Podcast
Questions and Answers
How does the reactivity of metals change as you move down a group in the periodic table? Explain the underlying reason for this trend.
How does the reactivity of metals change as you move down a group in the periodic table? Explain the underlying reason for this trend.
Reactivity increases down the group. This is because the outermost electrons are further from the nucleus, experiencing less attraction, and are thus more easily lost.
Differentiate between the terms 'malleable' and 'ductile' when describing metals. Provide an example of a metal that exhibits both properties.
Differentiate between the terms 'malleable' and 'ductile' when describing metals. Provide an example of a metal that exhibits both properties.
Malleable means a metal can be hammered into thin sheets, while ductile means it can be drawn into wires. Copper is a common example of a metal that is both malleable and ductile.
Explain why silver and gold are considered to be among the least reactive metals. What makes them useful in jewelry?
Explain why silver and gold are considered to be among the least reactive metals. What makes them useful in jewelry?
Silver and gold are least reactive because they have a strong attraction for their valence electrons, making them resistant to oxidation and corrosion. This inertness preserves their luster and appearance, which is why they are used in jewelry.
What is the significance of platinum in catalytic converters in automobiles, and how does it contribute to reducing pollution?
What is the significance of platinum in catalytic converters in automobiles, and how does it contribute to reducing pollution?
Define 'oxidation state' and explain its importance in predicting the chemical behavior of an element. Give an example.
Define 'oxidation state' and explain its importance in predicting the chemical behavior of an element. Give an example.
Describe the process of electroplating using silver or chromium, mentioning the role of the anode, cathode, and electrolyte in coating a metallic object.
Describe the process of electroplating using silver or chromium, mentioning the role of the anode, cathode, and electrolyte in coating a metallic object.
Describe the process of electrolytic refining of copper. What are the key components and reactions that occur during the refining process and what is its purpose?
Describe the process of electrolytic refining of copper. What are the key components and reactions that occur during the refining process and what is its purpose?
What is electrolysis? Briefly explain the process of electrolysis of water, including the products formed at the anode and cathode.
What is electrolysis? Briefly explain the process of electrolysis of water, including the products formed at the anode and cathode.
Explain the working principle of Nelson's cell for the preparation of sodium hydroxide (NaOH) from brine. What are the advantages of using Nelson's cell over other methods?
Explain the working principle of Nelson's cell for the preparation of sodium hydroxide (NaOH) from brine. What are the advantages of using Nelson's cell over other methods?
What is the difference between 22-carat and 24-carat gold? Why is gold often alloyed with other metals in jewelry?
What is the difference between 22-carat and 24-carat gold? Why is gold often alloyed with other metals in jewelry?
Flashcards
What is Electrolysis?
What is Electrolysis?
The process of using electricity to drive a non-spontaneous chemical reaction.
What is oxidation state?
What is oxidation state?
A number that represents the degree of oxidation of an atom in a chemical compound.
What is electroplating?
What is electroplating?
Coating a metal object with a thin layer of another metal using electrolysis for protection or decoration.
Physical Properties of Metals
Physical Properties of Metals
Signup and view all the flashcards
Chemical Properties of Metals & Non-metals
Chemical Properties of Metals & Non-metals
Signup and view all the flashcards
Platinum as a Catalyst
Platinum as a Catalyst
Signup and view all the flashcards
Examples of Halogens
Examples of Halogens
Signup and view all the flashcards
Silver/Gold Low Reactivity
Silver/Gold Low Reactivity
Signup and view all the flashcards
Why use copper for wires?
Why use copper for wires?
Signup and view all the flashcards
Malleable vs. Ductile
Malleable vs. Ductile
Signup and view all the flashcards
Study Notes
- The Extended Kalman Filter (EKF) is a Kalman filter version designed for nonlinear systems.
- It approximates non-linear systems by linearizing them around the current estimate and then applying the standard Kalman filter.
Kalman Filter Basics
- Mathematical tool used to estimate the state of a system from noisy measurements
- Extensively used in robotics, economics, and control systems.
Extended Kalman Filter
- Addresses non-linearity by linearizing the system around the current estimate using Taylor series expansion.
EKF Steps
- Prediction: Predict the next state and covariance using a non-linear system model.
- Linearization: Linearize the system model around the predicted state.
- Update: Update the state estimate using the Kalman gain, computed with the linearized system and measurement models.
Jacobian Matrix
- The matrix of all first-order partial derivatives of a vector-valued function. $$ J = \begin{bmatrix} \frac{\partial f_1}{\partial x_1} & \cdots & \frac{\partial f_1}{\partial x_n} \ \vdots & \ddots & \vdots \ \frac{\partial f_m}{\partial x_1} & \cdots & \frac{\partial f_m}{\partial x_n} \end{bmatrix} $$
- $f: \mathbb{R}^n \rightarrow \mathbb{R}^m$ is a vector-valued function.
