Flotation Chemistry and Process Overview
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What is the primary purpose of the Denver flotation equipment in laboratory trials?

  • To measure pH levels of water samples
  • To mix floating particles with air
  • To condition minerals before flotation
  • To collect concentrates at various time intervals (correct)
  • What function does the air serve in the Denver flotation experiment?

  • It separates non-floating particles from floating ones
  • It collects the froth and concentrates at the top of the cell
  • It facilitates the sinking of heavier particles
  • It helps to condition the minerals during flotation (correct)
  • During a Denver flotation experiment, how many concentrates are typically collected?

  • 4 or 5 concentrates at different periods (correct)
  • Only one concentrate per experiment
  • 10 concentrates over extended periods
  • 2 or 3 concentrates at once
  • How are minerals that float during the Denver flotation process removed from the system?

    <p>They are collected by skimming the froth from the top (B)</p> Signup and view all the answers

    What aspect of the Denver flotation cells contributes to the conditioning of minerals?

    <p>The volume of the flotation cells (B)</p> Signup and view all the answers

    Which properties of particles are crucial for the flotation process?

    <p>Wettability and hydrophobicity (A)</p> Signup and view all the answers

    What is necessary for the continuity of the froth during the flotation process?

    <p>Mechanical mixing and the addition of frother (D)</p> Signup and view all the answers

    What role do flotation reagents play in the flotation process?

    <p>They enhance the capture of mineral particles by air bubbles. (D)</p> Signup and view all the answers

    Which type of mining utilizes the flotation process for mineral extraction?

    <p>Both underground and open pit mining (B)</p> Signup and view all the answers

    Which of the following is NOT a mineral commonly enriched using the flotation method?

    <p>Gold (A)</p> Signup and view all the answers

    What must happen to the ore before flotation can effectively separate minerals?

    <p>The ore must be adequately ground. (B)</p> Signup and view all the answers

    What type of particles tend to float easily during the flotation process?

    <p>Hydrophobic particles (C)</p> Signup and view all the answers

    What type of adsorption occurs when an anionic collector interacts with a positive charged mineral surface?

    <p>Physical adsorption (A)</p> Signup and view all the answers

    What is the main effect of increasing the SDS concentration on bubble-particle attachment time measurements?

    <p>It increases the amount of particles attached to the bubble surfaces. (A)</p> Signup and view all the answers

    Which adsorption type is indicated when a cationic collector attaches to a negative charged mineral surface?

    <p>Physical adsorption (C)</p> Signup and view all the answers

    In bubble-particle attachment time experiments, how long was the measurement period for all concentrations of SDS?

    <p>100 ms (A)</p> Signup and view all the answers

    Which option describes the adsorption of anionic collectors on negatively charged mineral surfaces?

    <p>Chemical adsorption (D)</p> Signup and view all the answers

    What does the variation in SDS concentrations from 1.10-5 M to 1.10-4 M indicate about attachment capacity?

    <p>It enhances attachment capacity. (C)</p> Signup and view all the answers

    What is the significance of the mineral surface's charge in the context of collector adsorption?

    <p>It influences the type of adsorption that can occur. (A)</p> Signup and view all the answers

    What conclusion can be drawn from observing an increase in particles attached to bubbles with higher SDS concentrations?

    <p>It indicates improved interface activity of surfactants. (D)</p> Signup and view all the answers

    Which scenario represents the method of chemical adsorption based on surface charge interactions?

    <p>Anionic collector on negative surface (D)</p> Signup and view all the answers

    What is primarily affected by the types of collectors used in the adsorption processes?

    <p>Type of mineral surface (B)</p> Signup and view all the answers

    What is the primary function of flotation activators?

    <p>To promote the reaction of collecting reagents with desired minerals (C)</p> Signup and view all the answers

    What is the significance of the contact angle in flotation processes?

