Forensic Science: Glass Analysis

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Questions and Answers

Glass is a hard, amorphous material made by melting sand, lime (also called calcium oxide), and sodium oxide at very high temperatures.

True (A)

The primary ingredient of glass is carbon dioxide.

False (B)

Glass is called an amphibious solid because its atoms are arranged in a random fashion.

False (B)

Fine glassware and decorative art glass, called crystal or leaded glass, contain lead oxide rather than calcium oxide.

<p>True (A)</p> Signup and view all the answers

Each type of glass has a density that is specific to that glass. One method of matching glass fragments is by a density comparison.

<p>True (A)</p> Signup and view all the answers

Density of glass is calculated by dividing the:

<p>mass of a substance by its volume.</p> Signup and view all the answers

The refractive index is a tool used to study how light bends as it passes through:

<p>one substance and into another</p> Signup and view all the answers

When light travels through any medium other than a vacuum, the particles in that medium slow the light down. As the density of the medium increases, the speed of light passing through that material _____.

<p>decreases</p> Signup and view all the answers

The speed of light passing through air is slightly:

<p>slower than the speed of light passing through a vacuum, because air is slightly denser than a vacuum.</p> Signup and view all the answers

What is Snell's law?

<p>It describes the behavior of light as it travels from one medium into a different medium.</p> Signup and view all the answers

One method of determining if the evidence glass matches the glass from the crime scene is to compare the:

<p>refractive index of the evidence glass to the refractive index of the glass from the crime scene.</p> Signup and view all the answers

The submersion method involves placing the glass fragment into different liquids of known refractive indexes. If a piece of glass and a liquid have the same refractive index, the glass fragment will seem:

<p>to disappear when placed in the liquid.</p> Signup and view all the answers

If the refractive indexes of several different liquids are known, the:

<p>submersion method can be used to estimate the refractive index of the glass.</p> Signup and view all the answers

If the refractive index of the liquid medium is different than the refractive index of the piece of glass, a halo-like ring appears around the edge of the glass. This halo-like effect is called a:

<p>Becke line.</p> Signup and view all the answers

Obsidian refers to:

<p>volcanic glass</p> Signup and view all the answers

When glass is hit:

<p>it can stretch slightly</p> Signup and view all the answers

By examining glass fracture patterns, it is:

<p>possible to determine which side of the glass was hit.</p> Signup and view all the answers

Silicon dioxide is:

<p>the chemical name for silica.</p> Signup and view all the answers

Glass will break first on the weaker side, the side:

<p>opposite the strike. Radial fractures will result.</p> Signup and view all the answers

As a bullet passes through glass, it pushes some glass ahead of it, causing a cone-shaped piece of glass to exit along with the bullet. The cone of glass makes the exit hole:

<p>larger than the entrance hole of the bullet.</p> Signup and view all the answers

If several shots are fired through glass, the _____ in which the shots were fired can be determined if enough of the glass is available or can be reconstructed.

<p>order</p> Signup and view all the answers

The angle at which a bullet enters a piece of window glass can help locate the position of the shooter. If the bullet was fired perpendicular to the windowpane, the entry hole of the bullet will be _____.

<p>round</p> Signup and view all the answers

A high-speed bullet fired from a great distance will often exhibit characteristics of a _____ fired from a closer range.

<p>slower-speed bullet</p> Signup and view all the answers

_____ is a combination of two or more types of glass, one hard and one soft. The softer layer makes the glass more elastic so it can flex instead of shatter.

<p>Bulletproof glass</p> Signup and view all the answers

_____ is also known as tempered glass. It is used in windshields and is composed of two layers of glass bonded together by a layer of plastic in the middle.

<p>Safety glass</p> Signup and view all the answers

How is the density of glass calculated?

<p>By dividing the mass of a substance by its volume.</p> Signup and view all the answers

The refractive index is a tool used to study how light bends as it passes through what?

<p>One substance and into another</p> Signup and view all the answers

When light travels through any medium other than a vacuum, the particles in that medium slow the light down. As the density of the medium increases, what happens to the speed of light passing through that material?

<p>The speed of light passing through that material decreases.</p> Signup and view all the answers

How does the speed of light passing through air compare to the speed of light passing through a vacuum?

<p>The speed of light passing through air is slightly slower than the speed of light passing through a vacuum, because air is slightly denser than a vacuum.</p> Signup and view all the answers

What does Snell's law describe?

<p>The behavior of light as it travels from one medium into a different medium.</p> Signup and view all the answers

In the submersion method, what happens if a piece of glass and a liquid have the same refractive index?

<p>The glass fragment will seem to disappear when placed in the liquid.</p> Signup and view all the answers

If the refractive indexes of several different liquids are known, what can the submersion method be used to estimate?

<p>The refractive index of the glass.</p> Signup and view all the answers

If the refractive index of the liquid medium is different than the refractive index of the piece of glass, a halo-like ring appears around the edge of the glass. What is this halo-like effect called?

