Fractional Distillation of Crude Oil

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What is the main principle behind fractional distillation of oil?

Size of molecules

Why do smaller molecules in fractional distillation of oil condense at the top at lower temperatures?

They are lighter in weight

What is the purpose of vacuum distillation in separating heavy residues from crude oil fractions?

To decrease the boiling point of heavy residues

In fractional distillation in the laboratory, why is the most volatile substance collected at the top of the fractionating column?

Due to having the lowest boiling point

What happens to vapors with higher boiling points in fractional distillation in the laboratory?

They condense back into the flask

How does lowering the pressure over a liquid affect its boiling point?

Decreases its boiling point

What is the purpose of fractional distillation in the context of separating liquids?

To cool the vapors and condense them into a liquid

What is the primary economic reason for the process of cracking larger hydrocarbons into smaller molecules?

To meet the demand for shorter hydrocarbon fractions

Which type of cracking produces mostly alkenes like ethene used in the production of polymers?

Thermal cracking

What are the conditions required for catalytic cracking to occur?

Moderate pressure and high temperature

In the context of combustion, what happens to alkanes when there is incomplete combustion?

They form toxic carbon monoxide and/or soot

What are the products of complete combustion of alkanes in the presence of excess oxygen?

$CO_2 (g)$ and $H_2O(l)$

Learn about the process of fractional distillation in the industrial refining of crude oil. Understand how different fractions condense at various heights in the column based on their boiling points and molecular sizes.

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