    <p>It measures the strength of the bubble-mineral attachment (C)</p> Signup and view all the answers

    Which range of contact angles is considered optimal for flotation?

    <p>50o &lt; θ &lt; 75o (B)</p> Signup and view all the answers

    What is the role of dispensers in flotation systems?

    <p>To prevent mineral particles from being covered by slime (D)</p> Signup and view all the answers

    What type of groups do flotation reagents typically contain?

    <p>Both polar and non-polar groups (D)</p> Signup and view all the answers

    Why must the buoyancy of the bubble exceed the force of gravity?

    <p>To enable the mineral to rise to the surface (B)</p> Signup and view all the answers

    Which characteristic describes non-polar groups in flotation reagents?

    <p>They are expressed as hydrophobic groups (D)</p> Signup and view all the answers

    What can be inferred about a mineral with a high contact angle?

    <p>It adheres strongly to bubbles (D)</p> Signup and view all the answers

    How does the presence of reagents impact flotation efficiency?

    <p>Reagents can either enhance or hinder mineral reactions (B)</p> Signup and view all the answers

    What effect does decreasing bubble size have on the amount of particles attached to the bubble surfaces?

    <p>The amount of particles attached increases. (C)</p> Signup and view all the answers

    At an SDS concentration of $2-4 imes 10^{-5}$ M, how does the flotation recovery relate to bubble-particle attachment time?

    <p>Flotation recovery exhibits a strong correlation with bubble-particle attachment time. (B)</p> Signup and view all the answers

    Which bubble size was shown to have the lowest particle attachment in the experiments?

    <p>2 mm (B)</p> Signup and view all the answers

    In the context of flotation recovery related to SDS concentration, what does the graph suggest?

    <p>Flotation recovery is enhanced by specific SDS concentration ranges. (C)</p> Signup and view all the answers

    What was the attachment time measured at for 1.10-5 M SDS in the study?

    <p>100 ms (B)</p> Signup and view all the answers

    How does the presence of SDS in solution influence the bubble-particle attachment process?

    <p>SDS acts as a surfactant, enhancing particle attachment to bubbles. (D)</p> Signup and view all the answers

    Which statement best describes the relationship between flotation recovery and bubble-particle attachment time based on the findings?

    <p>There is a strong positive relationship between flotation recovery and attachment time. (A)</p> Signup and view all the answers

    Regarding bubble size's effect on attachment, what trend was observed?

    <p>Smaller bubbles increase the particle attachment more significantly than larger ones. (C)</p> Signup and view all the answers

    How is flotation recovery quantitatively expressed in the results?

    <p>As a percentage indicated on the graph. (A)</p> Signup and view all the answers

    What conclusion can be drawn regarding the relationship between SDS concentration and flotation recovery from the experiments?

    <p>A specific range of SDS concentrations optimizes flotation recovery. (D)</p> Signup and view all the answers

    Study Notes

    Flotation Chemistry

    • Flotation is a process for separating hydrophobic (water-repellent) particles from hydrophilic (water-wetted) ones using bubbles.
    • It's used in various industries, including wastewater treatment, mineral processing, and construction.
    • At least 100 different minerals (like copper, lead, zinc, nickel, silver, manganese, chrome, cobalt, titanium, quartz, feldspar, and coal) are enriched through flotation.

    Flotation Process

    • The process involves several stages, including underground mining, open-pit mining, stock area, crushing, transfer to grinding, grinding at the flotation plant, and flotation in cells.
    • Minerals are separated based on their wettability: hydrophobic minerals attach to air bubbles while hydrophilic minerals sink.
    • The continuous process of flotation involves proper grinding of the ore, ensuring continuous froth, adding frothers to the medium, and adding flotation reagents to ensure bubble capture of mineral particles.
    • The medium must remain continuous for mineral particles to properly attach to air bubbles.

