Fused Polynuclear Aromatic Hydrocarbons Quiz

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Questions and Answers

What is the largest single constituent of coal-tar?

  • Phenanthrene
  • Naphthalene (correct)
  • Methane
  • Anthracene

Which of the following is a fused or condensed aromatic hydrocarbon?

  • Methanol
  • Naphthalene (correct)
  • Ethanol
  • Propane

What is used to remove acidic impurities during the purification of naphthalene?

  • Hydrochloric acid
  • Sodium hydroxide (correct)
  • Water
  • Dilute sulfuric acid

How is naphthalene obtained from the middle oil fraction?

<p>By chilling and subsequent purification (C)</p> Signup and view all the answers

In naming derivatives of naphthalene, what numbering system is used?

<p>$1, 2$ numbering system (A)</p> Signup and view all the answers

What is the most important member of the class of fused or condensed aromatic hydrocarbons?

<p>Naphthalene (B)</p> Signup and view all the answers

How is naphthalene obtained from the middle oil fraction?

<p>By chilling the middle oil fraction and subsequent purification processes (B)</p> Signup and view all the answers

Which aromatic hydrocarbon contains two pairs of carbon atoms shared by two rings?

<p>Anthracene (B)</p> Signup and view all the answers

What is used to remove basic impurities during the purification of naphthalene?

<p>Dilute sulfuric acid (C)</p> Signup and view all the answers

What is the alternative nomenclature system used when there is only one substituent on the naphthalene skeleton?

<p>$1,2$-naming system (D)</p> Signup and view all the answers

How is naphthalene obtained from the middle oil fraction?

<p>By chilling the middle oil fraction and then washing it successively with dilute sulfuric acid, sodium hydroxide, and water (A)</p> Signup and view all the answers

What is used to remove acidic impurities during the purification of naphthalene?

<p>Sodium hydroxide (A)</p> Signup and view all the answers

What is the largest single constituent of coal-tar?

<p>Naphthalene (C)</p> Signup and view all the answers

In naming derivatives of naphthalene, what numbering system is used?

<p>$1, 6$-numbering system (B)</p> Signup and view all the answers

Which aromatic hydrocarbon contains two pairs of carbon atoms shared by two rings?

<p>Anthracene (B)</p> Signup and view all the answers

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Study Notes

Naphthalene and Coal-Tar

  • Naphthalene is the largest single constituent of coal-tar.
  • Naphthalene is a fused or condensed aromatic hydrocarbon.

Purification of Naphthalene

  • Acidic impurities are removed during the purification of naphthalene using sodium hydroxide.
  • Basic impurities are removed during the purification of naphthalene using sulphuric acid.

Obtaining Naphthalene

  • Naphthalene is obtained from the middle oil fraction through fractional distillation.

Nomenclature of Naphthalene Derivatives

  • The peripheral numbering system is used to name derivatives of naphthalene.
  • The alternative nomenclature system used when there is only one substituent on the naphthalene skeleton is the ortho-meta-para system.

Characteristics of Naphthalene

  • Naphthalene is the most important member of the class of fused or condensed aromatic hydrocarbons.
  • It contains two pairs of carbon atoms shared by two rings.

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