- $J$ is an $m \times n$ matrix where each entry $\frac{\partial f_i}{\partial x_j}$ represents the rate of change of the $i$-th component of $f$ with respect to the $j$-th component of $x$.
- Used to linearize a non-linear function around a specific point
Taylor Series Expansion
- Used to approximate a function at a point using its derivatives at another point.
- Scalar function $f(x)$ expansion around a point $a$: $$ f(x) = f(a) + f'(a)(x-a) + \frac{f''(a)}{2!}(x-a)^2 + \cdots $$
- Vector-valued function $f(x)$ expansion around a point $a$: $$ f(x) \approx f(a) + J(a)(x-a) $$ Where $J(a)$ is the Jacobian matrix of $f$ evaluated at $a$.
System Model
- The means to describe the evolution of the system state over time.
$$
x_t = f(x_{t-1}, u_{t-1}, w_{t-1})
$$
Where:
- $x_t$ = the state at time t
- $x_{t-1}$ = the state at time t-1
- $u_{t-1}$ = the control input at time t-1
- $w_{t-1}$ = the process noise at time t-1
- $f$ = a non-linear function that describes the system dynamics.
Measurement Model
- Depicts the relationship between measurements and the system state
$$
z_t = h(x_t, v_t)
$$
Where:
- $z_t$ = the measurement at time t
- $x_t$ = the state at time t
- $v_t$ = the measurement noise at time t
- $h$ = a non-linear function relating the state to the measurement
EKF Algorithm Steps
- Initialization: Initialize the state estimate $\hat{x}_0$ and the covariance matrix $P_0$. $$ \hat{x}_0 = E[x_0] $$ $$ P_0 = E[(x_0 - \hat{x}_0)(x_0 - \hat{x}_0)^T] $$
- Prediction: Predict the state and covariance at time $t$ given the state estimate at time $t-1$.
$$
\hat{x}t = f(\hat{x}{t-1}, u_{t-1}, 0)
$$
$$
P_t = F_{t-1}P_{t-1}F_{t-1}^T + W_{t-1}Q_{t-1}W_{t-1}^T
$$
Where:
- $F_{t-1}$ is the Jacobian matrix of $f$ with respect to $x$ evaluated at $\hat{x}_{t-1}$
- $W_{t-1}$ is the Jacobian matrix of $f$ with respect to $w$ evaluated at $0$
- $Q_{t-1}$ is the covariance matrix of the process noise $w_{t-1}$
- Measurement Update: Update the state estimate and covariance at time $t$ given the measurement at time $t$.
$$
\tilde{y}_t = z_t - h(\hat{x}_t, 0)
$$
$$
S_t = H_tP_tH_t^T + V_tR_tV_t^T
$$
$$
K_t = P_tH_t^TS_t^{-1}
$$
$$
\hat{x}_t = \hat{x}_t + K_t\tilde{y}_t
$$
$$
P_t = (I - K_tH_t)P_t
$$
Where :
- $H_t$ is the Jacobian matrix of $h$ with respect to $x$ evaluated at $\hat{x}_t$
- $V_t$ is the Jacobian matrix of $h$ with respect to $v$ evaluated at $0$
- $R_t$ is the covariance matrix of the measurement noise $v_t$
- $\tilde{y}_t$ is the measurement residual
- $S_t$ is the innovation covariance
- $K_t$ is the Kalman gain
EKF Algorithm Summary
Step | Equation | Description |
---|---|---|
1. Initialization | $\hat{x}_0 = E[x_0]$, $P_0 = E[(x_0 - \hat{x}_0)(x_0 - \hat{x}_0)^T]$ | Initialize state estimate and covariance. |
2. Prediction | $\hat{x}t = f(\hat{x}{t-1}, u_{t-1}, 0)$ | Predict state using the non-linear system model |
$P_t = F_{t-1}P_{t-1}F_{t-1}^T + W_{t-1}Q_{t-1}W_{t-1}^T$ | Predict covariance using the linearized system model. | |
3. Update | $\tilde{y}_t = z_t - h(\hat{x}_t, 0)$ | Compute measurement residual. |
$S_t = H_tP_tH_t^T + V_tR_tV_t^T$ | Compute innovation covariance. | |
$K_t = P_tH_t^TS_t^{-1}$ | Compute Kalman gain. | |
$\hat{x}_t = \hat{x}_t + K_t\tilde{y}_t$ | Update state estimate using the Kalman gain and measurement residual. | |
$P_t = (I - K_tH_t)P_t$ | Update covariance. |
Robot Model
- Considers a robot moving in a 2D plane.
