Environmental Chemistry Unit Review

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Questions and Answers

What is a primary function of secure landfills?

  • To prevent pollution outside the facility (correct)
  • To promote anaerobic biodegradation
  • To store hazardous waste safely
  • To eliminate the production of methane gas

What is produced when hydrocarbons are burned?

  • Hydrogen sulfide and sulfur dioxides
  • Carbon dioxide and water vapor (correct)
  • Methane and water vapor
  • Ozone and nitrogen oxides

Which compounds are present in natural gas?

  • Methane and hydrogen sulfide only
  • Methane, ethane, propane, and butane (correct)
  • Methane, propane, and sulfur dioxides
  • Only carbon dioxide and water vapor

What occurs when hydrogen sulfide is removed from sour gas?

<p>Sulfur dioxide is produced (C)</p> Signup and view all the answers

Which of the following is NOT a pollutant produced from industrial processes?

<p>Methane (D)</p> Signup and view all the answers

What is the primary goal of wastewater treatment?

<p>To return water to the environment with minimal pollutants (C)</p> Signup and view all the answers

Which treatment process involves bacteria decomposing organic matter?

<p>Secondary Treatment (B)</p> Signup and view all the answers

What material is primarily removed during the primary treatment of wastewater?

<p>Large solids and sediments (D)</p> Signup and view all the answers

What role do septic tanks play in rural waste management?

<p>They trap grease and large solids for local soil breakdown (D)</p> Signup and view all the answers

What is a significant feature of sanitary landfills?

<p>They use clay liners to prevent leachate from contaminating groundwater (A)</p> Signup and view all the answers

During which treatment phase are biosolids typically removed from water?

<p>Secondary Treatment (C)</p> Signup and view all the answers

Where does domestic waste primarily originate from?

<p>Household kitchens, bathrooms, and laundries (C)</p> Signup and view all the answers

What treatment method is used to remove phosphates and nitrates from water?

<p>Tertiary Treatment (A)</p> Signup and view all the answers

What is the pH of normal rain or snow?

<p>5.6 (A)</p> Signup and view all the answers

What process describes the dramatic lowering of water pH due to accumulated acidic deposits melting in spring?

<p>Spring Acid Shock (B)</p> Signup and view all the answers

Which of the following compounds is NOT considered a component of acid rain?

<p>NaCl (Sodium Chloride) (D)</p> Signup and view all the answers

What is the function of scrubbers in controlling acid effects?

<p>To neutralize acidic compounds with limestone (D)</p> Signup and view all the answers

What role do catalytic converters play in vehicle emissions control?

<p>Facilitating complete combustion to reduce harmful gases (D)</p> Signup and view all the answers

Which property is characteristic of acids?

<p>Taste sour (D)</p> Signup and view all the answers

What does the pH scale primarily measure?

<p>The acidity or basicity of a solution (C)</p> Signup and view all the answers

Which of the following is a characteristic of bases?

<p>Produces a slippery feel (C)</p> Signup and view all the answers

What is created as a result of the neutralization reaction between an acid and a base?

<p>Salt and water (C)</p> Signup and view all the answers

Which indicator is commonly used to determine pH levels?

<p>Bromothymol Blue (C)</p> Signup and view all the answers

What environmental phenomenon results from the combination of rainwater and atmospheric chemicals?

<p>Acid rain (D)</p> Signup and view all the answers

What is the approximate pH of neutral substances on the pH scale?

<p>7 (C)</p> Signup and view all the answers

Which of the following statements about acids is NOT true?

<p>Acids have a pH greater than 7. (C)</p> Signup and view all the answers

Which type of molecule primarily serves as an energy source for metabolism?

<p>Carbohydrates (D)</p> Signup and view all the answers

What defines macronutrients in the context of biological molecules?

<p>Essential nutrients required in large amounts (C)</p> Signup and view all the answers

Which of the following compounds is classified as a lipid?

