Equilibrium in Chemical Processes

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Questions and Answers

What is a characteristic of systems at chemical equilibrium?

  • Opposing processes occur at different rates.
  • Reactant concentrations are always higher than product concentrations.
  • One of the system's parameters has a constant value. (correct)
  • Measurable properties fluctuate continuously.

Why is chemical equilibrium described as dynamic?

  • The reaction stops after reaching equilibrium.
  • Forward and reverse reactions occur at different rates.
  • The reaction produces more products than reactants.
  • Reactants and products are continuously converting into each other. (correct)

In the Haber-Bosch process, what does the use of Dâ‚‚ instead of Hâ‚‚ demonstrate?

  • Different starting materials do not affect equilibrium composition. (correct)
  • Higher temperatures always shift equilibrium towards products.
  • Equilibrium is dependent on initial reactant concentration.
  • Equilibrium cannot be achieved with isotopes.

What does a leveling-off curve in a concentration versus time graph indicate?

<p>The system has reached a state of equilibrium. (B)</p> Signup and view all the answers

Which condition is necessary for a system to reach chemical equilibrium?

<p>The temperature must remain constant in a closed system. (C)</p> Signup and view all the answers

Flashcards

Chemical Equilibrium

A state where the rates of the forward and reverse reactions in a chemical process are equal, resulting in constant concentrations of reactants and products.

Dynamic Equilibrium

A state of balance where opposing processes continue to occur at equal rates, maintaining constant measurable properties.

Closed system

A system where neither matter nor energy can enter or leave, which allows for the creation of equilibrium.

Constant Temperature

A crucial condition for equilibrium. Temperature must remain fixed during equilibrium.

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Reaction rates

The speed at which reactants turn into products (forward reaction) and products revert to reactants (reverse reaction).

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Equilibrium Composition

The relative amounts of reactants and products present when a reaction is at equilibrium and, especially, has reached a constant ratio

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Haber-Bosch Process

An example of a chemical reaction that reaches equilibrium when synthesizing ammonia from nitrogen and hydrogen.

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Le Chatelier's Principle

A principle stating that if an equilibrium is disrupted, the system will shift in the direction that relieves the stress.

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Equilibrium Graph

A graph showing concentration levels against time, exhibiting levelling-off suggesting the equilibrium state is reached.

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Study Notes

Equilibrium in Chemical Processes

  • Chemical reactions can reach equilibrium, a state where the rates of forward and reverse reactions are equal.
  • Equilibrium can be achieved starting with reactants or products.
  • Equilibrium is dynamic; both forward and reverse reactions continue, but at equal rates, maintaining constant concentrations of reactants and products.
  • Equilibrium is characterized by constant measurable properties at a given temperature.
  • The magnitude of these properties indicates the extent of the process's progression toward equilibrium.

Dynamic Equilibrium

  • Equilibrium is dynamic, meaning both forward and reverse reactions occur, but at equal rates.
  • The system is closed, preventing external influences.
  • Reactant and product concentrations remain constant.
  • The system exhibits constant, measurable properties.

Examples of Equilibrium

  • Haber-Bosch process: synthesis of ammonia.
  • The reaction in a closed system reaches equilibrium regardless of initial amounts of reactants or products.
  • The rate at which the products are produced is equal to the rate at which the reactants are used to make them.

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