    Flotation Introduction

    • Flotation is a physico-chemical process leveraging differences in mineral surface properties (wettability or hydrophobicity).
    • Key parameters affecting flotation success include shape factor, pH, and surface roughness of the minerals, along with the size of the air bubbles.

    Flotation Reagents

    • Flotation reagents are grouped into collectors, frothers, and control reagents (which include activators and depressants, pH regulators, and others).
    • Collectors attach minerals to air bubbles.
    • Frothers create and stabilize foam.
    • Activators facilitate desired mineral reactions.
    • Depressants prevent unwanted mineral reactions.
    • pH regulators control the pH of the environment.

    Flotation Chemistry

    • Minerals typically don't attach to bubbles if they're hydrophilic.
    • Mineral enrichment through flotation depends on making mineral surfaces hydrophobic, the pH of the environment, and air bubble size.
    • The chemicals added to the flotation medium are called flotation reagents.

    The Main Rules of Operation

    • Key operational factors for effective flotation include bubble-particle attachment efficiency and the number of bubbles.

    Flotation Reagents (Continued)

    • Activators and depressants facilitate and disrupt reactions, respectively, between desired minerals and reagents.
    • Dispensers prevent mineral particles from sticking together in the pulp.

    Flotation Technique

    • Prior to flotation, ore mineralogical analysis, liberation degree, appropriate reagents, required time for reagent adsorption, and pulp-solids ratio are determined.

    Hallimond Tube

    • A micro-flotation unit (made of glass) used to study mineral behavior in a dynamic environment.

    Micro-flotation Cell Experiments

    • Details of micro-flotation cell experimental setups are provided.

    Denver Flotation Experiments

    • Denver flotation is a common laboratory procedure for mineral processing trials.
    • Specific experimental procedures include conditioning the mineral samples within the flotation device and introducing air.
    • Collected concentrates are sampled and tested at different time intervals (0–1 min., 1–2 min., 2–4 min., 4–8 min., and 8–16 min.).
    • Float and sink product samples are dried and weighed for final analysis.

    Pilot-Scale Flotation Experiments

    • Includes various pilot-scale flotation equipment setups, including circuits, to study treatment processes for different materials.

    Flotation Kinetics

    • Provides correlations between attachment time, minerals, and flotation grade.

    Next Week

    • Scheduled lessons include coagulation/flocculation, rheology, summary, and lab compensations.

    Results for Bubble-Particle Attachment, Time Experiments

    • The number of particles attached to the bubble's surface increases with increasing SDS concentration
    • Measurements of bubble-particle attachment time and the relationship between attachment time and flotation recovery. The amount of particles attached to the bubble surface increases as the bubble size decreases.

    Mineral Commodities

    • A supplementary list of common minerals, including oxides, silicates, sulfides, complex hydrocarbons, and some soluble salts

    Flotation Parameters

    • The buoyancy of the bubble must exceed the gravity force of the mineral for successful flotation.
    • A large contact angle makes minerals float more easily.
    • The contact angle is a measure of a mineral's suitability for flotation.
    • A good flotation involves a contact angle between 50° and 75°.

    Flotation Reagents (Polar and Nonpolar Groups)

    • Reagents for flotation include both polar and nonpolar groups.
    • Nonpolar groups (hydrocarbon chains) are hydrophobic because they interact weakly with water molecules.
    • Polar groups are hydrophilic, strongly interacting with water molecules.

    Adsorption of Collectors on Mineral Surfaces

    • There are different types of adsorption (physical and chemical) of collectors on a mineral surface
    • The adsorption depends on the charge of the mineral surface

    Batch Scale Flotation Experiments

    • The chemical analysis of water used in the process is included
    • Results from a batch scale experiment with different flotation concentrates.

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    Description

    Explore the fascinating world of flotation chemistry, a crucial process for separating minerals based on their wettability. This quiz covers the fundamental principles, stages, and applications in industries like mineral processing and wastewater treatment. Test your knowledge on how various minerals are enriched through flotation techniques.

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