Electrophiles

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Questions and Answers

What is an electrophile?

  • A chemical species that accepts an electron pair from a nucleophile (correct)
  • A chemical species that reacts with a Lewis acid
  • A chemical species that reacts with a Lewis base
  • A chemical species that donates an electron pair to a nucleophile

Which of the following statements is true about electrophiles?

  • They are Lewis bases
  • They interact with nucleophiles through elimination reactions
  • They can be ranked in order of reactivity using the electrophilicity index (correct)
  • They are optically unstable

What is the product of the hydrohalogenation reaction?

  • Alcohol
  • Alkene
  • Alkyl halide (correct)
  • Aldehyde

What is the product of the hydration reaction?

<p>Alcohol (D)</p> Signup and view all the answers

What are the common electrophiles in organic syntheses?

<p>Cations, polarized neutral molecules, oxidizing agents, and Lewis acids (B)</p> Signup and view all the answers

What is the use of nitromethane in racing cars and model engines?

<p>Fuel (B)</p> Signup and view all the answers

What is the chemical formula of fluorosulfuric acid?

<p>HSO3F (A)</p> Signup and view all the answers

What is the difference between gitionic and distonic superelectrophiles?

<p>Gitionic superelectrophiles have charged centers separated by no more than one atom, while distonic superelectrophiles have charged centers separated by 2 or more atoms. (D)</p> Signup and view all the answers

What is the role of F-TEDA-BF4?

<p>A distonic superelectrophile (D)</p> Signup and view all the answers

What is the role of nitronium tetrafluoroborate in the nitration of nitromethane?

<p>A distonic superelectrophile (B)</p> Signup and view all the answers

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Study Notes

  • An electrophile is a chemical species that accepts an electron pair from a nucleophile.
  • Electrophiles are Lewis acids because they accept electrons.
  • Electrophiles interact with nucleophiles through addition and substitution reactions.
  • Common electrophiles in organic syntheses include cations, polarized neutral molecules, oxidizing agents, and Lewis acids.
  • Hydrogen halides add to alkenes to give alkyl halides in hydrohalogenation.
  • The hydration reaction adds a molecule of water to a molecule of ethene and produces ethanol.
  • Chiral electrophiles are optically stable and can be used in enantioselective reactions.
  • Electrophilicity index is a method to rank electrophiles in order of reactivity.
  • Superelectrophiles are cationic electrophilic reagents with greatly enhanced reactivities in the presence of superacids.
  • Electrophiles are important in organic chemistry and have many industrial applications.
  • Nitromethane can be nitrated with nitronium tetrafluoroborate only in presence of a strong acid like fluorosulfuric acid.
  • The nitration occurs via the protonated nitronium dication.
  • Gitionic superelectrophiles have charged centers separated by no more than one atom.
  • Distonic superelectrophiles have charged centers separated by 2 or more atoms.
  • The protonitronium ion is an example of a gitionic superelectrophile.
  • F-TEDA-BF4 is an example of a distonic superelectrophile.
  • The nitronium tetrafluoroborate used for nitration is a distonic superelectrophile.
  • Nitromethane is a colorless, oily liquid with a slightly sweet odor.
  • Nitromethane is used as a fuel in racing cars and model engines.
  • Fluorosulfuric acid is a strong acid with the chemical formula HSO3F.

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