sets of quantum numbers.
  • Ionization energy & Atomic size: Define and explain
  • Electronic configuration of Ti²⁺: Answer correct configuration for Titanium ion.
  • Orbital occupancies: Identify the correct orbital occupied by an electron given the quantum numbers.
  • Atomic size variations in periodic table: Explain how atomic size changes across periods and down groups, and why.
  • Size change between elements (e.g., Li₂ & Be₄): Explain why the decrease in size is greater in one case than the other.

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Description

Prepare for your General Chemistry I final exam with this comprehensive quiz. Covering key concepts such as excluded volume, effusion of gases, and the real gas equation, this quiz is perfect for first-year Molecular Biology students. Brush up on your calculations and definitions to excel in your exam.

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