<p>Vegetable oil (C)</p> Signup and view all the answers

Which statement about proteins is correct?

<p>Proteins are primarily used for structural support and chemical reactions. (C)</p> Signup and view all the answers

What is the main role of nucleic acids in biological systems?

<p>Building blocks of DNA (C)</p> Signup and view all the answers

What are trace elements required for in living organisms?

<p>Maintaining enzyme function (A)</p> Signup and view all the answers

Which group of substances is referred to as macrominerals?

<p>Minerals required in large quantities (B)</p> Signup and view all the answers

What distinguishes organic molecules from inorganic ones?

<p>Predominantly composed of carbon and hydrogen (B)</p> Signup and view all the answers

What is the primary distinction between point source and non-point source pollution?

<p>Point source pollution can be easily traced back to its origin. (D)</p> Signup and view all the answers

How does an increase in pH levels affect aquatic organisms?

<p>It decreases the diversity of all organisms. (C)</p> Signup and view all the answers

Which of the following factors can contribute to the concentration of pollution in aquatic environments?

<p>Accumulation of agricultural runoff nutrients. (D)</p> Signup and view all the answers

What does dilution of pollution mean?

<p>Pollution becomes less concentrated over time. (C)</p> Signup and view all the answers

Which of the following is a chemical factor that affects water quality?

<p>Heavy metals present in the water. (A)</p> Signup and view all the answers

What are biological indicators used for in water quality assessment?

<p>To determine water quality through living organisms (A)</p> Signup and view all the answers

Which of the following organisms indicates good quality water due to their need for high oxygen levels?

<p>Caddisflies (D)</p> Signup and view all the answers

What does a parts per million (ppm) measurement indicate in environmental science?

<p>One unit of an element per one million units of an overall solution (B)</p> Signup and view all the answers

Which factor does NOT influence the levels of dissolved oxygen in water?

<p>The pH level of the water (C)</p> Signup and view all the answers

Which type of organisms are considered microbiological indicators of water quality?

<p>Bacteria (A)</p> Signup and view all the answers

Which of the following substances is best characterized as a solute in a water solution?

<p>Salt (C)</p> Signup and view all the answers

What is a significant consequence of low levels of dissolved oxygen in water?

<p>Decline in fish populations (C)</p> Signup and view all the answers

How is the concentration of pollutants often reported in environmental studies?

<p>As a parts per million (ppm) or parts per billion (ppb) (A)</p> Signup and view all the answers

What is the concentration of sulfuric acid in parts per million (ppm) after a 50 L drum spills into a lake containing 30,000 L of water?

<p>1663 ppm (B)</p> Signup and view all the answers

If a student adds 70 mL of pee to a 1000 L pool, what is the resulting concentration in ppm?

<p>70 ppm (C)</p> Signup and view all the answers

What is the concentration of free chlorine in ppm if a 20 mL sample contains 0.5 mL of chlorine?

<p>25,000 ppm (C)</p> Signup and view all the answers

What does LD50 represent in toxicity studies?

<p>Lethal dose for 50% of test subjects (A)</p> Signup and view all the answers

With an LD50 of 0.27 mg/kg for rat poison, will a 0.50 mg dose likely kill a rat weighing 0.85 kg?

<p>Yes, it exceeds the safe limit (D)</p> Signup and view all the answers

What consequence can arise from mixing different pesticides in water systems?

<p>Formation of deadly chemical combinations (C)</p> Signup and view all the answers

What term describes substances that can cause severe health issues or fatalities?

<p>Toxins (A)</p> Signup and view all the answers

What is primarily responsible for breaking down most modern pesticides after one growing season?

<p>Bacterial action (A)</p> Signup and view all the answers

What is the maximum dosage of arsenic that can be given to a 1.75 kg duck to reach its LD50?

<p>22.75 mg (B)</p> Signup and view all the answers

If a 55 kg person ingests 9625 mg of caffeine, what would this caffeine dosage cause?