<p>Becke line</p> Signup and view all the answers

What does obsidian refer to?

<p>Volcanic glass</p> Signup and view all the answers

What can happen to glass when it is hit?

<p>It can stretch slightly</p> Signup and view all the answers

What is possible to determine by examining glass fracture patterns?

<p>It is possible to determine which side of the glass was hit.</p> Signup and view all the answers

What is the chemical name for silica?

<p>Silicon dioxide.</p> Signup and view all the answers

Glass will break first on the weaker side, which is which side relative to the strike? What type of fractures will result?

<p>The side opposite the strike. Radial fractures will result.</p> Signup and view all the answers

As a bullet passes through glass, it pushes some glass ahead of it, causing a cone-shaped piece of glass to exit along with the bullet. How does this affect the exit hole compared to the entrance hole?

<p>The cone of glass makes the exit hole larger than the entrance hole of the bullet.</p> Signup and view all the answers

When light travels through any medium other than a vacuum, the particles in that medium slow the light down. As the density of the medium increases, the:

<p>speed of light passing through that material decreases.</p> Signup and view all the answers

What materials are used to create soda lime glass?

<p>Silica (silicon dioxide), sodium oxide, and calcium oxide.</p> Signup and view all the answers

Can glass be considered trace evidence?

<p>True (A)</p> Signup and view all the answers

What is the primary ingredient in glass?

<p>Silica (silicon dioxide, $SiO_2$).</p> Signup and view all the answers

What is sodium oxide used for in glass production?

<p>To reduce the melting temperature of silica, making it easier and less expensive to melt.</p> Signup and view all the answers

What is the role of calcium oxide in glass production?

<p>Calcium oxide (lime) prevents the glass from being soluble in water.</p> Signup and view all the answers

What are crystalline solids?

<p>Solids that have a regular, repeating atomic structure.</p> Signup and view all the answers

What are amorphous solids?

<p>Solids that have an irregular, non-repeating atomic structure.</p> Signup and view all the answers

Is glass crystalline or amorphous?

<p>Amorphous.</p> Signup and view all the answers

How does glass break?

<p>Glass breaks in a variety of irregular fracture patterns because it is an amorphous solid.</p> Signup and view all the answers

What is soda lime glass?

<p>It is the most common and inexpensive type of glass, typically used for windows and glass containers.</p> Signup and view all the answers

What effect does adding different metal oxides have on glass?

<p>Adding different metal oxides yields glasses with different colors.</p> Signup and view all the answers

What characteristics of glass allow for comparisons in forensic analysis?

<p>Comparing properties like density, refractive index, and color (due to added metal oxides).</p> Signup and view all the answers

What is the formula for calculating density?

<p>$d = m/v$ (density equals mass divided by volume).</p> Signup and view all the answers

How is mass typically measured in a lab setting for density determination?

<p>Using a balance (often a beam balance or electronic balance) to measure in grams (g).</p> Signup and view all the answers

How can the volume of an irregular glass fragment be measured?

<p>By using the water displacement method: placing the glass fragment into a graduated cylinder or beaker filled with a known volume of water and measuring the volume change (typically in milliliters, mL).</p> Signup and view all the answers

What is the refractive index?

<p>A measure of how much a beam of light changes speed and bends (refracts) when it moves from one medium into another.</p> Signup and view all the answers

Define refractive index in the context of forensic analysis.

<p>It is a tool used to study how light bends as it passes from one substance (like air or a liquid) into another (like glass), which helps in comparing glass fragments.</p> Signup and view all the answers

What is the normal line in the context of light refraction?

<p>An imaginary line perpendicular to the surface of the glass (or interface) at the point where the light ray enters.</p> Signup and view all the answers

What happens to light when it moves from a less dense medium to a more dense medium?

<p>Its speed slows down, and the light bends towards the normal line.</p> Signup and view all the answers

What does the term refraction mean?

<p>The bending of a wave (like light) as it passes at an angle from one medium into another where its speed is different.</p> Signup and view all the answers

What happens to light when it moves from a more dense medium to a less dense medium?

<p>Its speed increases, and the light bends away from the normal line.</p> Signup and view all the answers

What is the submersion method used for in glass analysis?

<p>It is used to determine the refractive index of small glass fragments found at a crime scene.</p> Signup and view all the answers

How is the refractive index practically applied in comparing glass fragments using the submersion method?

<p>The glass fragments seem to disappear (or have minimal visible edges) when placed in a liquid that has the same refractive index.</p> Signup and view all the answers

What is a Becke line and what does it indicate?

<p>A Becke line is a halo-like effect appearing at the edges of a glass fragment when viewed under a microscope submerged in a liquid with a different refractive index. Its location indicates which medium (glass or liquid) has the higher refractive index.</p> Signup and view all the answers

Provide examples of glass commonly found at crime scenes.

