First Law of Thermodynamics and Enthalpy Relation Quiz
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Questions and Answers

Define an extensive property of a system and provide an example.

An extensive property depends on the quantity of matter in the system. Example: mass.

What is an intensive property of a system? Give an example.

An intensive property does not depend on the quantity of matter in the system. Example: temperature.

What does it mean for a thermodynamic system to be in a state?

A thermodynamic system is in a state when all its thermodynamic properties are fixed.

How can the state of a system be changed?

<p>The state of a system can be changed by altering the values of its thermodynamic properties.</p> Signup and view all the answers

According to the ideal gas equation, what does PV=nRT represent?

<p>PV=nRT represents the ideal gas equation for a gas with 'n' moles.</p> Signup and view all the answers

What are the three state variables that determine the state of a system?

<p>Pressure, volume, and temperature are the three state variables that determine the state of a system.</p> Signup and view all the answers

What is the first law of thermodynamics equation?

<p>q = △E + P△V</p> Signup and view all the answers

Define the relationship between enthalpy and internal energy at constant pressure.

<p>△H = △E + △nRT</p> Signup and view all the answers

What does it indicate if △n = 0 in a chemical reaction?

<p>△H = △E</p> Signup and view all the answers

In an exothermic reaction, how does △H compare to △E?

<p>△H &lt; △E</p> Signup and view all the answers

What is the ideal gas equation for reactants and products involving gases at constant pressure and temperature?

<p>P(V2 – V1) = (n2 – n1) RT</p> Signup and view all the answers

Explain the energy profile diagram in the context of chemical reactions.

<p>The diagram shows the energy levels of reactants and products, with energy being absorbed or released during bond formation or breaking.</p> Signup and view all the answers

What does Lavoisier and Laplace law state?

<p>The enthalpy change of a chemical reaction is equal but opposite in sign for the reverse reaction.</p> Signup and view all the answers

Mathematically, how is the enthalpy change of a backward reaction related to the forward reaction?

<p>ΔH_forward reaction = -(ΔH_backward reaction)</p> Signup and view all the answers

Explain Hess's Law of Constant Heat Summation.

<p>The total change in enthalpy in a chemical reaction is constant, regardless of the number of steps involved.</p> Signup and view all the answers

How can the enthalpy change of a reaction be calculated using Hess's Law?

<p>ΔH = ΔH1 + ΔH2 + ΔH3</p> Signup and view all the answers

What does Hess's Law imply about the change in enthalpy of a chemical reaction?

<p>It depends on the initial and final state of the reaction, not the number of steps involved.</p> Signup and view all the answers

Explain the scenario where Q2 > Q1 according to Hess's Law.

<p>If Q2 &gt; Q1, transforming a reactant to product and then back would result in a gain of heat energy.</p> Signup and view all the answers

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