<p>Half the population would possibly die. (A)</p> Signup and view all the answers

What is the LD50 of arsenic in mg/kg?

<p>13 mg/kg (B)</p> Signup and view all the answers

How many cans of Monster Energy Drink would it take to reach a lethal dose for a 55 kg person, consuming one can containing 300 mg of caffeine each?

<p>32 cans (C)</p> Signup and view all the answers

What are the potential side effects of consuming over 400 mg of caffeine daily?

<p>Unpleasant side effects like jitteriness and insomnia (C)</p> Signup and view all the answers

What does the LD50 value represent?

<p>The amount of poison needed to kill half of the population. (D)</p> Signup and view all the answers

What can complicate the interpretation of toxicity tests conducted on animals?

<p>Different effects in animals vs humans (A)</p> Signup and view all the answers

What is the appropriate LD50 range for caffeine in mg/kg?

<p>150-200 mg/kg (D)</p> Signup and view all the answers

Flashcards

Wastewater Treatment

A process that takes used water and returns it to the environment with minimal pollutants.

Primary Treatment

The initial step in wastewater treatment, where large solids and sediments are physically separated.

Secondary Treatment

The second stage in wastewater treatment, where bacteria decompose organic matter, resulting in the removal of 'biosolids' and further purification with chlorine, ozone, or UV light.

Tertiary Treatment

The final stage of wastewater treatment, where water percolates through a plant bed to remove phosphates and nitrates.

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Septic Tank

A large underground container that traps grease and large solids from sewage, commonly used in rural areas.

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Sanitary Landfill

A method of waste disposal where garbage is compacted and covered with earth and clay daily to prevent leachate from reaching groundwater.

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Leachate

Liquid that drains from a landfill and can be contaminated with various chemicals and pollutants.

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Clay Liner

A clay liner used at the bottom of sanitary landfills to prevent the harmful leachate from leaking into groundwater.

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What is methane gas and how is it used in landfills?

Methane is a gas produced when organic matter decays without oxygen, like in landfills. It's captured and used as fuel to prevent environmental harm.

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What is a secure landfill?

Secure landfills are designed to contain hazardous waste, preventing pollution from escaping the site.

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What happens when fossil fuels are burned?

Burning fossil fuels like coal, oil, and natural gas releases carbon dioxide, water vapor, and other harmful gases.

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What are the main sources of air pollution from industrial processes?

Industrial processes like electricity generation, mining, and fertilizer production can release harmful chemicals into the air, including sulfur dioxide and nitrogen oxides.

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What is 'sour gas'?

Natural gas with a high concentration of hydrogen sulfide (H2S) is called 'sour gas'. It's treated to remove sulfur dioxide before being used as fuel.

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Acid Rain/Snow

Rain or snow with a pH lower than 5.6, caused by acidic compounds like sulfuric and nitric acid.

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Spring Acid Shock

The rapid decrease in water pH during spring melt when acidic deposits accumulate over winter.

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Scrubbers

A process used in power plants to neutralize sulfur dioxide emissions, using limestone and water to absorb sulfur particles.

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Catalytic Converters

A device in cars that converts harmful exhaust gases into less harmful ones using a catalyst (like platinum), reducing CO and NOx emissions.

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What compounds cause acid rain?

The acidic compounds in the atmosphere, primarily sulfuric, nitric and nitrous acid, that contribute to acid rain and snow.

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What are acids?

Chemicals that produce acidic substances; have a pH less than 7. They tend to taste sour and feel stinging.

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What are bases?

Chemicals that produce basic substances; have a pH greater than 7. They tend to taste bitter and feel slippery.

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What are indicators?

Substances that change color when they react with acids or bases. Examples include litmus paper and universal indicator.

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What is neutralization?

A reaction between an acid and a base, where both are used up, producing salt and water.

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What is the pH scale?