<p>Glass fragments from vehicle headlights, broken car windows, or windows from buildings.</p> Signup and view all the answers

Why is the location of the Becke line significant when comparing refractive indices?

<p>The Becke line moves into the medium with the higher refractive index when the microscope focus is raised. If it moves into the glass, the glass index is higher; if it moves into the liquid, the liquid index is higher.</p> Signup and view all the answers

What happens when glass is forced to stretch beyond its elastic limit?

<p>It fractures, and fracture lines appear.</p> Signup and view all the answers

What type of fracture typically occurs first when glass breaks due to impact?

<p>Radial fractures.</p> Signup and view all the answers

What are radial fractures?

<p>Fractures that radiate outward from the point of impact, occurring first on the side of the glass opposite to the impact force (the tension side).</p> Signup and view all the answers

What information can glass fracture patterns provide to investigators?

<p>Clues about the direction of impact, the rate of impact (high or low velocity), and the sequence of multiple impacts.</p> Signup and view all the answers

Why doesn't glass break into regular pieces?

<p>Because it is an amorphous solid, meaning its internal atomic structure is irregular and lacks the ordered planes found in crystalline solids.</p> Signup and view all the answers

What are secondary fractures in glass, and where do they occur?

<p>Secondary fractures are also known as concentric fractures. They form after radial fractures and occur on the same side as the point of impact.</p> Signup and view all the answers

How does glass behave on the side it is impacted?

<p>The side of the glass that is hit is compressed.</p> Signup and view all the answers

What are concentric fractures in glass?

<p>Fractures that form circles or arcs around the point of impact, typically on the same side of the glass as the impact force.</p> Signup and view all the answers

Describe the forces acting on glass when it is hit by an object like a rock or bullet.

<p>The side that is hit undergoes compression, while the opposite side stretches and experiences tension.</p> Signup and view all the answers

Which type of fractures appear first when glass is impacted?

<p>Radial fractures appear first.</p> Signup and view all the answers

Describe what happens as a bullet passes through glass.

<p>It pushes a cone-shaped piece of glass out ahead of it.</p> Signup and view all the answers

How does the exit side of a bullet hole in glass typically compare to the entrance side?

<p>The exit side of the hole is larger than the entrance side.</p> Signup and view all the answers

How does the entrance side of a bullet hole in glass typically appear?

<p>The entrance side of the hole is smaller than the exit side.</p> Signup and view all the answers

How do radiating fracture lines from a subsequent shot interact with existing fracture lines?

<p>Radiating fracture lines from a subsequent shot will stop when they encounter the edge of fracture lines already present in the glass from a previous shot.</p> Signup and view all the answers

Under what condition can the sequence of shots fired through glass be determined?

<p>The sequence can often be determined if there is enough glass remaining with overlapping fracture patterns.</p> Signup and view all the answers

What is tempered glass, and where is it commonly used?

<p>Glass that is strengthened by rapid heating and cooling. It crumbles into small, granular pieces when broken. Commonly used for side and rear car windows, and glass doors in buildings.</p> Signup and view all the answers

What is safety glass (laminated glass), and where is it commonly used?

<p>Safety glass consists of two or more layers of glass bonded together with a layer of plastic (like PVB) sandwiched in between. It's commonly used for car windshields.</p> Signup and view all the answers

What evidence related to window glass can help locate the position of a shooter?

<p>The angles at which bullets enter window glass, determined by the shape and characteristics of the bullet hole and surrounding fractures.</p> Signup and view all the answers

How can glass fragments become trace evidence related to a shooter?

<p>Bits of glass can fly backwards towards the shooter upon impact (backscatter), creating trace evidence that can link the shooter to the scene.</p> Signup and view all the answers

Describe the composition of bulletproof glass.

<p>It typically consists of multiple layers of glass alternating with layers of plastic (polycarbonate). One layer is often hard (glass) and the other soft (plastic).</p> Signup and view all the answers

Describe the shape of a bullet hole in glass for different impact angles.

<p>A shot fired perpendicular (straight on) to the glass surface tends to create a round or circular hole. A shot fired from an angle tends to create an elongated or oval-shaped hole.</p> Signup and view all the answers

What is the relationship between the incident angle and the reflected angle when light hits a surface?

<p>The angle of incidence is equal to the angle of reflection.</p> Signup and view all the answers

What type of property is density?

<p>A physical property.</p> Signup and view all the answers

Is density an intensive or extensive property?

<p>Intensive.</p> Signup and view all the answers

What does it mean for a property to be intensive?

<p>An intensive property does not change if the size of the sample changes. For example, the density of a small glass fragment is the same as the density of the original large pane.</p> Signup and view all the answers

What is a common unit for density, particularly for liquids or relating volume by displacement?

<p>g/mL (grams per milliliter).</p> Signup and view all the answers

If the volume of an object increases while its mass stays the same, what happens to its numerical value of density?

