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Questions and Answers
Which of the following is a characteristic of aromatic hydrocarbons?
Which of the following is a characteristic of aromatic hydrocarbons?
- They contain only straight-chain hydrocarbon structures.
- They include a benzene ring in their molecular structure. (correct)
- They exclusively consist of aliphatic compounds.
- They are composed entirely of saturated hydrocarbons.
What represents the correct formula for the complete combustion of hydrocarbons in the presence of excess oxygen?
What represents the correct formula for the complete combustion of hydrocarbons in the presence of excess oxygen?
- Hydrocarbon + Oxygen → CO + H₂O + energy
- Hydrocarbon + Oxygen → CO₂ + H₂ + energy
- Hydrocarbon + Oxygen → H₂ + CO
- Hydrocarbon + Oxygen → CO₂ + H₂O + heat (correct)
Which of the following accurately lists a characteristic of octane number affecting factors?
Which of the following accurately lists a characteristic of octane number affecting factors?
- Cyclic structures generally yield lower octane numbers.
- Linear structures lead to higher octane ratings.
- A greater number of branches in hydrocarbons increases octane number. (correct)
- Long carbon chains increase octane number.
Which of the following fractions is correctly matched with its corresponding hydrocarbon range?
Which of the following fractions is correctly matched with its corresponding hydrocarbon range?
What is the equation used to determine heat change in a substance?
What is the equation used to determine heat change in a substance?
Why is hydrogen not commonly used as a fuel source despite its high energy content?
Why is hydrogen not commonly used as a fuel source despite its high energy content?
What is the role of tetraethyl lead as an additive in fuels?
What is the role of tetraethyl lead as an additive in fuels?
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Study Notes
Law of Conservation of Energy
- Energy cannot be created or destroyed; it can only change forms.
- Implications include the ability to transform energy from one type to another while maintaining total energy balance.
Aromatic Hydrocarbons
- Characterized by the presence of a benzene ring in their molecular structure.
- Include compounds that exhibit unique stability and chemical properties due to their resonance structure.
Hydrocarbon Fractions
- C₁ - C₄: Refinery gas, primarily used for heating and as fuel.
- C₅ - C₁₀: Petrol (light gasoline), commonly used as fuel in vehicles.
- C₇ - C₁₀: Naphtha, often used as a solvent or as a feedstock in petrochemical processes.
- C₁₀ - C₁₄: Kerosene (paraffin), used as a fuel for jet engines and heating.
- C₁₄ - C₁₉: Diesel oil (gas oil), utilized in diesel engines and for heating purposes.
- C₁₉ - C₃₅: Lubricating oil, essential for reducing friction in machinery.
- C₃₀ - C₄₅: Fuel oil, used for heating and in power generation.
- C₃₅: Bitumen, used in road construction and roofing materials.
Combustion of Hydrocarbons
- Combustion equation: Hydrocarbon + Oxygen → CO₂ + H₂O + heat.
- Represents the chemical reaction where hydrocarbons release energy and produce carbon dioxide and water.
Heat Change Equation
- Formula: m x c x ∆T.
- m = mass of the liquid in kg, c = specific heat capacity, ∆T = change in temperature.
Auto-Ignition
- Refers to ignition occurring without an external spark, typically due to high temperatures and pressure.
Factors Affecting Octane Number
- Influenced by carbon chain length, degree of branching, and presence of cyclic structures.
- Higher octane numbers indicate better fuel stability and resistance to knocking.
Additives for Increasing Octane Number
- Tetraethyl lead: Historically used but was phased out due to toxicity and poisoning effects on catalytic converters.
- Oxygenates: Improve combustion efficiency and reduce emissions, as they burn more cleanly.
Hydrogen as Fuel Source
- Hydrogen's use is limited due to its high explosiveness.
- Storage challenges arise from its low density and the energy required for safe containment.
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