Gas Properties and Kinetic Molecular Theory

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Questions and Answers

What properties distinguish gases from solids and liquids?

  • Gases can be compressed
  • Gases expand to fill any container (correct)
  • Gases flow easily
  • Gases have no volume (correct)

What theory explains the behavior of gases with respect to conditions such as temperature and pressure?

Kinetic Molecular Theory (KMT)

What are the five basic assumptions of the kinetic theory about the properties of gases?

Gas particles have no volume, move in constant random motion, collisions are elastic, no forces between molecules, average kinetic energy depends on temperature.

What characteristics do real gases have that contradict the assumptions of kinetic molecular theory?

<p>Real gases have volume and forces of attraction.</p> Signup and view all the answers

What conditions are needed for gases to behave in a nearly ideal manner?

<p>High temperature, low pressure, non-polar atoms/molecules, and small particles.</p> Signup and view all the answers

What is true about the compressibility of gases?

<p>Gases are compressible due to the large empty spaces between gas particles.</p> Signup and view all the answers

What are the 4 variables used to describe the characteristics of a gas?

<p>Volume (L), Temperature (K), Amount of Moles (n), Pressure (atm, kPa)</p> Signup and view all the answers

How is gas pressure produced?

<p>Gas particles press against the walls of the container.</p> Signup and view all the answers

What is the difference between a barometer and a manometer?

<p>A barometer measures atmospheric pressure, while a manometer measures the pressure of any gas.</p> Signup and view all the answers

What describes how gases behave when the temperature increases?

<p>The average kinetic energy of gas particles increases, leading to faster-moving particles and greater pressure.</p> Signup and view all the answers

How are the average kinetic energy of gas particles and their Kelvin temperature related?

<p>They are directly proportional.</p> Signup and view all the answers

What conditions indicate STP (standard temperature and pressure)?

<p>0 degrees Celsius and 1 atm OR 273 K and 101.325 kPa.</p> Signup and view all the answers

What is the SI unit for pressure?

<p>kPa</p> Signup and view all the answers

What are the conversion unit factors for pressure?

<p>760 torr = 1 atm, 14.7 psi = 1 atm, 760 mmHg = 1 atm, 101.325 kPa = 1 atm.</p> Signup and view all the answers

What is the conversion factor to convert °F to °C?

<p>ºC = (5/9)(ºF - 32)</p> Signup and view all the answers

What is the conversion factor to convert °C to Kelvin?

<p>K = °C + 273</p> Signup and view all the answers

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Study Notes

Properties Distinguishing Gases

  • Gases expand to occupy any container and have no fixed volume.

Kinetic Molecular Theory (KMT)

  • KMT explains gas behavior regarding temperature and pressure.

Basic Assumptions of Kinetic Theory

  • Gas particles are considered to have no volume.
  • Particles are in constant, random, straight-line motion.
  • Collisions between particles are perfectly elastic.
  • There are no attractive or repulsive forces between gas molecules.
  • Average kinetic energy relates directly to temperature.

Real Gas Behavior

  • Real gases possess volume and exhibit forces of attraction between particles, contradicting KMT assumptions.

Ideal Gas Conditions

  • Near-ideal gas behavior occurs at high temperatures, low pressure, with non-polar molecules, and small particle sizes.

Compressibility of Gases

  • Gas particles have large relative distances, resulting in considerable empty space and thus high compressibility.
  • Compressibility measures the volume decrease of matter under pressure.

Gas Characteristics Variables

  • Key variables defining gas characteristics include volume (L), temperature (K), amount of moles (n), and pressure (atm, kPa).

Gas Pressure Mechanism

  • Gas pressure arises from particles colliding with the walls of their container.

Pressure Measurement Devices

  • A barometer measures atmospheric pressure, while a manometer measures the pressure of a specific gas.

Effects of Temperature on Gas Behavior

  • Increasing temperature raises the average kinetic energy of gas particles, leading to faster motion.
  • Faster particles strike container walls more energetically, resulting in higher pressure.

Average Kinetic Energy Relation

  • Average kinetic energy of gas particles directly correlates to their Kelvin temperature; as one increases, so does the other.

Standard Temperature and Pressure (STP)

  • STP is defined as either 0 degrees Celsius and 1 atm or 273 K and 101.325 kPa.

Pressure Units

  • The SI unit for pressure is kilopascals (kPa), while pounds per square inch (psi) is commonly used in the U.S.

Atmospheric Pressure Conversion Factors

  • 760 torr = 1 atm
  • 14.7 psi = 1 atm
  • 760 mmHg = 1 atm
  • 101.325 kPa = 1 atm

Temperature Conversion Factors

  • To convert Fahrenheit (°F) to Celsius (°C): ºC = (5/9)(ºF - 32)
  • To convert Celsius (°C) to Kelvin (K): K = °C + 273

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