<p>The density decreases.</p> Signup and view all the answers

What is another common unit for density, often used for solids when dimensions are measured?

<p>$g/cm^3$ (grams per cubic centimeter).</p> Signup and view all the answers

What property of a material is the refractive index primarily dependent upon?

<p>The density of the material.</p> Signup and view all the answers

What happens to light passing between two mediums if it strikes the interface perpendicularly (at a 0° angle to the normal)?

<p>It does not bend (refract), although its speed changes.</p> Signup and view all the answers

Glass can be considered trace evidence.

<p>True (A)</p> Signup and view all the answers

What is sodium oxide ($Na_2O$) used for in glassmaking?

<p>To reduce the melting temperature of silica</p> Signup and view all the answers

What is the role of calcium oxide ($CaO$) in glassmaking?

<p>Prevents glass from being soluble in water</p> Signup and view all the answers

What property characterizes crystalline solids?

<p>They have a regular, repeating atomic structure.</p> Signup and view all the answers

What property characterizes amorphous solids?

<p>They have an irregular atomic structure.</p> Signup and view all the answers

How does glass typically break?

<p>In a variety of irregular fracture patterns</p> Signup and view all the answers

What is soda lime glass often used for?

<p>Inexpensive glass items like most containers (bottles, jars) and window panes.</p> Signup and view all the answers

What characteristics allow forensic comparisons between glass fragments?

<p>Density, refractive index, and chemical composition (e.g., presence of specific metal oxides).</p> Signup and view all the answers

How is mass typically measured when determining the density of a glass fragment?

<p>Using a balance, measured in grams (g).</p> Signup and view all the answers

How is the volume of an irregular glass fragment typically measured?

<p>By water displacement: placing the fragment into a graduated cylinder or beaker with water and measuring the volume of water it displaces (in mL or cm³).</p> Signup and view all the answers

What is the normal line in optics?

<p>An imaginary line perpendicular to the surface at the point where a light ray strikes the interface between two mediums.</p> Signup and view all the answers

When light moves from a less dense medium to a more optically dense medium, how does its speed and direction change?

<p>Its speed decreases, and the light bends towards the normal line.</p> Signup and view all the answers

Define refraction.

<p>The bending of a wave (such as light) as it passes from one medium to another.</p> Signup and view all the answers

When light moves from a more optically dense medium to a less dense medium, how does its speed and direction change?

<p>Its speed increases, and the light bends away from the normal line.</p> Signup and view all the answers

When is the submersion method particularly useful in forensic glass analysis?

<p>When the glass fragments found at the crime scene are too small for density determination.</p> Signup and view all the answers

How does the submersion method work to determine refractive index?

<p>The glass fragment is placed in liquids of known refractive indices. When the fragment is immersed in a liquid with the same refractive index, it will seem to disappear.</p> Signup and view all the answers

What is a Becke line and how is it used?

<p>A halo-like effect appearing at the edges of a glass fragment when immersed in a liquid with a different refractive index. It is used to compare the refractive index of the glass to that of the liquid.</p> Signup and view all the answers

What are common examples of glass evidence found at crime scenes?

<p>Fragments from broken car windows, headlights, or windows from buildings.</p> Signup and view all the answers

Why is the location of the Becke line significant?

<p>It indicates which medium (the glass fragment or the surrounding liquid) has the higher refractive index.</p> Signup and view all the answers

What happens when glass is stressed beyond its elastic limit?

<p>Fracture lines appear.</p> Signup and view all the answers

What information can be inferred from glass fracture patterns?

<p>Clues about the direction, rate, and sequence of the impacts.</p> Signup and view all the answers

Why doesn't glass break into regular, predictable pieces?

<p>Because it is an amorphous solid with an irregular internal structure.</p> Signup and view all the answers

What are concentric fractures?

<p>Fractures that form circles or arcs around the point of impact. They occur after radial fractures and form on the same side as the impact.</p> Signup and view all the answers

What happens to the side of glass that is hit during an impact?

<p>It is compressed.</p> Signup and view all the answers

What happens to the side of glass opposite the point of impact?

<p>It stretches and experiences tension.</p> Signup and view all the answers

What often happens as a high-velocity projectile like a bullet passes through glass?

<p>It pushes a cone-shaped piece of glass out ahead of it.</p> Signup and view all the answers

How can the sequence of multiple impacts (e.g., bullet holes) on glass be determined?

<p>By observing the termination points of radial fracture lines; fractures from a later impact will end when they meet fractures from an earlier impact.</p> Signup and view all the answers

What is tempered glass?

<p>Glass that is rapidly heated and cooled during manufacturing, creating high compressive stress on the surfaces and tension inside. It shatters into small, granular pieces.</p> Signup and view all the answers

What is laminated safety glass?

