Electronic Spectroscopy: UV and Visible Absorption
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Questions and Answers

Which of the following events occurs when a molecule transitions from a higher energy level to a lower energy level?

  • Emission of radiation (correct)
  • Excitation
  • Absorption of radiation
  • Nonradiative decay
  • What is the primary cause of electronic excitation in a molecule?

  • Absorption of radio waves
  • Absorption of UV-vis photons (correct)
  • Absorption of microwave radiation
  • Absorption of infrared radiation
  • What is the name of the molecular orbital that an electron is typically promoted from during electronic excitation?

  • Pi antibonding orbital
  • LUMO
  • HOMO (correct)
  • Sigma bonding orbital
  • What is the name of the group of atoms in a molecule that absorbs light, whether or not a color is produced?

    <p>Chromophore</p> Signup and view all the answers

    What is the term used to describe a transition from a higher energy level to a lower energy level without the emission of radiation?

    <p>Nonradiative decay</p> Signup and view all the answers

    Which region of the electromagnetic spectrum is associated with electronic excitation of molecules?

    <p>Ultraviolet and visible</p> Signup and view all the answers

    What is the primary requirement for a molecule to exhibit an electronic spectrum?

    <p>The molecule must have a chromophore</p> Signup and view all the answers

    Which type of molecular orbital transition is typically involved in electronic excitation?

    <p>HOMO to LUMO</p> Signup and view all the answers

    What is the primary energy range (in kJ/mol) associated with electronic excitation in molecules?

    <p>10^14 to 10^16 kJ/mol</p> Signup and view all the answers

    What is the term used to describe the process of a molecule absorbing a photon of UV-visible light?

    <p>Absorption</p> Signup and view all the answers

    What is the primary cause of the observed color in a molecule that absorbs visible light?

    <p>The molecule absorbs light of a specific wavelength</p> Signup and view all the answers

    Which of the following transitions is not considered an electronic transition?

    <p>Vibrational transitions</p> Signup and view all the answers

    Which of the following statements about electronic transitions is incorrect?

    <p>Electronic transitions are always accompanied by the emission of light</p> Signup and view all the answers

    Which region of the electromagnetic spectrum has the highest energy associated with it?

    <p>Cosmic rays</p> Signup and view all the answers

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