A scale from 0 to 14 that measures the acidity or alkalinity of a substance. 7 is neutral, below 7 is acidic, and above 7 is basic.

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What is acid rain?

Rainwater that has become acidic due to pollutants in the atmosphere, such as sulfur dioxide and nitrogen dioxide. It can have a pH as low as 3.

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How do we measure pH?

A process that uses indicators to determine the pH of a substance. It involves matching the color of the indicator with a chart to find the corresponding pH value.

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What are the effects of acid rain and how is it neutralized?

Acid rain is a significant environmental problem that can harm ecosystems, damage buildings, and impact human health. Methods to neutralize acids include using bases, such as limestone, to reduce acidity levels in affected areas.

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Polymers

Large molecules made of repeating smaller units called monomers.

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Monomers

The building blocks of polymers, like the links in a chain.

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Macronutrients

Organic compounds essential for life, including carbohydrates, proteins, lipids and nucleic acids. They are needed in large amounts.

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Carbohydrates

Provide energy for metabolism and are found in foods like rice, grains, potatoes, and fruits.

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Proteins

Form structural components for the body, help with chemical reactions, and are found in meat, eggs, dairy, legumes, nuts, etc.

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Lipids (Fats and Oils)

Store chemical energy, provide insulation, and are found in vegetable oils, nut oils, legumes, and some dairy products.

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Nucleic Acids

Make up DNA and RNA, which are essential for genetic information and protein synthesis.

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Macrominerals

Minerals needed in significant amounts for healthy bones, teeth, and other bodily functions.

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What is pollution?

Pollution is any change to the environment that negatively affects living organisms.

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Point source pollution

A point source is a specific, identifiable location where pollution is coming from, like a factory.

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Non-point source pollution

A non-point source is a wide area where pollution is coming from, but it's not easily identified, like runoff from farmland.

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Dilution and Concentration

Dilution is when pollution is getting less concentrated, like adding fresh water to a polluted stream. Concentration is the opposite, where pollution gets stronger.

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Water quality categories

Water quality is measured in five categories by the government: drinking water, recreation, aquatic life, agriculture, and industrial use.

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Biological Indicators

Using living organisms like fish, plants, worms, and insects to assess water quality. Their presence or absence, and their health, indicate the overall quality of the water.

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Microbiological Indicators

Microscopic organisms, mainly bacteria, that can cause health problems if present in water. Their presence indicates potential contamination and risk.

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Dissolved Oxygen

The amount of oxygen dissolved in water, essential for aquatic life, insects, and microorganisms. It is affected by temperature, photosynthesis, turbulence, and the number of organisms using it.

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Parts Per Million (ppm) or Parts Per Billion (ppb)

A way to express the concentration of pollutants in water, representing one unit of the pollutant per million or billion units of water.

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Solute

The substance being dissolved in a solution, like salt in water.

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Solvent

The substance that dissolves the solute, like water in a saltwater solution.

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Concentration

A measure of the amount of solute dissolved in a given amount of solvent. It is often expressed as parts per million (ppm).

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Dilution

The process of reducing the concentration of a solute in a solution by adding more solvent.

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LD50

The amount of a toxic substance that causes 50% of test animals to die if they are given a specific dose at once.

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Toxicity

The measure of how poisonous a substance is.

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Toxins

A substance that can cause serious health problems or death when ingested or absorbed into the body.

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Parts per million (ppm)

A measure of the concentration of a substance in a solution. It is expressed as parts per million (ppm).

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Biodegradable

A substance that gets broken down by bacteria in the environment.

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Persistent Pesticides

Pesticides that persist in the environment and are not easily broken down.

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Synergistic Effect

A combination of chemicals that can be more deadly than each individual chemical on its own.

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Biodegradation

The process of breaking down waste materials into less harmful substances, often by using microorganisms like bacteria.

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What is LD50?

The amount of a substance that is needed to kill 50% of a population of test animals.

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How to calculate Maximum Dosage?