<p>Glass made by sandwiching a layer of plastic (typically polyvinyl butyral, PVB) between two or more layers of glass.</p> Signup and view all the answers

What aspect of a bullet hole in a window can help locate the shooter's position?

<p>The angle at which the bullet entered the glass, often indicated by the shape of the hole (circular vs. oval) and associated fractures.</p> Signup and view all the answers

How can breaking glass create trace evidence relevant to the person causing the break?

<p>Small fragments of glass can fly backwards (backscatter) and embed in the clothing or hair of the person.</p> Signup and view all the answers

Describe the typical structure of bullet-resistant glass.

<p>It usually consists of multiple layers of glass and/or plastics (like polycarbonate) bonded together. Layers may vary in hardness.</p> Signup and view all the answers

How does the shape of a bullet hole relate to the angle of impact?

<p>A perpendicular impact (90 degrees to the surface) creates a mostly circular hole. An angled impact creates an oval hole, elongated in the direction of travel.</p> Signup and view all the answers

What is the relationship between the angle of incidence and the angle of reflection?

<p>They are equal ($ heta_i = heta_r$).</p> Signup and view all the answers

Is density a physical or chemical property?

<p>Physical property</p> Signup and view all the answers

What defines an intensive property?

<p>A property that does not depend on the amount or size of the sample.</p> Signup and view all the answers

What is a common unit for density?

<p>grams per milliliter (g/mL) or grams per cubic centimeter (g/cm³).</p> Signup and view all the answers

If the volume of an object increases while its mass remains constant, what happens to its density?

<p>The density decreases.</p> Signup and view all the answers

What physical property is the refractive index closely related to?

<p>The density of the material.</p> Signup and view all the answers

Does light bend if it enters a new medium perpendicular to the surface (along the normal)?

<p>No, there is no bending (refraction).</p> Signup and view all the answers

What characterizes crystalline solids?

<p>They have a regular, repeating atomic structure.</p> Signup and view all the answers

What characterizes amorphous solids?

<p>They have an irregular atomic structure.</p> Signup and view all the answers

Is glass considered crystalline or amorphous?

<p>Amorphous</p> Signup and view all the answers

What characteristics of glass allow for forensic comparisons?

<p>Color (due to metal oxides), density, and refractive index.</p> Signup and view all the answers

How is mass typically measured in a laboratory setting?

<p>Using a balance (often measured in grams).</p> Signup and view all the answers

How can the volume of an irregular object like a glass fragment be measured?

<p>By water displacement: placing the fragment in a graduated cylinder or beaker with water and measuring the volume of water displaced (usually in milliliters).</p> Signup and view all the answers

What happens to light when it moves from one medium into another, relating to the refractive index?

<p>Its speed changes and its direction bends (refracts).</p> Signup and view all the answers

What is the refractive index a measure of?

<p>It is a measure used to study how light bends (refracts) as it passes from one substance to another.</p> Signup and view all the answers

What is the "normal line" in the context of refraction?

<p>An imaginary line perpendicular to the surface where the two mediums meet.</p> Signup and view all the answers

What happens to light when it moves from a less dense medium to a more optically dense medium?

<p>Its speed slows down, and it bends towards the normal line.</p> Signup and view all the answers

What does "refraction" mean in the context of light?

<p>Bending.</p> Signup and view all the answers

What happens to light when it moves from a more optically dense medium to a less dense medium?

<p>Its speed increases, and it bends away from the normal line.</p> Signup and view all the answers

When is the submersion method typically used in glass analysis?

<p>When the glass fragments found at a crime scene are too small for other methods.</p> Signup and view all the answers

How is the refractive index applied in the submersion method?

<p>The glass fragment will seem to disappear, or have minimal Becke lines, when placed in a liquid that has the same refractive index.</p> Signup and view all the answers

What is a Becke line?

<p>A halo-like effect appearing at the edges of a glass fragment when viewed under a microscope in a liquid, visible when the refractive indices of the glass and liquid differ.</p> Signup and view all the answers

Why is the location and movement of the Becke line significant during refractive index analysis?

<p>Its movement when adjusting focus indicates which medium (the glass fragment or the surrounding liquid) has the higher refractive index.</p> Signup and view all the answers

What is a primary type of fracture pattern in broken glass?

<p>Radial fracture.</p> Signup and view all the answers

What are radial fractures and where do they originate?

<p>They are fractures that radiate outward from the point of impact and form first on the side opposite the impact.</p> Signup and view all the answers

What clues can glass fracture patterns provide to investigators?

<p>The direction, rate (relative speed), and sequence of impacts.</p> Signup and view all the answers

Why doesn't glass typically break into regular, predictable pieces?

<p>Because it is an amorphous solid.</p> Signup and view all the answers

What are secondary fractures in glass often called, and where do they form?

<p>Concentric fractures; they form on the same side as the point of impact.</p> Signup and view all the answers

What happens to the side of the glass that is impacted?

