First Law of Thermodynamics
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Questions and Answers

What is the law that states mass is conserved and not created or destroyed?

  • First Law of Thermodynamics (correct)
  • Third Law of Thermodynamics
  • Second Law of Thermodynamics
  • Zeroth Law of Thermodynamics
  • In a steady-state, steady-flow process with multiple inlets and multiple outlets, what form does the energy balance take?

  • Closed system form
  • Differential form
  • Open system form
  • Rate basis (correct)
  • Which type of systems can be considered as special forms of open systems?

  • Reversible systems
  • Isolated systems
  • Adiabatic systems
  • Closed systems (correct)
  • In a steady-state, steady-flow single inlet, single outlet open system, what is the mass flow rate term equal to?

    <p>$0$</p> Signup and view all the answers

    What is the general first law of thermodynamics also known as?

    <p>Conservation of Energy</p> Signup and view all the answers

    Which principle asserts that closed systems do not exchange matter with their surroundings?

    <p><strong>First Law</strong></p> Signup and view all the answers

    What does the Zeroth Law of Thermodynamics state?

    <p>If two systems are at the same time in thermal equilibrium with a third system, they are in thermal equilibrium with each other.</p> Signup and view all the answers

    Who first formulated and labeled the Zeroth Law of Thermodynamics?

    <p>R.H. Fowler in 1931</p> Signup and view all the answers

    What is the function of a thermocouple in temperature measurement?

    <p>Detects a difference in electrical potential between two conductors of dissimilar materials</p> Signup and view all the answers

    Why is the Zeroth Law of Thermodynamics called 'zeroth'?

    <p>Because it should have preceded the first and second laws of thermodynamics logically</p> Signup and view all the answers

    What role does a thermometer's thermometric substance play?

    <p>Shows changes in properties due to heat interactions</p> Signup and view all the answers

    In temperature measurement, why are two systems considered to be in thermal equilibrium according to the Zeroth Law of Thermodynamics?

    <p>When they are at the same temperature as a third system</p> Signup and view all the answers

    According to the First Law of Thermodynamics, what is the relationship between work and heat in a system?

    <p>They are directly proportional.</p> Signup and view all the answers

    What is the main principle behind the First Law of Thermodynamics?

    <p>Energy conversion leads to a constant total energy.</p> Signup and view all the answers

    In a closed system, the change in internal energy (∆E) is equal to what combination of energy changes?

    <p>∆P∆E + ∆K∆E + ∆U + ∆(PV)</p> Signup and view all the answers

    What is the formula for determining the enthalpy (H) of an ideal gas using the First Law?

    <p>H = q + w</p> Signup and view all the answers

    In determining the internal energy of an ideal gas using the First Law, what does the term qv represent?

    <p>Heat transfer at constant volume</p> Signup and view all the answers

    What does the First Law of Thermodynamics state about the conservation of mass?

    <p>Mass is conserved similar to energy.</p> Signup and view all the answers

    What do ∆PE and ∆KE represent in the context of the First Law of Thermodynamics?

    <p>Changes in potential and kinetic energy</p> Signup and view all the answers

    Study Notes

    First Law of Thermodynamics

    • The First Law of Thermodynamics, also known as the Law of Conservation of Energy, states that energy cannot be created or destroyed, only converted from one form to another.
    • The law is often mathematically expressed as ΔE = Q - W, where ΔE is the change in total energy of the system, Q is the heat added to the system, and W is the work done on the system.

    Systems

    • A closed system is a system where no mass is exchanged with the surroundings, but energy can be exchanged in the form of heat and work.
    • An open system is a system where both mass and energy can be exchanged with the surroundings.

    Energy Forms

    • Kinetic energy (KE) is the energy of motion.
    • Potential energy (PE) is the energy of position or stored energy.
    • Internal energy (U) is the total energy of the system, including kinetic energy, potential energy, and other forms of energy.
    • Enthalpy (H) is a measure of the total energy of a system, including internal energy and the energy associated with the pressure and volume of a system.

    First Law of Thermodynamics for Closed and Open Systems

    • For a closed system, ΔE = Q - W, where ΔE is the change in internal energy of the system.
    • For an open system, ΔE = Q - W + ΔEPE, where ΔEPE is the change in potential energy of the system.

    Applications of the First Law of Thermodynamics

    • Compression of gas in a closed system: Q - W = ΔU
    • Ideal gas: dh = du + pdv, where dh is the change in enthalpy, du is the change in internal energy, pdv is the work done on the system.

    Heat Transfer and Specific Heat Capacity

    • Heat transfer (Q) can be calculated using the formula Q = mcΔT, where m is the mass of the substance, c is the specific heat capacity, and ΔT is the temperature difference.
    • Specific heat capacity (c) is the amount of heat energy required to raise the temperature of a unit mass of a substance by one degree Celsius.

    Conservation of Mass

    • The law of conservation of mass states that mass is neither created nor destroyed, only converted from one form to another.

    Time Rate Form of the First Law

    • The time rate form of the First Law of Thermodynamics is a mathematical expression of the law that describes the rate of energy exchange between a system and its surroundings.

    Zeroth Law of Thermodynamics

    • The Zeroth Law of Thermodynamics states that if two systems are in thermal equilibrium with a third system, they are also in thermal equilibrium with each other.
    • The Zeroth Law is the basis of temperature measurement and is used to define the temperature of a system.

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    Description

    Test your knowledge on the First Law of Thermodynamics, which states that energy cannot be created or destroyed, only converted from one form to another. This law explains the relationship between heat, work, and energy in a system.

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