The maximum dosage of a substance that can be given to a specific weight of an animal before reaching the LD50.

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What is the caffeine LD50?

The amount of caffeine that is needed to kill 50% of a population of test animals.

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How much caffeine is lethal for a 55kg person?

The maximum dosage of caffeine that can be given to a 55 kg person before reaching the LD50.

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What are the side effects of exceeding the recommended caffeine dose?

Side effects of consuming caffeine above the recommended daily dose.

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What is a toxin?

A chemical or substance that is poisonous or harmful to living organisms.

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What is toxicity?

The ability of a substance to cause harm to living organisms.

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What is biodegradation?

The process of breaking down waste materials into less harmful substances, often by using microorganisms like bacteria.

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Study Notes

Wastewater Treatment Overview

  • Wastewater treatment aims to return used water to the environment with minimal pollutants.
  • This involves several stages including primary, secondary, and tertiary treatment.
  • Primary treatment physically separates large solids and sediments.
  • Secondary treatment involves bacteria decomposing organic matter.
  • Tertiary treatment removes phosphates and nitrates to meet discharge standards, often using percolation through plant beds or UV light.

Sources of Wastewater Nitrogen

  • A study suggests that wastewater adds 6.2 million tonnes of nitrogen to coastal waters globally.
  • Leading polluters include China (1,890 thousand tonnes), India (659 thousand tonnes), and the United States (358 thousand tonnes).
  • Major sources include a lack of proper toilet facilities, septic tanks, and inadequate sewer systems.
  • Wastewater nitrogen sources include household wastes like toilets, sinks, showers, and other household wastewater.

Nutrients in Wastewater

  • Wastewater contains significant amounts of nitrogen, phosphorus, and potassium, enough to offset over 13% of global agricultural fertilizer demand.
  • Potential revenue from recovering these nutrients is estimated at US$13.6 billion annually.
  • Nitrogen, phosphorus, and potassium levels in wastewater are significant in teragrams. Wastewater contains these nutrients in teragrams.

Stormwater vs. Wastewater

  • Stormwater runoff from streets and other surfaces is collected separately from wastewater from sinks and toilets.
  • Stormwater is routed to different channels and basins and is not treated before flowing into water sources.
  • Wastewater is treated before releasing into water bodies to prevent pollution and meet discharge standards.

Sanitary Landfills

  • Sanitary landfills are used for household and industrial waste disposal, usually compacted, and covered with earth, and sometimes clay.
  • Leachate collection pipes and liners keep contaminants from contaminating groundwater.
  • Methane gas byproducts are managed to prevent release into the atmosphere. The gas is often recovered for use.

Secure Landfills

  • Secure landfills are for hazardous waste disposal in land, designed, constructed, and operated to prevent pollution outside the facility.
  • Hazardous waste is contained using liners and collection systems to prevent contaminants from entering groundwater.

Fuel Combustion

  • Burning hydrocarbons (e.g., coal, oil, natural gas) releases carbon dioxide, water vapor, sulfur dioxide, nitrogen oxides, mercury, and lead into the atmosphere.
  • These emissions contribute to environmental issues like acid rain and air pollution.

Industrial Processes

  • Industrial processes, such as electrical energy generation, mineral processing, and fertilizer production, release harmful chemicals, such as sulfur oxides and nitrogen oxides into the air. These processes also release compounds like methane, ethane, propane, and butane.
  • Natural gas (containing hydrogen sulfide, H2S, "sour gas") requires treatment to remove H2S, generating sulfur dioxide.

Other Considerations

  • Septic tanks (rural areas) are large underground containers that trap grease and solids. Liquid waste is distributed through pipes into a gravel drainage area, preventing groundwater contamination.
  • Bacteria and microorganisms help decompose organic waste in sewage and septic systems.
  • Wastewater treatment plants use biological and chemical processes to remove pollutants (e.g., lime, biological treatment methods like activated sludge).

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