<p>It is compressed.</p> Signup and view all the answers

Describe concentric fractures in glass.

<p>They form circles or arcs around the point of impact, sharing a common center, and occur on the same side of the glass as the impact.</p> Signup and view all the answers

When an object like a rock or bullet hits glass, what forces act on each side?

<p>The side that is hit is compressed, while the opposite side stretches under tension.</p> Signup and view all the answers

Which type of glass fracture appears first upon impact?

<p>Radial fractures.</p> Signup and view all the answers

What typically happens as a bullet passes through glass?

<p>It pushes a cone-shaped piece of glass out ahead of it.</p> Signup and view all the answers

How does the exit side of a bullet hole in glass compare to the entrance side?

<p>The exit side is larger than the entrance side.</p> Signup and view all the answers

Is the entrance hole of a bullet in glass smaller or larger than the exit hole?

<p>Smaller.</p> Signup and view all the answers

What happens to radiating fracture lines from a subsequent bullet shot when they encounter existing fracture lines?

<p>They will stop at the edge of the fracture lines already present in the glass.</p> Signup and view all the answers

How can the order of multiple shots fired through glass be determined?

<p>By examining how the radial fracture lines from later shots terminate at the fracture lines from earlier shots (assuming enough of the glass remains).</p> Signup and view all the answers

What is tempered glass and how is it made?

<p>It is safety glass made by heating glass and then cooling it rapidly, creating a stressed state (compression on surfaces, tension inside).</p> Signup and view all the answers

What evidence in broken window glass can help locate the position of a shooter?

<p>The angles at which bullets entered the glass.</p> Signup and view all the answers

How can breaking glass create trace evidence relevant to a shooter or person causing the impact?

<p>Small bits of glass can fly backward (backscatter) from the impact point onto the person or object causing the break.</p> Signup and view all the answers

Describe the composition of typical bullet-resistant glass.

<p>It is usually made of multiple layers, often alternating hard glass layers and softer plastic (like polycarbonate) layers, laminated together.</p> Signup and view all the answers

What shape is a bullet hole in glass if the impact is perpendicular? What if the angle is oblique?

<p>A perpendicular impact creates a generally circular hole. An oblique (angled) impact creates a more oval-shaped hole.</p> Signup and view all the answers

According to the law of reflection, how does the angle of incidence relate to the angle of reflection?

<p>They are equal ($θ_i = θ_r$).</p> Signup and view all the answers

What is a common unit for density relevant to forensic glass analysis?

<p>Grams per milliliter (g/mL) or grams per cubic centimeter (g/cm³).</p> Signup and view all the answers

If the mass of an object remains constant but its volume increases, what happens to its density?

<p>The density decreases.</p> Signup and view all the answers

Flashcards

What is glass?

A hard, amorphous material made by melting sand, lime (calcium oxide), and sodium oxide at high temperatures.

Is carbon dioxide the primary ingredient of glass?

False. The primary ingredient of glass is silicon dioxide (SiO2) or silica, derived from sand.

Is glass an 'amphibious' solid with ordered atoms?

False; glass is called an amorphous solid because its atoms are arranged randomly, not in a crystalline structure.

Does fine glassware contain lead oxide?

True. Fine glassware often contains lead oxide for clarity and brilliance.

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Is density comparison used to match glass fragments?

True. Density is a key property for matching glass fragments.

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How is density calculated?

Mass divided by Volume.

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What is refractive index?

The bending of light as it passes from one substance to another.

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How does density affect light speed?

The speed of light decreases.

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Is light faster in air or a vacuum?

Slower.

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What is Snell's Law?

Describes how light behaves when transitioning between different mediums.

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How to match glass fragments?

Comparing refractive indexes.

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What happens when glass matches liquid's refractive index?

To disappear.

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What can be estimated using the submersion method?

The submersion method can be used to estimate the refractive index of the glass.

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What is the halo-like ring called?

Becke line.

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What is obsidian?

Volcanic glass.

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What happens when glass is hit?

It can stretch slightly.

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What can be determined by examining glass fracture patterns?

Possible to determine which side was hit.

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What is silicon dioxide?

The chemical name for silica.

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Where does glass break first?

Opposite the strike.

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Is the exit hole larger than the entrance hole?

Larger than the entrance hole.

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What can be determined from multiple shots through glass?

Order

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What shape will the bullet entry hole be if fired perpendicularly?

Round

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What characteristics will a high-speed bullet exhibit from a great distance?

Slower-speed bullet

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What type of glass is a combination of two or more other glasses?

Bulletproof glass

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What kind of glass is used in windshields?

Safety glass

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Soda Lime Glass Ingredients

Silica, sodium oxide, and calcium oxide.

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Glass as Trace Evidence?

Yes, if the glass fragment is of sufficient size to analyze.

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Primary Glass Ingredient

Silica (silicon dioxide, SiO2).