- The state of the robot is given by:
$$
x_t = \begin{bmatrix}
x \
y \
\theta
\end{bmatrix}
$$
Where:
- $x$ and $y$ are the coordinates of the robot in the 2D plane
- $\theta$ is the orientation of the robot
- The control input is given by:
$$
u_t = \begin{bmatrix}
v \
\omega
\end{bmatrix}
$$
Where:
- $v$ is the linear velocity of the robot
- $\omega$ is the angular velocity of the robot
- The system model is given by:
$$
\begin{bmatrix}
x_{t+1} \
y_{t+1} \
\theta_{t+1}
\end{bmatrix} = \begin{bmatrix}
x_t + v_t\cos(\theta_t)\Delta t \
y_t + v_t\sin(\theta_t)\Delta t \
\theta_t + \omega_t\Delta t
\end{bmatrix} + w_t
$$
Where:
- $\Delta t$ is the time step
- $w_t$ is the process noise
- In this case, the function $f$ is: $$ f(x_t, u_t, w_t) = \begin{bmatrix} x_t + v_t\cos(\theta_t)\Delta t \ y_t + v_t\sin(\theta_t)\Delta t \ \theta_t + \omega_t\Delta t \end{bmatrix} + w_t $$
Measurement Model
- The robot has a sensor measuring landmark distance:
$$
z_t = \sqrt{(x_l - x_t)^2 + (y_l - y_t)^2} + v_t
$$
Where:
- $(x_l, y_l)$ are the coordinates of the landmark
- $v_t$ is the measurement noise
- In this case, the function $h$ is: $$ h(x_t, v_t) = \sqrt{(x_l - x_t)^2 + (y_l - y_t)^2} + v_t $$
EKF Implementation
- Initialization: Initialize the state estimate $\hat{x}_0$ and the covariance matrix $P_0$.
- Prediction: Predict the state and covariance at time $t$ given the state estimate at time $t-1$:
$$
\hat{x}t = f(\hat{x}{t-1}, u_{t-1}, 0) = \begin{bmatrix}
x_{t-1} + v_{t-1}\cos(\theta_{t-1})\Delta t \
y_{t-1} + v_{t-1}\sin(\theta_{t-1})\Delta t \
\theta_{t-1} + \omega_{t-1}\Delta t
\end{bmatrix}
$$
$$
P_t = F_{t-1}P_{t-1}F_{t-1}^T + W_{t-1}Q_{t-1}W_{t-1}^T
$$
Where:
- $F_{t-1}$ is the Jacobian matrix of $f$ with respect to $x$ evaluated at $\hat{x}{t-1}$: $$ F{t-1} = \begin{bmatrix} 1 & 0 & -v_{t-1}\sin(\theta_{t-1})\Delta t \ 0 & 1 & v_{t-1}\cos(\theta_{t-1})\Delta t \ 0 & 0 & 1 \end{bmatrix} $$
- $W_{t-1}$ is the Jacobian matrix of $f$ with respect to $w$ evaluated at $0$: $$ W_{t-1} = \begin{bmatrix} 1 & 0 & 0 \ 0 & 1 & 0 \ 0 & 0 & 1 \end{bmatrix} $$
- $Q_{t-1}$ is the covariance matrix of the process noise $w_{t-1}$
- Measurement Update: Update the state estimate and covariance at time $t$ given the measurement at time $t$:
$$
\tilde{y}_t = z_t - h(\hat{x}_t, 0) = z_t - \sqrt{(x_l - x_t)^2 + (y_l - y_t)^2}
$$
$$
S_t = H_tP_tH_t^T + V_tR_tV_t^T
$$
$$
K_t = P_tH_t^TS_t^{-1}
$$
$$
\hat{x}_t = \hat{x}_t + K_t\tilde{y}_t
$$
$$
P_t = (I - K_tH_t)P_t
$$
Where:
- $H_t$ is the Jacobian matrix of $h$ with respect to $x$ evaluated at $\hat{x}_t$: $$ H_t = \begin{bmatrix} \frac{-(x_l - x_t)}{\sqrt{(x_l - x_t)^2 + (y_l - y_t)^2}} & \frac{-(y_l - y_t)}{\sqrt{(x_l - x_t)^2 + (y_l - y_t)^2}} & 0 \end{bmatrix} $$
- $V_t$ is the Jacobian matrix of $h$ with respect to $v$ evaluated at $0$.
- $R_t$ is the covariance matrix of the measurement noise $v_t$.
Results
- Iteratively applying the prediction and update steps enables the EKF to estimate the robot's state over time.
- The estimate's accuracy is affected by the accuracy of the system model, the measurement model, and noise characteristics.
Advantages of EKF
- Handles Non-linear Systems by linearizing around the current estimate.
- Computationally Efficient compared to other non-linear filters like particle filters.
- Wide Applicability in robotics, computer vision, and control systems.
Disadvantages of EKF
- Linearization Errors arise, especially in highly non-linear systems.
- Jacobian Matrix Calculation can be difficult or impossible for some systems.
- Tuning Required: careful tuning of noise covariance matrices can be time-consuming.
Conclusion
- The EKF is a robust tool for estimating the state of non-linear systems, widely used in robotics and control systems.
- Limitations: linearization errors and Jacobian calculation.
- May need other non-linear filters like Unscented Kalman Filter (UKF) and particle filters for highly non-linear systems.
Studying That Suits You
Use AI to generate personalized quizzes and flashcards to suit your learning preferences.