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Sodium Oxide's Role in Glass

To reduce the melting temperature of silica.

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Calcium Oxide's Role in Glass

To prevent the glass from dissolving in water.

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Crystalline Solids

Solids with a regular, repeating atomic structure.

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Amorphous Solids

Solids with an irregular, non-repeating atomic structure.

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Glass: Crystalline or Amorphous?

Amorphous.

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How Glass Breaks

In a variety of irregular fracture patterns.

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Soda-Lime Glass

An inexpensive type of glass commonly used for containers.

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Metal Oxides in Glass

To impart different colors to the glass.

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Glass Comparison Factors

Adding metal oxides, density, and refractive index.

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Density Formula

Density equals mass divided by volume (d = m/v).

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Measuring Mass

Using a balance beam to measure in grams.

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Measuring Volume

By placing the glass fragment into a beaker filled with water and measuring the volume of water displaced (in milliliters).

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Refractive Index

The bending of light as it passes from one medium to another due to a change in speed.

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Refractive Index (Definition)

A tool used to study how light bends as it passes from one substance to another.

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Normal Line

A line perpendicular to the glass surface where two mediums meet.

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Light: Less Dense to More Dense

The speed of light slows down, and the light bends towards the normal line.

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Refraction

The bending of light.

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Light: More Dense to Less Dense

The speed of light increases, and the light bends away from the normal line.

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Submersion Method

A method used when glass fragments are small.

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Applying Refractive Index

The glass fragment will disappear when placed in a liquid of the same refractive index.

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Becke Line

A halo-like effect appearing at the edges of a glass fragment when the refractive indices of the glass and liquid are different.

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Glass at Crime Scenes

Glass fragments from headlights or broken car windows.

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Becke Line Significance

It indicates which medium has a higher refractive index.

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Glass Stretching

Fracture lines appear.

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Glass Break Types

Radial fractures.

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Radial Fractures

Occur first on the opposite side of the impact and radiate outward.

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Fracture Pattern Clues

Direction, rate, and sequence of impacts.

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Why Glass Doesn't Break Regularly

Because it is an amorphous solid.

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Secondary Fractures

Concentric fractures; form on the same side as the point of impact.

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Impacted Glass

It is compressed on the side it is hit.

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Concentric Glass

Form circles around the point of impact.

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Rock/Bullet Hitting Glass

The side that is hit is compressed, and the opposite side stretches and experiences tension.

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First Fractures to Appear

Radial fractures.

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Bullet Through Glass

It pushes a cone-shaped piece of glass out of the glass ahead of it.

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Exit Side of Hole

Larger than the entrance side.

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Entrance

Smaller than the exit.

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Subsequent Shot Fracture Lines

Stop at the edge of the fracture lines already present in the glass.

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Determining Shot Order

If there is enough glass to analyze the fracture patterns.

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Tempered Glass

Glass that has been heated and cooled quickly to create a hard outer surface; commonly used in car and building windows.

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Safety Glass

Glass that is sandwiched in plastic; commonly used in car windshields.

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Locating the Shooter

The angles at which bullets enter window glass.

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Backscatter

Bits of glass that fly backwards upon impact.

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Bulletproof Glass

Multiple layers of glass, with one hard and one soft layer that have the same refractive index to appear transparent.

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Bullet Entry

Circular, from the left blows out to the right and oval.

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Incident vs. Reflected Angle

They are the same.

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Density Property Type

Physical.

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Density: Intensive or Extensive?

Intensive.

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Intensive (Property)

Doesn't change if the sample is broken or a part is removed.

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Density Unit

g/mL (grams per milliliter).

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Increasing Volume's Impact on Density

Decreases.

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Object Volume Unit

g/cm^3.

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Refraction Index Dependence

Density of the material.

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Light w/out Angle

There is no bend.

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Study Notes

  • Glass is a hard, amorphous material.
  • Glass is created by melting sand, lime (calcium oxide), and sodium oxide at very high temperatures.
  • The primary ingredient of glass is not carbon dioxide
  • Glass is not called an amphibious solid
  • Crystal or leaded glass contains lead oxide rather than calcium oxide.
  • Each type of glass has a specific density.
  • Matching glass fragments can be done by density comparison.
  • Depending on the size, glass can be trace evidence.

Materials to create soda-lime glass

  • Silica, sodium oxide, and calcium oxide are used

Role of Silica/Silicon Dioxide (Primary Ingredient)

  • The primary ingredient in glass is silica/silicon dioxide.

Role of Sodium Oxide

  • Sodium oxide reduces the temperature of silica so it melts sooner.

Role of Calcium Oxide

  • Calcium oxide prevents glass from being soluble in water.

Crystalline vs Amorphous Solids

  • Crystalline solids have a regular atomic structure.
  • Amorphous solids have an irregular atomic structure.
  • Glass is amorphous.
  • Glass breaks in a variety of irregular fracture patterns because it is amorphous.

Soda-Lime Glass

  • Soda-lime glass is inexpensive and is used for most glass containers.

Adding Different Metal Oxides

  • Adding different metal oxides yields different colors and characteristics allowing comparisons, such as densities and refractive indexes.

Density

  • Density is calculated by dividing the mass of a substance by its volume.
  • d=m/v is a formula for calculating density
  • Mass is measured with a balance beam in grams
  • Volume is measured by placing the glass fragment into a beaker filled with water and measuring the overflow in millimeters.
  • The density numerical value decreases if the volume of an object increases.
  • g/mL is the unit for density
  • The volume of an object is g/cm^3
  • Density is a physical property.
  • Density is intensive which means it doesn't change if it is broken or a part of the sample is taken away

Refractive Index

  • Refractive index studies how light bends as it passes through one substance into another.
  • The refractive index is dependent upon the density of the material.
  • As the density of a medium increases, the speed of light passing through it decreases.
  • Light travels slower through air than a vacuum because air is denser.
  • Snell's law describes the behavior of light as it travels from one medium to another.
  • Comparing the refractive index of evidence glass to the refractive index of glass from the crime scene can help determine if they match.
  • Refraction occurs when a beam of light moves from one medium into another, the speed changes, and the direction bends.
  • Refraction is the bend
  • Without an angle, there is no bend
  • The normal line is perpendicular to the glass surface, where the two mediums meet.
  • When light travels from a less dense medium to a more dense medium, the speed slows, and bends light towards the normal line.
  • When light travels from a more dense medium to a less dense medium the speed goes up, and bends light away from the normal line
  • The incident vs reflected angle are the same.

Submersion Method

  • The submersion method involves placing a glass fragment into liquids with known refractive indexes.
  • The submersion method is used when glass fragments found at the crime scene are small.
  • Glass seems to disappear when placed in a liquid with the same refractive index.
  • The submersion method can estimate the refractive index of glass if the refractive indexes of several liquids are known.
  • A Becke line is a halo-like ring that appears around the edge of glass when the refractive index of the liquid medium is different than that of the glass.
  • Applying the refractive index, the glass fragments will disappear when placed in a liquid of the same refractive index
  • A Becke line is a halo like effect appearing at the edges of a glass fragment when the reflective index of the glass and liquid are different.
  • If the line is inside the glass perimeter, the glass index is higher than the index of the liquid; if the line is outside the glass perimeter, the glass index is lower.
  • The location of the becke line is significant because it is located in the medium with the higher index; located on the outside=refractive index is higher for the medium

Additional Information

  • Obsidian is volcanic glass.
  • Examples of glass used in crime scenes, are glass fragments from headlights or broken car windows
  • Glass can stretch slightly when hit.
  • Examining glass fracture patterns allows for the determination of which side of the glass was hit.
  • Silicon dioxide is the chemical name for silica.
  • Glass breaks first on the side opposite the strike, resulting in radial fractures.
  • Fracture lines appear when glass is forced to stretch too far.
  • What kind of breaks does glass have? Radial fracture
  • Radial fractures occur on the opposite side and radiate out
  • Fracture patterns provide clues about direction, rate, and sequence of impacts.
  • Impacted glass is compressed on the side it is hit.
  • Concentric fractures form circles around the point of impact and have the same center and form on the same side of glass as a point of impact.
  • Secondary fractures are concentric fractures and are on the same side as the point of impact.
  • When a rock or bullet hits the glass, the side that is hit is compressed and the other side will stretch and provide tension.
  • Radial fractures appear first.
  • A cone-shaped piece of glass exits with a bullet, making the exit hole larger than the entrance hole.
  • As a bullet passes through glass, it pushes a cone shaped piece of glass out of the glass ahead of it
  • The order in which shots were fired through glass can be determined if enough glass is available.
  • Radiating fracture lines from a subsequent shot will stop at the edge of the fracture lines already present in the glass.
  • The exit side of the hole is larger than the entrance side of the hole
  • The entrance is smaller than the exit
  • If a bullet was fired perpendicular to a windowpane, the entry hole will be round.
  • If perpindicular, circular, from the left blows out to the right and oval
  • A high-speed bullet fired from a great distance can exhibit characteristics of a slower-speed bullet fired from a closer range.
  • Bulletproof glass combines a hard and soft type of glass.
  • One hard and one soft have the same refractive index, so they appear as one, transparent
  • A softer layer makes the glass more elastic so it can flex instead of shattering.
  • Safety glass is also known as tempered glass which is used in windshields.
  • Tempered glass is heated and cooled quickly and has a hard outer surface and is found in car and building windows
  • Safety glass is also known as car glass
  • Safety glass is composed of two layers of glass bonded together by a layer of plastic in the middle.
  • Bits of the glass can fly backwards and backscatter and creates trace evidence
  • The angles at which bullets enter window glass can help locate the position of the shooter.

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